ChemicalBook > CAS DataBase List > 2-Amino-4-methoxy-6-methylpyrimidine

2-Amino-4-methoxy-6-methylpyrimidine

Product Name
2-Amino-4-methoxy-6-methylpyrimidine
CAS No.
7749-47-5
Chemical Name
2-Amino-4-methoxy-6-methylpyrimidine
Synonyms
TIMTEC-BB SBB006744;4-Methoxy-6-methylpyrimidin-2-amine;4-METHOXY-6-METHYL-2-PYRIMIDINAMINE;4-Methyl-6-methoxypyrimidine-2-amine;4-Methoxy-6-methylpyrimidine-2-amine;2-AMINO-4-METHYL-6-METHOXYPYRIMIDINE;2-AMINO-4-METHOXY-6-METHYLPYRIMIDINE;2-Pyrimidinamine, 4-methoxy-6-methyl-;2-Amino-4-methoxy-6-methylpyrimidine >2-AMINO-4-METHOXY-6-METHYLPYRIMIDINE, 98 %
CBNumber
CB0213118
Molecular Formula
C6H9N3O
Formula Weight
139.16
MOL File
7749-47-5.mol
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2-Amino-4-methoxy-6-methylpyrimidine Property

Melting point:
156-158 °C (lit.)
Boiling point:
255.11°C (rough estimate)
Density 
1.2081 (rough estimate)
refractive index 
1.6500 (estimate)
solubility 
methanol: soluble1%, clear to very slightly hazy, colorless to yellow
form 
powder to crystal
pka
6.38±0.10(Predicted)
color 
White to Almost white
BRN 
121733
CAS DataBase Reference
7749-47-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-21/22
Safety Statements 
26-36-37/39
WGK Germany 
3
F 
8
Hazard Note 
Irritant
HS Code 
29335990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
379468
Product name
2-Amino-4-methoxy-6-methylpyrimidine
Purity
98%
Packaging
5g
Price
$47.5
Updated
2023/06/20
Sigma-Aldrich
Product number
379468
Product name
2-Amino-4-methoxy-6-methylpyrimidine
Purity
98%
Packaging
25g
Price
$219
Updated
2023/01/07
TCI Chemical
Product number
A0950
Product name
2-Amino-4-methoxy-6-methylpyrimidine
Purity
>98.0%(T)
Packaging
25g
Price
$37
Updated
2024/03/01
TCI Chemical
Product number
A0950
Product name
2-Amino-4-methoxy-6-methylpyrimidine
Purity
>98.0%(T)
Packaging
500g
Price
$363
Updated
2024/03/01
Alfa Aesar
Product number
B24673
Product name
2-Amino-4-methoxy-6-methylpyrimidine, 99%
Packaging
5g
Price
$34.9
Updated
2021/12/16
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2-Amino-4-methoxy-6-methylpyrimidine Chemical Properties,Usage,Production

Chemical Properties

white to pinkish or light beige

Uses

2-Amino-4-methoxy-6-methylpyrimidine may be employed as nucleophile to investigate the regioselective introduction of some nucleophiles at the secondary position of Baylis-Hillman adducts. It may be used in the preparation of 2-amino-4-methoxy-6-methylpyrimidin-1-ium picrate.

General Description

2-Amino-4-methoxy-6-methylpyrimidine (AMMP) is a pyrimidine derivative. It acts as electron donor and forms charge transfer complexes with iodine (σ-electron acceptor). The FTIR and FT-Raman spectra of 2-amino-4-methoxy-6-methylpyrimidine have been recorded to evaluate the energy, structural and thermodynamical parameters. Molecules of AMMP exhibit space group of Pnma and are joined by two N-H…N hydrogen bonds.

Purification Methods

Recrystallise it from H2O. The picrate has m 220-221o(dec). [Baker et al. J Am pKEst ~ Chem Soc 69 3072, 3075 1947, Sirakawa et al. Yakugaku Zasshi 73 598 1953, Backer & Grevenstuk Recl Trav Chim, Pays-Bas 61 291 1942, Beilstein 25 III/IV 3385.]

2-Amino-4-methoxy-6-methylpyrimidine Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Amino-4-methoxy-6-methylpyrimidine Suppliers

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View Lastest Price from 2-Amino-4-methoxy-6-methylpyrimidine manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
2-Amino-4-methoxy-6-methylpyrimidine 7749-47-5
Price
US $1.00-900.00/KG
Min. Order
1g
Purity
98%
Supply Ability
50ton
Release date
2020-05-15
Dideu Industries Group Limited
Product
2-Amino-4-methoxy-6-methylpyrimidine 7749-47-5
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons Min
Release date
2021-12-06
Zhuozhou Wenxi import and Export Co., Ltd
Product
2-Amino-4-methoxy-6-methylpyrimidine 7749-47-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

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