ChemicalBook > CAS DataBase List > 4-Iodobenzotrifluoride

4-Iodobenzotrifluoride

Product Name
4-Iodobenzotrifluoride
CAS No.
455-13-0
Chemical Name
4-Iodobenzotrifluoride
Synonyms
1-IODO-4-(TRIFLUOROMETHYL)BENZENE;4-(TRIFLUOROMETHYL)IODOBENZENE;4-IodobenzotrifL;BUTTPARK 45\01-80;4-Iodobenztrifluoride;P-IODOBENZOTRIFLUORIDE;4-IODOBENZOTRIFLUORIDE;Iodine benzotrifluoride;P-IODO TRIFLUORO TOLUENE;p-Iodine Trifluoro Toluene
CBNumber
CB0277912
Molecular Formula
C7H4F3I
Formula Weight
272.01
MOL File
455-13-0.mol
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4-Iodobenzotrifluoride Property

Melting point:
-8.33 °C (lit.)
Boiling point:
185-186 °C/745 mmHg (lit.)
Density 
1.851 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.516(lit.)
Flash point:
156 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Liquid
color 
Clear pale yellow to yellow or red
Specific Gravity
1.851
Water Solubility 
Insoluble in water.
Sensitive 
Light Sensitive
BRN 
1944013
InChIKey
UDHAWRUAECEBHC-UHFFFAOYSA-N
CAS DataBase Reference
455-13-0(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-iodo-4-(trifluoromethyl)-(455-13-0)
EPA Substance Registry System
4-Iodobenzotrifluoride (455-13-0)
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Safety

Hazard Codes 
Xi,T
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
RIDADR 
1760
WGK Germany 
3
Hazard Note 
Toxic/Irritant
TSCA 
T
HazardClass 
8
PackingGroup 
III
HS Code 
29039990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
365858
Product name
4-Iodobenzotrifluoride
Purity
97%
Packaging
1g
Price
$36.4
Updated
2024/03/01
Sigma-Aldrich
Product number
365858
Product name
4-Iodobenzotrifluoride
Purity
97%
Packaging
5g
Price
$92.1
Updated
2024/03/01
TCI Chemical
Product number
I0550
Product name
4-Iodobenzotrifluoride (stabilized with Copper chip)
Purity
>97.0%(GC)
Packaging
5g
Price
$61
Updated
2024/03/01
TCI Chemical
Product number
I0550
Product name
4-Iodobenzotrifluoride (stabilized with Copper chip)
Purity
>97.0%(GC)
Packaging
25g
Price
$180
Updated
2024/03/01
Alfa Aesar
Product number
A12189
Product name
4-Iodobenzotrifluoride, 98%
Packaging
1g
Price
$24.65
Updated
2024/03/01
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4-Iodobenzotrifluoride Chemical Properties,Usage,Production

Chemical Properties

4-Iodobenzotrifluoride is a clear red to pink liquid with has the odor of halogenated benzene, is insoluble in water, and is miscible with benzene, toluene, ethanol, ether, halogenated hydrocarbons, etc.

Uses

4-Iodobenzotrifluoride may be employed as substrate with electron-deficient aromatic ring, during Mizoroki-Heck reaction with acrylic acid, to afford 4-trifluoromethylcinnnamic acid. It undergoes aminocarbonylation in DMF using phosphoryl chloride to give N,N-dimethyl-(4-trifluoromethyl)benzamide.

Preparation

Synthesis of 4-Iodotrifluorotoluene: Prepared by diazotization and iodination of 4-aminobenzotrifluoride or 4-Iodobenzotrifluoride is prepared by direct iodination with trifluorotoluene as raw material.

Application

The fluorine atom in the molecular structure of 4-iodotrifluorotoluene makes it have special activity. It is an important pesticide and pharmaceutical intermediate. It can be used as the intermediate of the insecticide fipronil and used for the synthesis of diphenyl ethers containing fluorine herbicide.

General Description

4-Iodobenzotrifluoride undergoes aminocarbonylation in DMF using phosphoryl chloride to give N,N-dimethyl-(4-trifluoromethyl)benzamide. Mechanism of the copper-free Sonogashira cross-coupling reaction of 4-iodobenzotrifluoride with differently para-substituted phenylacetylenes has been investigated.

4-Iodobenzotrifluoride Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Iodobenzotrifluoride Suppliers

FUXIN QINGJISHENG SCIENCE AND TECHNOLOGY CO.,LID
Tel
13365798276
Email
hxy696128@126.com
Country
China
ProdList
154
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15848
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
Advantage
57
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2883
Advantage
65
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35906
Advantage
56
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View Lastest Price from 4-Iodobenzotrifluoride manufacturers

Kindchem(Nanjing)Co.,Ltd
Product
4-Iodobenzotrifluoride 455-13-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
100
Release date
2024-01-02
Shanghai Xinchem Co., Ltd.
Product
4-Iodobenzotrifluoride 455-13-0
Price
US $0.00-0.00/KG
Min. Order
25KG
Purity
99%
Supply Ability
500KG
Release date
2023-12-21
Hebei Mojin Biotechnology Co., Ltd
Product
4-Iodobenzotrifluoride 455-13-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-18

455-13-0, 4-IodobenzotrifluorideRelated Search:


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