Reaction
ChemicalBook > CAS DataBase List > 4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole

4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole

Reaction
Product Name
4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole
CAS No.
1268693-24-8
Chemical Name
4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole
Synonyms
rac-AntPhos;ZJ-0014;4-(anthracen-9-yl)-3-tert-butyl-2,3-dihydro-1,3-benzoxaphosphole;4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole;4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole;4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole;4-(9-Anthracenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-1,3-benzoxaphosphole;1,3-Benzoxaphosphole, 4-(9-anthracenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-;4-(ANTHRACEN-9-YL)-3-(T-BUTYL-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,98+%RAC-ANTPHOS
CBNumber
CB63340349
Molecular Formula
C25H23OP
Formula Weight
370.42
MOL File
1268693-24-8.mol
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4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole Property

Boiling point:
525.7±50.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
pale yellow
Sensitive 
air sensitive, store cold
InChI
InChI=1S/C25H23OP/c1-25(2,3)27-16-26-22-14-8-13-21(24(22)27)23-19-11-6-4-9-17(19)15-18-10-5-7-12-20(18)23/h4-15H,16H2,1-3H3
InChIKey
HKAWVLHXUZNLPP-UHFFFAOYSA-N
SMILES
O1C2=CC=CC(C3C4=CC=CC=C4C=C4C=3C=CC=C4)=C2P(C(C)(C)C)C1
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Safety

HS Code 
2931499090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-1960
Product name
4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, 98+% rac-AntPhos
Purity
98+% rac-AntPhos
Packaging
250mg
Price
$58
Updated
2024/03/01
Strem Chemicals
Product number
15-1960
Product name
4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, 98+% rac-AntPhos
Purity
98+% rac-AntPhos
Packaging
1g
Price
$172
Updated
2024/03/01
Strem Chemicals
Product number
15-1960
Product name
4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, 98+% rac-AntPhos
Purity
98+% rac-AntPhos
Packaging
5g
Price
$687
Updated
2024/03/01
Activate Scientific
Product number
AS148307
Product name
RAC-ANTPHOS
Purity
97%
Packaging
1g
Price
$204
Updated
2021/12/16
ChemScene
Product number
CS-0020502
Product name
rac-AntPhos
Purity
≥97.0%
Packaging
250mg
Price
$67
Updated
2021/12/16
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4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole Chemical Properties,Usage,Production

Reaction

  1. Ligand/palladium catalyst for general Miyaura borylation reactions.
  2. Ligand/palladium catalyst for general and sterically demanding Suzuki-Miyaura cross-coupling reactions.
  3. Ligand/palladium catalyst for aryl-alkyl Suzuki-Miyaura cross-coupling reactions.
  4. Ligand/nickel catalyst for intramolecular reductive cyclization.
  5. Ligand/palladium catalyst for Dearomative cyclization.

4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole Suppliers

China 38 United States 2 Global 40
SHAOXING ZHIJUN PHARMACEUTICAL TECHNOLOGY CO.,LTD
Tel
0575-82126188 15395856318
Email
service@zejunpharma.com
Country
China
ProdList
75
Advantage
58
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44802
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61
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9254
Advantage
66
Shanghai Topbiochem Technology Co., Ltd
Tel
021-58170097 15801866362;
Email
info@topbiochem.com
Country
China
ProdList
9520
Advantage
58
Shanghai Macklin Biochemical Co.,Ltd.
Tel
15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
ProdList
15781
Advantage
55
Shanghai Haozhixiang Biotechnology Co., Ltd
Tel
526763801 13301653310
Fax
+86-21-51619052
Email
526763801@qq.com
Country
China
ProdList
9433
Advantage
55
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
86249
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60
LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
ProdList
2280
Advantage
58
Greenherbs Science and Technology Development Co., Ltd.
Tel
010-61136123
Fax
+86 (10) 8857-9127
Email
pub02@greenherbs.com.cn
Country
China
ProdList
4049
Advantage
58
Aikon International Limited
Tel
025-66061636 19370895928
Fax
(3)02557626880
Email
qqyang@aikonchem.com
Country
China
ProdList
15813
Advantage
58

1268693-24-8, 4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphospholeRelated Search:

(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole (2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole (2S,2'S,3S,3'S)-4,4'-di(anth racen-9-yl)-3,3'-di-tert-but yl-2,2',3,3'-tetrahydro-2,2'- bibenzo[d][1,3]oxaphosph ole (S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole (S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole (2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2R,2'R,3R,3'R)-3,3'-di-tert-butyl-4,4'-bis(2,6-dimethoxyphenyl)-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole (2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole (R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole

  • 4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole
  • 4-(9-Anthracenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-1,3-benzoxaphosphole
  • 4-(ANTHRACEN-9-YL)-3-(T-BUTYL-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,98+%RAC-ANTPHOS
  • ZJ-0014
  • rac-AntPhos
  • 1,3-Benzoxaphosphole, 4-(9-anthracenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-
  • 4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole
  • 4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole
  • 4-(anthracen-9-yl)-3-tert-butyl-2,3-dihydro-1,3-benzoxaphosphole
  • 1268693-24-8
  • Achiral Phosphine
  • Aryl Phosphine