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ChemicalBook > CAS DataBase List > (R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole

(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole

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Product Name
(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole
CAS No.
1338454-03-7
Chemical Name
(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole
Synonyms
(R)-BIDIME;ZJ-0022;(R)-4-(2,6-Dimethoxyphenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole;(R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole;(R)-3-(Tert-Butyl)-4-(2,6-Dimethoxyphenyl)-2,3-Dihydrobenzo[d][1,3]Oxaphosp5Hole;(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole;(3R)-4-(2,6-Dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-1,3-benzoxaphosphole;1,3-Benzoxaphosphole, 4-(2,6-dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-, (3R)-;(R)-3-(T-BUTYL)-4-(2,6-DIMETHOXYPHENYL)-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,MIN.97%(R)-BI-DIME
CBNumber
CB63340389
Molecular Formula
C19H23O3P
Formula Weight
330.36
MOL File
1338454-03-7.mol
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(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole Property

Boiling point:
422.1±45.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
crystal
color 
light-yellow
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Safety

HS Code 
2931499090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-6211
Product name
(R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (R)-BI-DIME
Packaging
100mg
Price
$77
Updated
2024/03/01
Strem Chemicals
Product number
15-6211
Product name
(R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (R)-BI-DIME
Packaging
500mg
Price
$309
Updated
2024/03/01
Strem Chemicals
Product number
15-6211
Product name
(R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (R)-BI-DIME
Purity
min. 97% (R)-BI-DIME
Packaging
2g
Price
$925
Updated
2024/03/01
ChemScene
Product number
CS-0020501
Product name
(R)-BI-DIME
Purity
>98.0%
Packaging
100mg
Price
$74
Updated
2021/12/16
ChemScene
Product number
CS-0020501
Product name
(R)-BI-DIME
Purity
>98.0%
Packaging
500mg
Price
$294
Updated
2021/12/16
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(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole Chemical Properties,Usage,Production

Reaction

  1. Ligand/palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.
  2. Ligand/nickel catalyst for asymmetric intramolecular reductive cyclization
  3. Ligand/rhodium catalyst for asymmetric hydroboration

(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole Suppliers

China 25 United States 2 Global 27
Shaoxing Zejun Pharmaceuticals Co.,Ltd
Tel
0575-82126188 15395856318
Email
service@zejunpharma.com
Country
China
ProdList
455
Advantage
58
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
Country
China
ProdList
7195
Advantage
65
Shanghai Topbiochem Technology Co., Ltd
Tel
021-58170097
Email
info@topbiochem.com
Country
China
ProdList
9458
Advantage
58
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41462
Advantage
60
LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
ProdList
2409
Advantage
58
Greenherbs Science and Technology Development Co., Ltd.
Tel
010-61136123
Fax
+86 (10) 8857-9127
Email
pub02@greenherbs.com.cn
Country
China
ProdList
4049
Advantage
58
Aikon International Limited
Tel
025-66028182 18112977050
Fax
(3)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
15818
Advantage
58
Rhawn Reagent
Tel
400-400-1332688 18019345275
Fax
400-133-2688
Email
amy@rhawn.cn
Country
China
ProdList
15497
Advantage
58
3A Chemicals
Tel
400-668-9898
Fax
010-51582189
Email
service@3achem.com
Country
China
ProdList
20557
Advantage
58

1338454-03-7, (R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph oleRelated Search:

(2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2R,2'R,3R,3'R)-3,3'-di-tert-butyl-4,4'-bis(2,6-dimethoxyphenyl)-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole (2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole (R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole (2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole 4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole (2S,2'S,3S,3'S)-4,4'-di(anth racen-9-yl)-3,3'-di-tert-but yl-2,2',3,3'-tetrahydro-2,2'- bibenzo[d][1,3]oxaphosph ole (S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole (S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole

  • (R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole
  • (R)-3-(T-BUTYL)-4-(2,6-DIMETHOXYPHENYL)-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,MIN.97%(R)-BI-DIME
  • (R)-4-(2,6-Dimethoxyphenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole
  • (R)-3-(Tert-Butyl)-4-(2,6-Dimethoxyphenyl)-2,3-Dihydrobenzo[d][1,3]Oxaphosp5Hole
  • (3R)-4-(2,6-Dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-1,3-benzoxaphosphole
  • (R)-BIDIME
  • ZJ-0022
  • 1,3-Benzoxaphosphole, 4-(2,6-dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-, (3R)-
  • (R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole
  • 1338454-03-7
  • Chiral Phosphine