ChemicalBook > CAS DataBase List > Methyl 5-fluoro-2-methyl-3-nitrobenzoate
Methyl 5-fluoro-2-methyl-3-nitrobenzoate
- Product Name
- Methyl 5-fluoro-2-methyl-3-nitrobenzoate
- CAS No.
- 697739-03-0
- Chemical Name
- Methyl 5-fluoro-2-methyl-3-nitrobenzoate
- Synonyms
- 104157;5-fluoro-2-methyl-3-nitrobenzoic acid;Methyl 5-fluoro-2-Methy-3-nitrobenzoate;5-fluoro-2-Methyl-3-nitro-, Methyl ester;methyl 5-fluoro-2-methyl-3-nitrobenzoate;5-FLUORO-2-METHYL-3-NITRO-BENZOIC ACID METHYL ESTER;Benzoic acid, 5-fluoro-2-Methyl-3-nitro-, Methyl ester
- CBNumber
- CB02466127
- Molecular Formula
- C9H8FNO4
- Formula Weight
- 213.16
- MOL File
- 697739-03-0.mol
More
Less
Methyl 5-fluoro-2-methyl-3-nitrobenzoate Property
- Boiling point:
- 297.7±40.0 °C(Predicted)
- Density
- 1.335±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Slightly soluble in water. Soluble in dimethyl sulfoxide and acetone.
- color
- White
More
Less
Safety
- HS Code
- 2916399090
More
Less
N-Bromosuccinimide Price
TRC
- Product number
- M706755
- Product name
- Methyl5-fluoro-2-methyl-3-nitrobenzoate
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
TRC
- Product number
- M706755
- Product name
- Methyl5-fluoro-2-methyl-3-nitrobenzoate
- Packaging
- 500mg
- Price
- $285
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- HCH0369549
- Product name
- METHYL-5-FLUORO-2-METHYL-3-NITROBENZOATE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $513.45
- Updated
- 2021/12/16
AK Scientific
- Product number
- 0795AC
- Product name
- Methyl5-fluoro-2-methyl-3-nitrobenzoate
- Packaging
- 100g
- Price
- $851
- Updated
- 2021/12/16
Matrix Scientific
- Product number
- 144927
- Product name
- Methyl 5-fluoro-2-methyl-3-nitrobenzoate
- Purity
- 95%
- Packaging
- 5g
- Price
- $1628
- Updated
- 2021/12/16
More
Less
Methyl 5-fluoro-2-methyl-3-nitrobenzoate Chemical Properties,Usage,Production
Uses
Methyl 5-fluoro-2-methyl-3-nitrobenzoate is used in organic synthesis and it is used in the synthesis of 6-Fluoro-4-nitroisobenzofuran-1 (3H)-one.
Preparation
Methyl 5-fluoro-2-methyl-3-nitrobenzoate synthesis: To a solution of conc. H2SO4 (700mL) was added portionwise 5-fluoro-2-methylbenzoic acid (80g, 520 mmol) at -5-0°C. Then a mixture of conc. HNO3(60.4 g. 624 mmol) in conc. H2SO4 (60 mL) was added drop-wise at -5-0°C. in a period of about 1.5 hrs. After the addition, the mixture was stirred at this temperature for 2 hrs. TLC (petroleum ether/ EtOAc=1:1) showed the reaction was complete. The mixture was poured into crash ice with vigorous stirring and the precipitate was collected by filtration. The precipitate was dissolved in EtOAc, washed with brine, dried over anhydrous Na2SO4 concentrated to give crude 5-fluoro-2-methyl-3-nitrobenzoic acid (54 g). A solution of this crude 5-fluoro-2-methyl-3-nitrobenzoic acid (54 g) in dry methanol (500 mL) was cooled to 0°C., SOCl2 (64.52g, 542.3 mmol) was added drop-wise. After the addition, the mixture was heated to reflux for 16hrs. TLC (petroleum ether/EtOAc=1:1) showed the reaction was complete. Solvent was removed under reduced pressure to give crude product. The crude product was purified by silica gel chromatography (petroleum ether to petro leum ether/EtOAc=50: 1) to give methyl 5-fluoro-2-methyl-3-nitrobenzoate (28 g, yield 25% for two steps) as a white solid.
Methyl 5-fluoro-2-methyl-3-nitrobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
More
Less
Methyl 5-fluoro-2-methyl-3-nitrobenzoate Suppliers
- Tel
- 010-82967028 13552068683
- Fax
- +86-10-82967029
- 2355560935@qq.com
- Country
- China
- ProdList
- 12458
- Advantage
- 60
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9551
- Advantage
- 66
- Tel
- 021-50795510 4000665055
- Fax
- 021-50795055
- sales@accelachem.com
- Country
- China
- ProdList
- 11660
- Advantage
- 64
- Tel
- Country
- China
- ProdList
- 42982
- Advantage
- 64
- Tel
- 010-59484199 18611897322
- sales@eternalchem.com
- Country
- China
- ProdList
- 4384
- Advantage
- 60
- Tel
- +8613162137806 18575662672
- Fax
- 021 51613951
- mzeng@3wpharm.com
- Country
- China
- ProdList
- 9746
- Advantage
- 57
- Tel
- 022-58013646 13011382049
- Fax
- 022-23854368
- sales@jinyudachem.com
- Country
- China
- ProdList
- 1882
- Advantage
- 55
- Tel
- 0555-8228058 13621628489
- Fax
- 0512-63261912
- sales1@stepuppharm.com
- Country
- China
- ProdList
- 228
- Advantage
- 55
- Tel
- 13598610367 0373-7129549
- Fax
- 0373-8369699
- 2468833170@qq.com
- Country
- China
- ProdList
- 932
- Advantage
- 58
- Tel
- 021-58170097
- info@topbiochem.com
- Country
- China
- ProdList
- 9452
- Advantage
- 58
- Tel
- 13901585132
- Fax
- +86-25-52131256
- 799750417@qq.com
- Country
- China
- ProdList
- 8888
- Advantage
- 55
- Tel
- 021-34666753 13311639313
- Fax
- +86-21-34979012
- info@shyrchem.com
- Country
- China
- ProdList
- 570
- Advantage
- 55
- Tel
- 021-58950125
- Fax
- (86) 21-58955996
- info@chemexpress.com
- Country
- China
- ProdList
- 7553
- Advantage
- 61
- Tel
- 020-39119399 18927568969
- Fax
- 020-39119999
- isunpharm@qq.com
- Country
- China
- ProdList
- 4428
- Advantage
- 55
- Tel
- +86-28-87361500 13880902127
- Fax
- +86-28-87361500
- arcche@163.com
- Country
- China
- ProdList
- 46
- Advantage
- 56
- Tel
- 0512-62857507
- Fax
- +86-512-62857507
- sales@sinorarechem.com
- Country
- China
- ProdList
- 981
- Advantage
- 58
- Tel
- 400-1647117 15221909166
- Fax
- +86-21-61629029
- product02@bidepharm.com
- Country
- China
- ProdList
- 41438
- Advantage
- 60
- Tel
- 0571-87086220 18657191323
- Fax
- 0571-87012927
- zyf@trylead-chem.com
- Country
- China
- ProdList
- 306
- Advantage
- 64
- Tel
- 0531-88803958; 18866891188
- Fax
- 0531-82777287
- zhaojiangxia@shiningpharm.com
- Country
- China
- ProdList
- 267
- Advantage
- 58
- Tel
- 021-021-56795766
- Fax
- +86-21-56795266
- sales@worldyachem.com
- Country
- China
- ProdList
- 9352
- Advantage
- 58
- Tel
- 86-0571-87649320
- Fax
- 86-0571-87649320
- dechem@aliyun.com
- Country
- China
- ProdList
- 163
- Advantage
- 58
- Tel
- 13120367189
- Fax
- 021-50315529
- mychess007@163.com
- Country
- China
- ProdList
- 1994
- Advantage
- 55
- Tel
- sales@ahpharmatech.com
- Country
- China
- ProdList
- 5738
- Advantage
- 55
- Tel
- 021-20900665 17321230821
- Fax
- 021-20900665
- 2986274987@qq.com
- Country
- China
- ProdList
- 982
- Advantage
- 55
- Tel
- 021-61478794
- Fax
- 021-61478794
- sales@hcshhai.com
- Country
- China
- ProdList
- 9798
- Advantage
- 50
- Tel
- 13598610367
- Fax
- QQ:2468833170
- 2841375912@qq.com
- Country
- China
- ProdList
- 2793
- Advantage
- 52
- Tel
- 021-60455363 18019463053
- Fax
- 50966098
- sales@coolpharm.com
- Country
- China
- ProdList
- 12357
- Advantage
- 58
- Tel
- 13770809694
- Fax
- +86 25 56203983
- googlexu_0114@sina.com
- Country
- China
- ProdList
- 989
- Advantage
- 58
- Tel
- 15066662237 15066662237
- 3281004549@qq.com
- Country
- China
- ProdList
- 278
- Advantage
- 55
- Tel
- 13912302692 13912302692
- Fax
- 0519-88064678
- sales@anxuanchem.com
- Country
- China
- ProdList
- 4825
- Advantage
- 58
- Tel
- 15618758386 15618758386
- Fax
- QQ:3004479444
- sales3@myuchem.com
- Country
- China
- ProdList
- 2019
- Advantage
- 55
- Tel
- 13918644899
- Fax
- -
- tianchong009@hotmail.com
- Country
- China
- ProdList
- 1757
- Advantage
- 55
- Tel
- 021-021-20242659 18930833303
- Fax
- +86 (21) 2024-2659
- order@changyanchem.com
- Country
- China
- ProdList
- 5008
- Advantage
- 55
- Tel
- 0519-85528066 13775048983
- Fax
- 0519-85528066
- sales@hopschem.com
- Country
- China
- ProdList
- 31557
- Advantage
- 55
- Tel
- 023-67950001 13883380852
- Fax
- 023-68265899
- cqhfyy@foxmail.com
- Country
- China
- ProdList
- 38
- Advantage
- 55
- Tel
- 025-025-58367986 18913956109
- Fax
- QQ:3209878052
- amy.xiang@ally-chem.com
- Country
- China
- ProdList
- 407
- Advantage
- 58
- Tel
- 028-83379370 13880556291
- Fax
- 028-87747383
- tcy@tcypharm.com
- Country
- China
- ProdList
- 5463
- Advantage
- 58
- Tel
- Fax
- -
- 13006575422@163.com
- Country
- China
- ProdList
- 6357
- Advantage
- 58
- Tel
- 571-89925085
- Fax
- 0086-571-89925065
- sales@amadischem.com
- Country
- China
- ProdList
- 131981
- Advantage
- 58
- Tel
- 13621628489
- 1322392736@qq.com
- Country
- China
- ProdList
- 264
- Advantage
- 58
- Tel
- 025-66162170
- Fax
- 025-66162170
- Country
- China
- ProdList
- 7183
- Advantage
- 55
- Tel
- 0371-55900031 18137872243
- Fax
- QQ：2853979815
- 2853979815@qq.com
- Country
- China
- ProdList
- 10021
- Advantage
- 55
- Tel
- 17836913271
- Fax
- 0374-8348899
- 3224305243@qq.com
- Country
- China
- ProdList
- 2718
- Advantage
- 58
- Tel
- 027-027-83778875 15807197853
- Fax
- 027-83991220
- 15807197853@163.com
- Country
- China
- ProdList
- 3979
- Advantage
- 58
- Tel
- 4006653949
- Fax
- QQ: 2136646215
- fred.wen@crcorporation.cn
- Country
- China
- ProdList
- 10108
- Advantage
- 58
- Tel
- 0755-28967200 13631290199
- Fax
- 0755-28967200
- wxf@sungening.com
- Country
- China
- ProdList
- 9507
- Advantage
- 60
- Tel
- 86-0573-85866609 13325730825
- Fax
- 0573-85866609
- 945717149@qq.com
- Country
- China
- ProdList
- 7959
- Advantage
- 58
- Tel
- 571-85586718 +8613336195806
- Fax
- +86-571-85864795
- sales@capotchem.com
- Country
- China
- ProdList
- 29797
- Advantage
- 60
- Tel
- 025-66028182 18112977050
- Fax
- (3)02557626880
- cfzhang@aikonchem.com
- Country
- China
- ProdList
- 15820
- Advantage
- 58
- Tel
- 027-87466105 15377573527
- 2678564200@qq.com
- Country
- China
- ProdList
- 17997
- Advantage
- 58
More
Less
View Lastest Price from Methyl 5-fluoro-2-methyl-3-nitrobenzoate manufacturers
Xingtai Haoxun Import and Export Trade Co., Ltd.
- Product
- 5-FLUORO-2-METHYL-3-NITRO-BENZOIC ACID METHYL ESTER 697739-03-0
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10tons
- Release date
- 2020-07-17
Henan Aochuang Chemical Co.,Ltd.
- Product
- Methyl 5-fluoro-2-methyl-3-nitrobenzoate 697739-03-0
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-09-30
Hebei Zhanyao Biotechnology Co. Ltd
- Product
- Methyl 5-fluoro-2-methyl-3-nitrobenzoate 697739-03-0
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2021-08-18
697739-03-0, Methyl 5-fluoro-2-methyl-3-nitrobenzoateRelated Search:
Methyl 5-fluoro-2-(MethylaMino)benzoate
Methyl 5-fluoro-2-iodobenzoate
METHYL 5-FLUORO-2-HYDROXYBENZOATE
Dimethyl carbonate
5-Formylimidazole-4-carboxylic acid methyl ester
Methyl 5-formylpyrrole-3-carboxylate
Methyl 5-fluoro-6-Methoxy-1H-indole-2-carboxylate
5-FLUORO-2-METHOXYBENZALDEHYDE
5-FLUORO-2-METHOXYACETOPHENONE
5-Fluoro-2-methoxyphenol
5-Fluoro-2-methoxyphenyl acetic acid
5-FLUORO-2-METHOXYBENZONITRILE
5-Fluoro-2-methylbenzoic acid
METHYL 2-METHYL-5-FLUOROBENZOATE