4-(Hydroxymethyl)phenoxyacetic acid

Product Name: 4-(Hydroxymethyl)phenoxyacetic acid
CAS No.: 68858-21-9
Chemical Name: 4-(Hydroxymethyl)phenoxyacetic acid
Synonyms: HMP;P87;P89;IMMT;Mic60;PIG52;MINOS2;P87/89;MGC111146;HPA LINKER
CBNumber: CB0294351
Molecular Formula: C9H10O4
Formula Weight: 182.17
MOL File: 68858-21-9.mol

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4-(Hydroxymethyl)phenoxyacetic acid Property

Melting point:: 112-114 °C
Boiling point:: 378.3±22.0 °C(Predicted)
Density: 1.316±0.06 g/cm3(Predicted)
storage temp.: -20°C
solubility: Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
pka: 3.15±0.10(Predicted)
form: Crystalline Powder
color: Off-white
biological source: rabbit
BRN: 5260336
InChI: InChI=1S/C9H10O4/c10-5-7-1-3-8(4-2-7)13-6-9(11)12/h1-4,10H,5-6H2,(H,11,12)
InChIKey: VUCNQOPCYRJCGQ-UHFFFAOYSA-N
SMILES: C(O)(=O)COC1=CC=C(CO)C=C1
CAS DataBase Reference: 68858-21-9(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 22-24/25-36/37/39-27-26
WGK Germany: 3
F: 10
HS Code: 29189900
Storage Class: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: HPA036165
Product name: Anti-IMMT antibody produced in rabbit
Purity: Prestige Antibodies? Powered by Atlas Antibodies, affinity isolated antibody, buffered aqueous glycerol solution
Packaging: 100μL
Price: $555
Updated: 2025/07/31

Sigma-Aldrich

Product number: HPA036164
Product name: Anti-IMMT antibody produced in rabbit
Purity: Prestige Antibodies? Powered by Atlas Antibodies, affinity isolated antibody, buffered aqueous glycerol solution
Packaging: 100μL
Price: $555
Updated: 2025/07/31

Sigma-Aldrich

Product number: 8.51000
Product name: HMPA
Purity: 4-Hydroxymethylphenoxyacetic acid Novabiochem?
Packaging: 5G
Price: $55
Updated: 2025/07/31

Sigma-Aldrich

Product number: 8.51000
Product name: HMPA
Purity: 4-Hydroxymethylphenoxyacetic acid Novabiochem?
Packaging: 25G
Price: $211
Updated: 2025/07/31

Sigma-Aldrich

Product number: HPA036164
Product name: Anti-IMMT antibody produced in rabbit
Purity: Prestige Antibodies? Powered by Atlas Antibodies, affinity isolated antibody, buffered aqueous glycerol solution
Packaging: 25μL
Price: $282
Updated: 2023/06/20

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4-(Hydroxymethyl)phenoxyacetic acid Chemical Properties,Usage,Production

Chemical Properties

Beige powder

Uses

4-(Hydroxymethyl)phenoxyacetic acid is a linkage agent used in solid-phase peptide synthesis according to the "FMOC-polyamide" technique.

reaction suitability

reagent type: linker

Synthesis

To a mixed solution of tetrahydrofuran ( 12 m L) and water ( 8 m L) of the precursor compound ester ( 312 mg , 1.48 mmol) was added lithium hydroxide ( 109 mg, 4.46 mmol) in aqueous solution, the resulting mixture was stirred and reacted at room temperature for 2 h. Then the tetrahydrofuran was removed under vacuum, and the residue obtained was acidified with 5N HCl acidified to make the reaction aqueous solution pH = 2 and extracted with EtOAc ( 3 ?? 20 m L ). ) was extracted, the combined organic layers were washed with brine, the organic layer was dried over sodium sulfate and then evaporated under vacuum to give 4-(hydroxymethyl)phenoxyacetic acid as a white solid in 89 % yield.

4-(Hydroxymethyl)phenoxyacetic acid Preparation Products And Raw materials

Raw materials

Phenoxyacetic acid Sodium sulfate Sodium chloride Formaldehyde Chloroform Ethyl acetate Hydrochloric acid Sodium bicarbonate PETROLEUM ETHER Sulfuric acid

Preparation Products

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4-(Hydroxymethyl)phenoxyacetic acid Suppliers

Americas 1 China 207 Europe 4 France 1 Germany 8 India 12 Japan 7 Slovakia 1 Switzerland 4 The Netherlands 1 Ukraine 1 United Kingdom 18 United States 48 Global 313

Suzhou Highfine Biotech Co., Ltd

Tel: 0512-68417696 13962195629
Fax: 0512-68417696
Email: minhan.zhao@highfine.com
Country: China
ProdList: 475
Advantage: 75

Huai'an Enrico Biotech Co., Ltd

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Email: 752281871@qq.com
Country: China
ProdList: 46
Advantage: 58

J & K SCIENTIFIC LTD.

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Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

INTATRADE GmbH

Tel: +49 3493/605464
Fax: +49 3493/605470
Email: sales@intatrade.de
Country: Germany
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3B Pharmachem (Wuhan) International Co.,Ltd.

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future industrial shanghai co., ltd

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Alfa Aesar

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TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
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Ark Pharm, Inc.

Tel: 847-367-3680
Fax: 847-367-3681
Email: sales@arkpharminc.com
Country: United States
ProdList: 1670
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View Lastest Price from 4-(Hydroxymethyl)phenoxyacetic acid manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 4-(Hydroxymethyl)phenoxyacetic acid 68858-21-9
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-01

Henan Aochuang Chemical Co.,Ltd.

Product: 4-(Hydroxymethyl)phenoxyacetic acid 68858-21-9
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-09-22

Zhuozhou Wenxi import and Export Co., Ltd

Product: 4-(Hydroxymethyl)phenoxyacetic acid 68858-21-9
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

68858-21-9, 4-(Hydroxymethyl)phenoxyacetic acidRelated Search:

Tris(hydroxymethyl)nitromethane Glycolic acid Ethyl methoxyacetate Methyl 2,2-dimethylphenylacetate Phenoxyacetic acid Diethoxymethyl acetate acetic acid, triethoxy-, ethyl ester 2-Hydroxyphenylacetic acid 4-Hydroxyphenylacetic acid 4-Methylphenylacetic acid Methoxyacetic acid 4-(Hydroxymethyl)benzoic acid Sodium methylparaben Methyl 4-cyanobenzoate Sodium propylparaben Ethyl 4-cyanobenzoate 4-CARBOXYPHENOXYACETIC ACID FENOFIBRIC ACID, HYDROXYMETHYL

P-(HYDROXYMETHYL)PHENOXYACETIC ACID

HydroxyMethyl)phenoxyaceticac

Anti-IMMT antibody produced in rabbit

DKFZp779P1653

IMMT

MGC111146

4-(Hydroxymethyl)phenoxyacetic acid≥ 98% (assay by titration)

HMPA 4-Hydroxymethylphenoxyacetic acid Novabiochem

HPA LINKER

HMP

HMPA LINKER

HMP LINKER

4-(HYDROXYMETHYL)PHENOXYACETIC ACID

HMP LINKER,4-(HYDROXYMETHYL) PHENOXYACETIC ACID

HMP Linker Synonyms:4-(Hydroxymethyl)Phenoxyacetic Acid

Fmoc-SCAL-linker (safety-catch linker for solid phase synthesis)

4-(HYDROXYMETHYL)PHENOXYACETIC ACID HMP LINKER 99+%

HMP LINKER, 99% MIN.

4-(Hydroxymethyl)phenoxyacetic acid, 98+%

4-(Hydroxymethyl)phe

HMPA, HMP linker

[4-(Hydroxymethyl)phenoxy]acetic acid 97%

2-[4-(hydroxymethyl)phenoxy]acetate

Hydroxymethyl Acid

4-(Hydroxymethyl)phenoxyaceticAcid&gt

Acetic acid, 2-[4-(hydroxymethyl)phenoxy]-

HMP (GDF-8)

HMPA Linker (4-(Hydroxymethyl)phenoxyacetic Acid) extrapure, 98%

Hydroxymethylphenoxyacetic acid

Mic60

MINOS2

P87

P87/89

P89

PIG52

HMP Linker, 4-(Hydroxmethyl)phenoxyacetic acid

68858-21-9

Enzyme Inhibitors

Enzyme Inhibitors by Type

Enzymes, Inhibitors, and Substrates

Substrate Analogs

Bifunctional Crosslinkers

Biochemicals and Reagents

BioChemical

Linkers

Combinatrial Chemistry

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Peptide Synthesis

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Enzyme Inhibitors by Type

Peptide Synthesis

Substrate Analogs

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Phenoxyacetic Acids and Alcohols (substituted)

Combinatorial Chemistry

Synthetic Organic Chemistry

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Linkers for Solid Phase Synthesis