ChemicalBook > CAS DataBase List > Furfurylamine

Furfurylamine

Product Name
Furfurylamine
CAS No.
617-89-0
Chemical Name
Furfurylamine
Synonyms
FAM;FFA;2-Furylmethanamine;2-Furanmethanamine;2-FURYLMETHYLAMINE;C-Furan-2-yl-methylamine;usafq-1;USAF q-1;NSC 49136;NSC 61168
CBNumber
CB0364366
Molecular Formula
C5H7NO
Formula Weight
97.12
MOL File
617-89-0.mol
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Furfurylamine Property

Melting point:
−70 °C(lit.)
Boiling point:
145-146 °C(lit.)
Density 
1.099 g/mL at 25 °C(lit.)
vapor density 
3.35 (vs air)
vapor pressure 
4 mm Hg ( 20 °C)
refractive index 
n20/D 1.490(lit.)
Flash point:
116 °F
storage temp. 
Store below +30°C.
solubility 
Chloroform, Ethyl Acetate (Slightly)
form 
Liquid
pka
9.12±0.29(Predicted)
color 
Clear colorless to yellow-brown
Odor
strong fishy ammonia-like odor
PH
11.6 (100g/l, H2O, 20℃)
explosive limit
1.8%(V)
Water Solubility 
soluble
Sensitive 
Air Sensitive
BRN 
1614
Stability:
Volatile
LogP
0.37
CAS DataBase Reference
617-89-0(CAS DataBase Reference)
NIST Chemistry Reference
2-Furanmethanamine(617-89-0)
EPA Substance Registry System
Furfurylamine (617-89-0)
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Safety

Hazard Codes 
C,F,Xi
Risk Statements 
10-21/22-34-20/21/22
Safety Statements 
26-36/37/39-45-23-16
RIDADR 
UN 2526 3/PG 3
WGK Germany 
3
RTECS 
LU9275000
Autoignition Temperature
350 °C DIN 51794
Hazard Note 
Harmful/Corrosive/Flammable
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29321900
Toxicity
LD50 orally in Rabbit: 200 - 2000 mg/kg LD50 dermal Rat 100 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H301Toxic if swalloed

H310Fatal in contact with skin

H314Causes severe skin burns and eye damage

H332Harmful if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
F20009
Product name
Furfurylamine
Purity
≥99%
Packaging
5g
Price
$36.4
Updated
2024/03/01
Sigma-Aldrich
Product number
F20009
Product name
Furfurylamine
Purity
≥99%
Packaging
100g
Price
$38.2
Updated
2024/03/01
TCI Chemical
Product number
F0091
Product name
Furfurylamine
Purity
>98.0%(GC)(T)
Packaging
25mL
Price
$16
Updated
2024/03/01
TCI Chemical
Product number
F0091
Product name
Furfurylamine
Purity
>98.0%(GC)(T)
Packaging
100mL
Price
$27
Updated
2024/03/01
Alfa Aesar
Product number
B23975
Product name
Furfurylamine, 99%
Packaging
100g
Price
$32.7
Updated
2024/03/01
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Furfurylamine Chemical Properties,Usage,Production

Chemical Properties

Furfurylamine is a colorless to light yellow aromatic amine in liquid form with an ammonia odor. Miscible with water, soluble in ethanol, ether. Deteriorates in air by absorbing carbon dioxide. Derived from furfural based on corn cobs, this green chemistry has proven useful in engine cleaners, and as an intermediate for pharmaceutical, industrial and agricultural chemicals.

Uses

Furfurylamine is used as a water miscible solvent and as an intermediate in manufacturing pharmaceuticals like diuretics, antihypertensive, and antiseptic agents.
Furfurylamine also has use in the synthesis of Barmastine.
2-Furfurylamine is used in the synthesis of 2-Amino-N-(2-furylmethyl)propanamide, as a novel alanylglycine equivalent synthesized by bacilysin synthetase.

Preparation

Synthesis of furfurylamine by Zn/HCl system: To a solution of furfuryloxime (2g, 18mmol) in hydrochloric acid (6.0M, 24ml) was added drop-wise zinc dust (4.71g, 72mmol), and the resultant solution was stirred at room temperature for 2 h. To the resulting slurry was added drop-wise a solution of ammonia (30%, 5.1 mL) and sodium hydroxide (6M, 24mL), the mixture was heated to 60° and stirred for 15mn. After, the resultant solution was cooled and filtered. Then, the mother liquid was extracted with cyclohexane, dried over anhydrous sodium sulfate and filtered. The solvent was removed under vacuum to afford the furfurylamine as a yellow liquid without further purification in 96% of yield (1.68g). The purity determined by NMR was found to be superior to 95%.
SIMPLE, NOVEL SYNTHESIS OF FURFURYLAMINE FROM FURFURAL BY ONE-POT REDUCTIVE AMINATION IN WATER USING ZINC METAL

General Description

Furfurylamine appears as a colorless liquid. About the same density as water. Used as a corrosion inhibitor and to make soldering flux.

Air & Water Reactions

Highly flammable. Soluble in water.

Reactivity Profile

Amines, such as Furfurylamine, are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Hazard

Flammable, moderate fire risk.

Health Hazard

May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Flammability and Explosibility

Flammable

Safety Profile

Poison by intraperitoneal route. A skin,eye, and mucous membrane irritant. A dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, drp chemical. When heated to decomposition it emits toxic fumes of NOx. See also MINES.

Furfurylamine Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Furfurylamine manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Furfurylamine 617-89-0
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100 mt
Release date
2024-11-04
Hebei Yanxi Chemical Co., Ltd.
Product
Furfurylamine 617-89-0
Price
US $20.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-11-03
Hebei Chuanghai Biotechnology Co,.LTD
Product
2-Furfurylamine 617-89-0
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-23

617-89-0, FurfurylamineRelated Search:


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