(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole

Reaction

Product Name: (R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole
CAS No.: 1456816-37-7
Chemical Name: (R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole
Synonyms: ZJ-0026;AntPhos;(R)-AntPhos;(R)-AntPhos;99％ee）[（R）-AntPhos];99% ee) [(R)-AntPhos];(3R)-4-(9-anthryl)-3-tert-butyl-2H-1,3-benzoxaphosphole;(R)-4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole;(R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole;(R)-4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole
CBNumber: CB73340391
Molecular Formula: C25H23OP
Formula Weight: 370.42
MOL File: 1456816-37-7.mol

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(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole Property

Boiling point:: 525.7±50.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: crystal
color: light yellow
Sensitive: air sensitive, store cold
InChI: 1S/C25H23OP/c1-25(2,3)27-16-26-22-14-8-13-21(24(22)27)23-19-11-6-4-9-17(19)15-18-10-5-7-12-20(18)23/h4-15H,16H2,1-3H3
InChIKey: HKAWVLHXUZNLPP-UHFFFAOYSA-N
SMILES: P1(COc2c1c(ccc2)c3c4c(cc5c3cccc5)cccc4)C(C)(C)C

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Safety

WGK Germany: WGK 3
HS Code: 2931499090
Storage Class: 11 - Combustible Solids

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 913456
Product name: (R)-AntPhos
Purity: ≥97%
Packaging: 250MG
Price: $224
Updated: 2025/07/31

Sigma-Aldrich

Product number: 913456
Product name: (R)-AntPhos
Purity: ≥97%
Packaging: 100MG
Price: $106
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1963
Product name: (R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (>99% ee) [(R)-AntPhos]
Packaging: 100mg
Price: $77
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1963
Product name: (R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (>99% ee) [(R)-AntPhos]
Packaging: 500mg
Price: $309
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1963
Product name: (R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (>99% ee) [(R)-AntPhos]
Purity: 98+% (>99% ee) [(R)-AntPhos]
Packaging: 2g
Price: $925
Updated: 2024/03/01

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(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole Chemical Properties,Usage,Production

Reaction

Ligand/palladium catalyst for general Miyaura borylation reactions.
Ligand/palladium catalyst for general and sterically demanding Suzuki-Miyaura cross-coupling reactions.
Ligand/palladium catalyst for aryl-alkyl Suzuki-Miyaura cross-coupling reactions.
Ligand/nickel catalyst for intramolecular reductive cyclization.
Ligand/palladium catalyst for Dearomative cyclization.

Uses

(R)-AntPhos is a P-chiral monophosphorus ligand used for the asymmetric Suzuki-Miyaura and Miyaura borylation reactions. This ligand is uniquely effective for sterically hindered cross-coupling reactions.

reaction suitability

reagent type: ligand

(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole Suppliers

China 29 United States 2 Global 31

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1456816-37-7, (R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphospholeRelated Search:

(2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2R,2'R,3R,3'R)-3,3'-di-tert-butyl-4,4'-bis(2,6-dimethoxyphenyl)-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole (2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole (R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole (2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole 4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole (2S,2'S,3S,3'S)-4,4'-di(anth racen-9-yl)-3,3'-di-tert-but yl-2,2',3,3'-tetrahydro-2,2'- bibenzo[d][1,3]oxaphosph ole (S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole (S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole

(R)-4-(ANTHRACEN-9-YL)-3-(T-BUTYL-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,98+%(>99%EE)[(R)-ANTPHOS]

(R)-4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole

(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole

(R)-AntPhos

ZJ-0026

99％ee）[（R）-AntPhos]

(R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98+% (&gt

99% ee) [(R)-AntPhos]

1,3-Benzoxaphosphole, 4-(9-anthracenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-, (3R)-

ZJ-0026/(R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole

(R)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole

(3R)-4-(9-anthryl)-3-tert-butyl-2H-1,3-benzoxaphosphole

(<i>R</i>)-AntPhos

AntPhos

(R)-4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole

1456816-37-7

Chiral Phosphine