(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole

Reaction

Product Name: (R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole
CAS No.: 1338454-03-7
Chemical Name: (R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole
Synonyms: (R)-BIDIME;ZJ-0022;(R)-BIDIME;(R)-4-(2,6-Dimethoxyphenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole;(R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole;(R)-3-(Tert-Butyl)-4-(2,6-Dimethoxyphenyl)-2,3-Dihydrobenzo[d][1,3]Oxaphosp5Hole;(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole;(3R)-4-(2,6-Dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-1,3-benzoxaphosphole;1,3-Benzoxaphosphole, 4-(2,6-dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-, (3R)-;(R)-3-(T-BUTYL)-4-(2,6-DIMETHOXYPHENYL)-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,MIN.97%(R)-BI-DIME
CBNumber: CB63340389
Molecular Formula: C19H23O3P
Formula Weight: 330.36
MOL File: 1338454-03-7.mol

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(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole Property

Boiling point:: 422.1±45.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: crystal
color: light-yellow
optical activity: 192.575°(C=0.8629g/100mL, CHCL3, 20°C, 589nm)
InChI: InChI=1S/C19H23O3P/c1-19(2,3)23-12-22-16-11-6-8-13(18(16)23)17-14(20-4)9-7-10-15(17)21-5/h6-11H,12H2,1-5H3/t23-/m0/s1
InChIKey: BWPDUHMFZCEKIP-QHCPKHFHSA-N
SMILES: O1C2=CC=CC(C3=C(OC)C=CC=C3OC)=C2[P@@](C(C)(C)C)C1

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Safety

HS Code: 2931499090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 15-6211
Product name: (R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (R)-BI-DIME
Packaging: 100mg
Price: $77
Updated: 2024/03/01

Strem Chemicals

Product number: 15-6211
Product name: (R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (R)-BI-DIME
Packaging: 500mg
Price: $309
Updated: 2024/03/01

Strem Chemicals

Product number: 15-6211
Product name: (R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (R)-BI-DIME
Purity: min. 97% (R)-BI-DIME
Packaging: 2g
Price: $925
Updated: 2024/03/01

ChemScene

Product number: CS-0020501
Product name: (R)-BI-DIME
Purity: >98.0%
Packaging: 100mg
Price: $74
Updated: 2021/12/16

ChemScene

Product number: CS-0020501
Product name: (R)-BI-DIME
Purity: >98.0%
Packaging: 500mg
Price: $294
Updated: 2021/12/16

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(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole Chemical Properties,Usage,Production

Reaction

Ligand/palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.
Ligand/nickel catalyst for asymmetric intramolecular reductive cyclization
Ligand/rhodium catalyst for asymmetric hydroboration

Uses

(R)-BIDIME is a P-chiral monophosphorus ligand used for the transition metal-catalyzed asymmetric Suzuki-Miyaura and hydroboration reactions.

reaction suitability

reagent type: ligand

(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole Suppliers

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1338454-03-7, (R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph oleRelated Search:

(2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2R,2'R,3R,3'R)-3,3'-di-tert-butyl-4,4'-bis(2,6-dimethoxyphenyl)-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole (2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole (R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole (2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole 4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole (2S,2'S,3S,3'S)-4,4'-di(anth racen-9-yl)-3,3'-di-tert-but yl-2,2',3,3'-tetrahydro-2,2'- bibenzo[d][1,3]oxaphosph ole (S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole (S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole

(R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole

(R)-3-(T-BUTYL)-4-(2,6-DIMETHOXYPHENYL)-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,MIN.97%(R)-BI-DIME

(R)-4-(2,6-Dimethoxyphenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole

(R)-3-(Tert-Butyl)-4-(2,6-Dimethoxyphenyl)-2,3-Dihydrobenzo[d][1,3]Oxaphosp5Hole

(3R)-4-(2,6-Dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-1,3-benzoxaphosphole

(R)-BIDIME

ZJ-0022

1,3-Benzoxaphosphole, 4-(2,6-dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-, (3R)-

(R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole

(<i>R</i>)-BIDIME

1338454-03-7

Chiral Phosphine