Piperonyl acetone
Aroma Uses in Perfume- Product Name
- Piperonyl acetone
- CAS No.
- 55418-52-5
- Chemical Name
- Piperonyl acetone
- Synonyms
- DULCINYL;4-(benzo[d][1,3]dioxol-5-yl)butan-2-one;PIPERONYLACETONE;FEMA 2701;HELIOTROPYL ACETONE;Piperonylacetone>Piperonyl acetone USP/EP/BP;4-(3,4-methylenedioxyphenyl)-2;3,4-METHYLENEDIOXYBENZYL ACETONE;4-(1,3-benzodioxol-5-yl)-2-butanon
- CBNumber
- CB0328014
- Molecular Formula
- C11H12O3
- Formula Weight
- 192.21
- MOL File
- 55418-52-5.mol
Piperonyl acetone Property
- Melting point:
- 49-54 °C(lit.)
- Boiling point:
- 176 °C17 mm Hg(lit.)
- Density
- 1.175±0.06 g/cm3(Predicted)
- FEMA
- 2701 | 4-(3,4-METHYLENEDIOXYPHENYL)-2-BUTANONE
- refractive index
- 1.52-1.522
- Flash point:
- >230 °F
- storage temp.
- 4°C
- solubility
- Chloroform (Slightly), DMSO (Slightly)
- form
- Solid
- color
- Colourless crystals.
- Odor
- at 10.00 % in dipropylene glycol. sweet raspberry heliotrope powdery cotton candy
- Odor Type
- floral
- JECFA Number
- 2048
- BRN
- 169843
- InChIKey
- TZJLGGWGVLADDN-UHFFFAOYSA-N
- LogP
- 1.53
- CAS DataBase Reference
- 55418-52-5(CAS DataBase Reference)
- NIST Chemistry Reference
- 4-(3,4-Methylenedioxyphenyl)-2-butanone(55418-52-5)
- EPA Substance Registry System
- 2-Butanone, 4-(1,3-benzodioxol-5-yl)- (55418-52-5)
Safety
- Safety Statements
- 22-24/25
- WGK Germany
- 2
- TSCA
- Yes
- HS Code
- 2914.19.0000
- Toxicity
- The acute oral LD50 value in rats was reported as 4Og/kg and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Wohl, 1974).
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- S114162
- Product name
- 4-BENZO(1,3)DIOXOL-5-YL-BUTAN-2-ONE
- Purity
- Aldrich
- Packaging
- 100mg
- Price
- $179
- Updated
- 2024/03/01
- Product number
- P1089
- Product name
- Piperonylacetone
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $123
- Updated
- 2024/03/01
- Product number
- L06258
- Product name
- 4-(3,4-Methylenedioxy)phenyl-2-butanone, 98%
- Packaging
- 5g
- Price
- $42.65
- Updated
- 2024/03/01
- Product number
- L06258
- Product name
- 4-(3,4-Methylenedioxy)phenyl-2-butanone, 98%
- Packaging
- 25g
- Price
- $153.65
- Updated
- 2024/03/01
- Product number
- P475345
- Product name
- PiperonylAcetone
- Packaging
- 2.5g
- Price
- $75
- Updated
- 2021/12/16
Piperonyl acetone Chemical Properties,Usage,Production
Aroma
Intensely sweet, floral and very slightly
woody-powdery odor reminiscent of the sweetfloral notes in Mimosa and Cassie. Also
remotely reminiscent of Heliotrope.
The taste in dilutions below 50 ppm is sweet,
somewhat fruity and "Cherry-pit"-like. Higher
concentrations tend to show a somewhat bitter
taste.
Uses in Perfume
For several decades well kept as a "secret"
chemical this ketone is one of the most interest ing and successful condensation products
from a perfumery point of view. Piperonyl acetone finds
application in Lilac, Lily, Sweet Pea, Appleblossom, Mimosa, Cassie, Ylang-Ylang, Heliotrope, Carnation, etc. and is particularly
interesting in lipstick perfumes, also because
it blends well with lonones.
Piperonyl acetone finds use in flavor compositions for imitation Cherry ("pit flavor")
in various fruit complexes. Occasionally as a
modifier in Vanilla imitation.
The concentration is about 8 to 45 ppm in
finished products. The highest figures are
usually in icecream, about 50 ppm.
Description
4-(3,4-Methylenedioxyphenyl)-2-butanone has an intensely sweet, floral, slightly woody odor. May be prepared by condensation of heliotropin with acetone, followed by hydrogenation in the presence of a palladium catalyst.
Chemical Properties
4-(3,4-Methylenedioxyphenyl)-2-butanone has an intensely sweet, floral, slightly woody odor reminiscent of raspberry, cotton candy (i.e., candy floss) with a cassie, heliotrope association.
Occurrence
Has apparently not been reported to occur in nature.
Definition
ChEBI: 4-(3,4-Methylenedioxyphenyl)-2-butanone is a member of benzodioxoles.
Preparation
By condensation of heliotropin with acetone, followed by hydrogenation in the presence of a palladium catalyst
Taste threshold values
Taste characteristics at 40 ppm: sweet, berry-like with spicy, jamy nuances
Metabolism
The oxygen-aromatic carbon link of aromatic ethers is generally biologically stable, and possible metabolites include the p-hydroxy derivative of the ether, the phenol or the p-hydroxyphenol (Williams, 1959). Ketones are not readily metabolized in the body. As a derivative of 2-butanone, piperonyl acetone might be expected to be partially reduced to the secondary alcohol and excreted as the glucuronide (Williams, 1959), since Saneyoshi (1911) isolated the glucuronide of 2-butanol from the urine of rabbits receiving methyl ethyl ketone.
Piperonyl acetone Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Piperonyl acetone manufacturers
- Product
- Piperonyl acetone 55418-52-5
- Price
- US $8.00-5.30/kg
- Min. Order
- 1kg
- Purity
- 99.99%
- Supply Ability
- 10 tons
- Release date
- 2024-06-21
- Product
- Piperonyl acetone 55418-52-5
- Price
- US $680.00/Kg
- Min. Order
- 1Kg
- Purity
- 98
- Supply Ability
- 500 Kg
- Release date
- 2024-09-15
- Product
- Piperonyl acetone 55418-52-5
- Price
- US $10.00/PCS
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2021-04-07