ChemicalBook > CAS DataBase List > (S)-3-(tert-butyl)-4-(2,6-di
methoxyphenyl)-2,3-dihyd
robenzo[d][1,3]oxaphosph
ole
(S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole
Reaction- Product Name
- (S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole
- CAS No.
- 1373432-09-7
- Chemical Name
- (S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole
- Synonyms
- BI-Dime;ZJ-0018;(S)-BIDIME;(S)-BIDIME;3-tert-butyl-4-(2,6-dimethoxyphenyl)-2,3-dihydro-1,3-benzoxaphosphole;(S)-4-(2,6-Dimethoxyphenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole;(S)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole;(S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole;ZJ-0018/(S)-3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole;1,3-Benzoxaphosphole, 4-(2,6-dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-, (3S)-
- CBNumber
- CB03340408
- Molecular Formula
- C19H23O3P
- Formula Weight
- 330.36
- MOL File
- 1373432-09-7.mol
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(S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole Property
- Boiling point:
- 422.1±45.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- crystal
- color
- light-yellow
- optical activity
- Consistent with structure
- InChI
- InChI=1S/C19H23O3P/c1-19(2,3)23-12-22-16-11-6-8-13(18(16)23)17-14(20-4)9-7-10-15(17)21-5/h6-11H,12H2,1-5H3/t23-/m1/s1
- InChIKey
- BWPDUHMFZCEKIP-HSZRJFAPSA-N
- SMILES
- O1C2=CC=CC(C3=C(OC)C=CC=C3OC)=C2[P@](C(C)(C)C)C1
- CAS DataBase Reference
- 1373432-09-7
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Safety
- HS Code
- 2931499090
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N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 15-6210
- Product name
- (S)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (S)-BI-DIME
- Packaging
- 100mg
- Price
- $77
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-6210
- Product name
- (S)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (S)-BI-DIME
- Packaging
- 500mg
- Price
- $309
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-6210
- Product name
- (S)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (S)-BI-DIME
- Purity
- min. 97% (S)-BI-DIME
- Packaging
- 2g
- Price
- $925
- Updated
- 2024/03/01
ChemScene
- Product number
- CS-W023101
- Product name
- (S)-BI-DIME
- Purity
- ≥98.0%
- Packaging
- 100mg
- Price
- $67
- Updated
- 2021/12/16
ChemScene
- Product number
- CS-W023101
- Product name
- (S)-BI-DIME
- Purity
- ≥98.0%
- Packaging
- 250mg
- Price
- $141
- Updated
- 2021/12/16
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(S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole Chemical Properties,Usage,Production
Reaction
- Ligand/palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.
- Ligand/nickel catalyst for asymmetric intramolecular reductive cyclization
- Ligand/rhodium catalyst for asymmetric hydroboration
Uses
(S)-BIDIME is a P-chiral monophosphorus ligand used for the transition metal-catalyzed asymmetric Suzuki-Miyaura and hydroboration reactions.
reaction suitability
reagent type: ligand
(S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole Preparation Products And Raw materials
Raw materials
Preparation Products
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(S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole Suppliers
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1373432-09-7, (S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph oleRelated Search:
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(R)-3-(tert-butyl)-4-(2,6-di
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