ChemicalBook > CAS DataBase List > Methyl 5-fluoro-2-methyl-3-nitrobenzoate

Methyl 5-fluoro-2-methyl-3-nitrobenzoate

Product Name
Methyl 5-fluoro-2-methyl-3-nitrobenzoate
CAS No.
697739-03-0
Chemical Name
Methyl 5-fluoro-2-methyl-3-nitrobenzoate
Synonyms
104157;5-fluoro-2-methyl-3-nitrobenzoic acid;Methyl 5-fluoro-2-Methy-3-nitrobenzoate;5-fluoro-2-Methyl-3-nitro-, Methyl ester;methyl 5-fluoro-2-methyl-3-nitrobenzoate;5-FLUORO-2-METHYL-3-NITRO-BENZOIC ACID METHYL ESTER;Benzoic acid, 5-fluoro-2-Methyl-3-nitro-, Methyl ester
CBNumber
CB02466127
Molecular Formula
C9H8FNO4
Formula Weight
213.16
MOL File
697739-03-0.mol
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Methyl 5-fluoro-2-methyl-3-nitrobenzoate Property

Boiling point:
297.7±40.0 °C(Predicted)
Density 
1.335±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Slightly soluble in water. Soluble in dimethyl sulfoxide and acetone.
color 
White
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Safety

HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
M706755
Product name
Methyl5-fluoro-2-methyl-3-nitrobenzoate
Packaging
50mg
Price
$45
Updated
2021/12/16
TRC
Product number
M706755
Product name
Methyl5-fluoro-2-methyl-3-nitrobenzoate
Packaging
500mg
Price
$285
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0369549
Product name
METHYL-5-FLUORO-2-METHYL-3-NITROBENZOATE
Purity
95.00%
Packaging
1G
Price
$513.45
Updated
2021/12/16
AK Scientific
Product number
0795AC
Product name
Methyl5-fluoro-2-methyl-3-nitrobenzoate
Packaging
100g
Price
$851
Updated
2021/12/16
Matrix Scientific
Product number
144927
Product name
Methyl 5-fluoro-2-methyl-3-nitrobenzoate
Purity
95%
Packaging
5g
Price
$1628
Updated
2021/12/16
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Methyl 5-fluoro-2-methyl-3-nitrobenzoate Chemical Properties,Usage,Production

Uses

Methyl 5-fluoro-2-methyl-3-nitrobenzoate is used in organic synthesis and it is used in the synthesis of 6-Fluoro-4-nitroisobenzofuran-1 (3H)-one.

Preparation

Methyl 5-fluoro-2-methyl-3-nitrobenzoate synthesis: To a solution of conc. H2SO4 (700mL) was added portionwise 5-fluoro-2-methylbenzoic acid (80g, 520 mmol) at -5-0°C. Then a mixture of conc. HNO3(60.4 g. 624 mmol) in conc. H2SO4 (60 mL) was added drop-wise at -5-0°C. in a period of about 1.5 hrs. After the addition, the mixture was stirred at this temperature for 2 hrs. TLC (petroleum ether/ EtOAc=1:1) showed the reaction was complete. The mixture was poured into crash ice with vigorous stirring and the precipitate was collected by filtration. The precipitate was dissolved in EtOAc, washed with brine, dried over anhydrous Na2SO4 concentrated to give crude 5-fluoro-2-methyl-3-nitrobenzoic acid (54 g). A solution of this crude 5-fluoro-2-methyl-3-nitrobenzoic acid (54 g) in dry methanol (500 mL) was cooled to 0°C., SOCl2 (64.52g, 542.3 mmol) was added drop-wise. After the addition, the mixture was heated to reflux for 16hrs. TLC (petroleum ether/EtOAc=1:1) showed the reaction was complete. Solvent was removed under reduced pressure to give crude product. The crude product was purified by silica gel chromatography (petroleum ether to petro leum ether/EtOAc=50: 1) to give methyl 5-fluoro-2-methyl-3-nitrobenzoate (28 g, yield 25% for two steps) as a white solid.

Methyl 5-fluoro-2-methyl-3-nitrobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl 5-fluoro-2-methyl-3-nitrobenzoate manufacturers

Xingtai Haoxun Import and Export Trade Co., Ltd.
Product
5-FLUORO-2-METHYL-3-NITRO-BENZOIC ACID METHYL ESTER 697739-03-0
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10tons
Release date
2020-07-17
Henan Aochuang Chemical Co.,Ltd.
Product
Methyl 5-fluoro-2-methyl-3-nitrobenzoate 697739-03-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-30
Hebei Zhanyao Biotechnology Co. Ltd
Product
Methyl 5-fluoro-2-methyl-3-nitrobenzoate 697739-03-0
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2021-08-18

697739-03-0, Methyl 5-fluoro-2-methyl-3-nitrobenzoateRelated Search:


  • 5-FLUORO-2-METHYL-3-NITRO-BENZOIC ACID METHYL ESTER
  • 5-fluoro-2-methyl-3-nitrobenzoic acid
  • Benzoic acid, 5-fluoro-2-Methyl-3-nitro-, Methyl ester
  • 5-fluoro-2-Methyl-3-nitro-, Methyl ester
  • Methyl 5-fluoro-2-Methy-3-nitrobenzoate
  • 104157
  • methyl 5-fluoro-2-methyl-3-nitrobenzoate
  • 697739-03-0
  • 69773-03-3
  • 697739-03-0