ChemicalBook > CAS DataBase List > (Carbomethoxymethyl)triphenylphosphonium bromide

(Carbomethoxymethyl)triphenylphosphonium bromide

Product Name
(Carbomethoxymethyl)triphenylphosphonium bromide
CAS No.
1779-58-4
Chemical Name
(Carbomethoxymethyl)triphenylphosphonium bromide
Synonyms
CMMTPPB;NSC 136109;methyl (triphenylphosphonio)acetate bromide;(2-methoxy-2-oxoethyl)-triphenylphosphanium;CARBOMETHOXYMETHYL TRIPHENYLPHOSPHONIUM BROMIDE;carbmethoxy Methyl Triphenyl Phosphonium Bromide;MethoxycarbonylMethyl)triphenylphosphoniuM broMi;(2-Oxo-2-methoxyethyl)triphenylphosphonium·bromide;(2-methoxy-2-oxoethyl)triphenylphosphonium bromide;Triphenyl(2-oxo-2-methoxyethyl)phosphonium·bromide
CBNumber
CB0254687
Molecular Formula
C21H20BrO2P
Formula Weight
415.26
MOL File
1779-58-4.mol
More
Less

(Carbomethoxymethyl)triphenylphosphonium bromide Property

Melting point:
165-170 °C (dec.) (lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble in methanol(almost transparency).
form 
solid
color 
White to Almost white
Sensitive 
Hygroscopic
BRN 
3812975
InChIKey
VCWBQLMDSMSVRL-UHFFFAOYSA-M
CAS DataBase Reference
1779-58-4(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
9
HS Code 
29319019
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
259063
Product name
(Methoxycarbonylmethyl)triphenylphosphonium bromide
Purity
98%
Packaging
50g
Price
$85.2
Updated
2023/01/07
Sigma-Aldrich
Product number
259063
Product name
(Methoxycarbonylmethyl)triphenylphosphonium bromide
Purity
98%
Packaging
250g
Price
$326
Updated
2023/01/07
TCI Chemical
Product number
M1326
Product name
Methoxycarbonylmethyl(triphenyl)phosphonium Bromide
Purity
>97.0%(HPLC)(T)
Packaging
25g
Price
$68
Updated
2024/03/01
Alfa Aesar
Product number
A16301
Product name
(Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%
Packaging
25g
Price
$33.65
Updated
2024/03/01
Alfa Aesar
Product number
A16301
Product name
(Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%
Packaging
100g
Price
$93.65
Updated
2024/03/01
More
Less

(Carbomethoxymethyl)triphenylphosphonium bromide Chemical Properties,Usage,Production

Chemical Properties

white powder

Uses

(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts.

Purification Methods

Wash it with pet ether (b 40-50o), recrystallise it from CHCl3/Et2O and dry it at high vacuum at 65o. [Isler et al. Helv Chim Acta 40 1242 1957, Wittig & Haag Chem Ber 88 1654, 1664 1955, Beilstein 16 IV 981.]

(Carbomethoxymethyl)triphenylphosphonium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(Carbomethoxymethyl)triphenylphosphonium bromide Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12438
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9414
Advantage
66
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11655
Advantage
64
More
Less

View Lastest Price from (Carbomethoxymethyl)triphenylphosphonium bromide manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
(Carbomethoxymethyl)triphenylphosphonium bromide 1779-58-4
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-23
Hebei Weibang Biotechnology Co., Ltd
Product
(Carbomethoxymethyl)triphenylphosphonium bromide 1779-58-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2022-11-03
Henan Fengda Chemical Co., Ltd
Product
(2-Methoxy-2-oxoethyl)triphenylphosphonium bromide 1779-58-4
Price
US $5.00-0.50/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-13

1779-58-4, (Carbomethoxymethyl)triphenylphosphonium bromideRelated Search:


  • (2-methoxy-2-oxoethyl)triphenylphosphonium bromide
  • carbmethoxy Methyl Triphenyl Phosphonium Bromide
  • Carbomethoxymethyl triphenylphosphonium bromide, 98+%
  • CARBOMETHOXYMETHYL TRIPHENYLPHOSPHONIUM BROMIDE
  • (METHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
  • methyl (triphenylphosphonio)acetate bromide
  • PHOSPHONIUM,(2-METHOXY-2-OXOETHYL)TRIPHENYL-,BROMIDE
  • (METHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE, 98+%
  • CMMTPPB
  • (2-methoxycarbonylphenyl)-methyl-diphenylphosphonium bromide
  • (2-Oxo-2-methoxyethyl)triphenylphosphonium·bromide
  • Triphenyl(2-oxo-2-methoxyethyl)phosphonium·bromide
  • Triphenyl(methoxycarbonylmethyl)phosphonium·bromide
  • MethoxycarbonylMethyl)triphenylphosphoniuM broMi
  • (MethoxycarbonylMethyl)triphenylphosphoniuM broMide, 98+%, 98+%
  • NSC 136109
  • Methoxycarbonylmethyl(triphenyl)phosphoniumBromide&gt
  • (2-methoxy-2-oxoethyl)-triphenylphosphanium,bromide
  • (2-methoxy-2-oxoethyl)-triphenylphosphanium
  • (methyloxycarbonylmethyl)triphenylphosphonium bromide
  • 1779-58-4
  • CH3O2CCH2PC6H53Br
  • CH3OCOCH2PBrC6H53
  • C21H20O2PBr
  • C-C Bond Formation
  • Phosphonium Compounds
  • Wittig & Horner-Emmons Reaction
  • Wittig Reaction
  • Synthetic Reagents
  • Wittig Reagents
  • Olefination
  • Phosphonium Compounds
  • Synthetic Organic Chemistry
  • Wittig & Horner-Emmons Reaction
  • Wittig Reaction
  • bc0001