ChemicalBook > CAS DataBase List > 7-Bromo[1,2,4]triazolo[1,5-a]pyridine

7-Bromo[1,2,4]triazolo[1,5-a]pyridine

Product Name
7-Bromo[1,2,4]triazolo[1,5-a]pyridine
CAS No.
1053655-66-5
Chemical Name
7-Bromo[1,2,4]triazolo[1,5-a]pyridine
Synonyms
7-broMo-[1;7-Bromo[1,2,4]triazolo[1,...;7-Bromo[1,2,4]triazolo[1,5-a]pyridine;[1,2,4]Triazolo[1,5-a]pyridine, 7-bromo-;7-Bromo[1,2,4]triazolo[1,5-a]pyridine
CBNumber
CB02471307
Molecular Formula
C6H4BrN3
Formula Weight
198.02
MOL File
1053655-66-5.mol
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7-Bromo[1,2,4]triazolo[1,5-a]pyridine Property

Density 
1.89±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
solid
pka
1.76±0.30(Predicted)
Appearance
Off-white to yellow Solid
InChI
InChI=1S/C6H4BrN3/c7-5-1-2-10-6(3-5)8-4-9-10/h1-4H
InChIKey
VGJYOOVSVQHZPL-UHFFFAOYSA-N
SMILES
C12=NC=NN1C=CC(Br)=C2
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Safety

HS Code 
2933998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
SYX00403
Product name
7-Bromo[1,2,4]triazolo[1,5-a]pyridine
Packaging
1g
Price
$497
Updated
2025/07/31
TRC
Product number
B688508
Product name
7-Bromo[1,2,4]triazolo[1,5-a]pyridine
Packaging
1g
Price
$175
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
B12862
Product name
7-Bromo-[1,2,4]triazolo[1,5-a]pyridine
Purity
93%
Packaging
500mg
Price
$100
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
B12862
Product name
7-Bromo-[1,2,4]triazolo[1,5-a]pyridine
Purity
93%
Packaging
1g
Price
$150
Updated
2021/12/16
Matrix Scientific
Product number
069771
Product name
7-Bromo[1,2,4]triazolo[1,5-a]pyridine
Purity
98%
Packaging
500mg
Price
$170
Updated
2021/12/16
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7-Bromo[1,2,4]triazolo[1,5-a]pyridine Chemical Properties,Usage,Production

Synthesis

64-18-6

1202704-61-7

1053655-66-5

General procedure for the synthesis of 7-bromo-[1,2,4]triazolo[1,5-a]pyridine from formic acid and the compound (CAS: 1202704-61-7): concentrated hydrochloric acid (3 mL) was added to a mixture of 98% formic acid (12 mL) and water (3 mL) of the compound 18, and the reaction mixture was heated and refluxed for 15 hours. Upon completion of the reaction, the mixture was concentrated under reduced pressure to half the original volume and neutralized with aqueous NaHCO3. The neutralized solution was extracted with a solvent mixture of methanol-chloroform (1:9, v/v). The organic phase was washed with water, dried over anhydrous sodium sulfate and evaporated under reduced pressure to remove the solvent. The resulting residue was recrystallized with hexane-chloroform mixed solvent to give 3.313 g of compound 19 as colorless needle-like crystals. The recrystallized mother liquor was further purified by column chromatography (eluent: methanol-chloroform, 1:19, v/v), and again recrystallized with hexane-chloroform mixed solvent to afford 977 mg of Compound 19 as colorless needle-like crystals. Total yield: 4.290 g (84%). Properties of compound 19: colorless needle-like crystals, melting point: 108-108.5 °C (hexane-CHCl3); 1H-NMR (300 MHz, CDCl3) δ 7.15 (dd, J = 7.2 Hz, 1H), 7.97 (d, J = 2 Hz, 1H), 8.34 (s, 1H), 8.48 (d, J = 7 Hz, 1H); LRMS m/z 197, 199 (M+, 100, 97), 156, 158 (10, 11), 91 (42), 64 (74).

References

[1] Patent: US2011/98471, 2011, A1. Location in patent: Page/Page column 59-60

7-Bromo[1,2,4]triazolo[1,5-a]pyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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7-Bromo[1,2,4]triazolo[1,5-a]pyridine Suppliers

Shanghai RenYue Chemical Technology Co., Ltd.
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China
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Hangzhou Copiore Chemical Co., Ltd.
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0571-56501939;0571-56076030 13757145729
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sales@copiore.com
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China
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J & K SCIENTIFIC LTD.
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Pure Chemistry Scientific Inc.
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View Lastest Price from 7-Bromo[1,2,4]triazolo[1,5-a]pyridine manufacturers

Career Henan Chemical Co
Product
7-Bromo[1,2,4]triazolo[1,5-a]pyridine 1053655-66-5
Price
US $6.68/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg-1000kg
Release date
2020-01-08

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