ChemicalBook > CAS DataBase List > BUPIRIMATE

BUPIRIMATE

Product Name
BUPIRIMATE
CAS No.
41483-43-6
Chemical Name
BUPIRIMATE
Synonyms
-4-ol;pp588;NIMROD;nimrodt;BUPIRIMATE;BUPIRAMATE;Bupirimate 25%;Bupirimate Standard;Nimrod (Bupirimate);Atrazine Impurity 8
CBNumber
CB0310530
Molecular Formula
C13H24N4O3S
Formula Weight
316.42
MOL File
41483-43-6.mol
More
Less

BUPIRIMATE Property

Melting point:
50-51°
Boiling point:
463.2±55.0 °C(Predicted)
Density 
1.2120 (rough estimate)
vapor pressure 
1.0 x 10-4 Pa at 25 °C
refractive index 
1.6200 (estimate)
Flash point:
100 °C
storage temp. 
0-6°C
solubility 
Chloroform (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly)
form 
Solid
pka
5
Water Solubility 
22 mg l-1 (pH 5.2), 18 mg l-1 (pH 7.3), 17 mg l-1 (pH 9.3) at 25 °C
color 
White to Pale Beige
Merck 
13,1482
BRN 
758056
InChIKey
DSKJPMWIHSOYEA-UHFFFAOYSA-N
LogP
2.700
EPA Substance Registry System
Bupirimate (41483-43-6)
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
21
Safety Statements 
36/37
WGK Germany 
2
RTECS 
WO5970000
Toxicity
LD50 orally in rats: 4000 mg/kg (Finney)
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H312Harmful in contact with skin

H317May cause an allergic skin reaction

H351Suspected of causing cancer

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313IF exposed or concerned: Get medical advice/attention.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
31510
Product name
Bupirimate
Purity
PESTANAL
Packaging
250mg
Price
$76.7
Updated
2024/03/01
TRC
Product number
B689635
Product name
Bupirimate,90%
Packaging
1g
Price
$405
Updated
2021/12/16
Usbiological
Product number
162966
Product name
Bupirimate
Packaging
1g
Price
$418
Updated
2021/12/16
AK Scientific
Product number
M129
Product name
Bupirimate
Packaging
250mg
Price
$106
Updated
2021/12/16
More
Less

BUPIRIMATE Chemical Properties,Usage,Production

Uses

Bupirimate is a systemic fungicide that provides protective and curative control of powdery mildew (Podosphaera leucotricha) mainly in pome fruits, stone fruits and glasshouse roses. Other uses include berries, vines and cucurbits.

Uses

Bupirimate is a pyrimidine based fungicide with protective and curative activity for the control of fungal diseases by interfearing with nucleic acid synthesis.

Uses

Fungicide.

Definition

ChEBI: A member of the class of aminopyrimidines that is 2-ethylaminopyrimidine carrying methyl, butyl and dimethylaminosulfooxy substituents at posiitons 4, 5 and 6 respectively.

Metabolic pathway

Bupirimate degrades rapidly when exposed to sunlight. Minimal penetration of bupirimate residues in treated apples was observed. Degradation of bupirimate in/on fruit surfaces was mainly due to photolytic processes. Metabolism in plants and animals is similar and includes the initial cleavage of the dimethylsulfamate-pyrimidine linkage to yield ethirimol which is also an active fungicide. Numerous degradation products were generated from N-dealkylation, hydroxylation and conjugation reactions and the opening of the pyrimidine ring (Scheme 1).

Degradation

Bupirimate (1) is stable in dilute alkaline solution, but readily hydrolysed in dilute acidic solution. Bupirimate was rapidly decomposed in aqueous solution when exposed to sunlight (Hassall, 1982). Cleavage of the dimethylsulfamate-pyrimidine linkage yielded ethirimol [5-butyl-2- ethylamino-6-methylpyrimidin-4-ol (2)] as the major product. Ethirimol, an active fungicide, was degraded slowly under these test conditions. Four additional minor products were also detected. Three of these products were identified aS isomers of bupirimate, resulting from the migration of the dimethylsulfamate moiety to the various nitrogen molecules (compounds 3, 4 and 5; Cavell and Lincoln, 1974; Teal and Skidmore, 1976).

BUPIRIMATE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

BUPIRIMATE Suppliers

Toronto Research Chemicals
Tel
--
Fax
--
Email
info@trc-canada.com
Country
Canada
ProdList
6038
Advantage
71
AmXpress
Tel
--
Fax
--
Email
cyu@amxpress.com
Country
Canada
ProdList
815
Advantage
51
Caledon Laboratories Ltd.
Tel
--
Fax
--
Email
tech@caledonlabs.com
Country
Canada
ProdList
1149
Advantage
68
More
Less

View Lastest Price from BUPIRIMATE manufacturers

qingdao trust agri chemical co.,ltd
Product
bupirimate 41483-43-6
Price
US $0.00/kg
Min. Order
1kg
Purity
99
Supply Ability
20tons
Release date
2024-07-31
Shaanxi Dideu Medichem Co. Ltd
Product
mersalyl 41483-43-6
Price
US $1.00-100.00/KG
Min. Order
1KG
Purity
95%
Supply Ability
300KG
Release date
2024-07-17
Shaanxi Dideu Medichem Co. Ltd
Product
1-5-ANHYDRO-D-MANNITOL CRYSTALLINE 41483-43-6
Price
US $1.00-100.00/KG
Min. Order
1KG
Purity
95%
Supply Ability
200000KG
Release date
2024-07-17

41483-43-6, BUPIRIMATERelated Search:


  • Bupirimate 25%
  • BUPIRIMATE PESTANAL, 250 MG
  • Sulfamic acid, dimethyl-, 5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinyl ester
  • bupirimate (bsi,iso,ansi)
  • BUPIRAMATE
  • 5-Butyl-2-ethylamino-6-methylpyrimidin-4-yl dimethylsulfamate
  • 5-BUTYL-2-ETHYLAMINO-6-METHYLPYRIMIDIN-4-YL-DIMETHYLSULPHAMATE
  • BUPIRIMATE
  • Dimethylsulfamic acid 5-butyl-2-ethylamino-6-methylpyrimidin-4-yl ester
  • N,N-Dimethylamidosulfuric acid 5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinyl ester
  • N,N-Dimethylsulfamic acid 5-butyl-2-(ethylamino)-6-methylpyrimidin-4-yl ester
  • NIMROD
  • 2-aethylamino-5-butyl-4-yl-dimethylsulfamat
  • -4-ol
  • dimethyl-sulfamicaci5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinylester
  • dimethylsulfamicacid5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinylester
  • n,n-dimethyl-sulfamicaciesterwith5-butyl-2-ethylamino-6-methylpyrimidin
  • nimrodt
  • pp588
  • Bupirimate @100 μg/mL in Methanol
  • Bupirimate Standard
  • BupirimateSolution,100mg/L,1ml
  • Bupirimate@1000 μg/mL in Methanol
  • Sulfamic acid, N,N-dimethyl-, 5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinyl ester
  • Nimrod (Bupirimate)
  • Ethyl phenol sulfonate
  • Atrazine Impurity 8
  • Bupirimate in Acetone
  • Bupirimate 10 μg/ml Ethyl acetate
  • Bupirimate 10.0 μg/ml Acetonitrile
  • Bupirimate 100 μg/ml Ethyl acetate
  • C10850000 Bupirimate
  • XA10850000ALBupirimatE100μg/mLin Acetonitril
  • 41483-43-6
  • 41983-43-6
  • BI - BZBuilding Blocks
  • PyrimidinesPesticides
  • A-BAlphabetic
  • Alpha sort
  • B
  • Fungicides
  • Heterocyclic Building Blocks
  • Pesticides&Metabolites
  • Pyrimidines