ChemicalBook > CAS DataBase List > (R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL

(R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL

Product Name: (R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL
CAS No.: 79868-79-4
Chemical Name: (R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL
Synonyms: (R)-1,1,2-Triphenyl-2-aminoethanol;(2R)-1,1,2-Triphenyl-2-aminoethanol;(R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL;R-N-Boc-2-Amino-1,1-diphenyl-1-propanol;(S)-2-Amino-1,1-diphenyl-1-propanol,99%e.e.;Benzeneethanol, β-amino-α,α-diphenyl-, (βR)-;Benzeneethanol, b-amino-a,a-diphenyl-, (bR)-;(R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL USP/EP/BP;(R)-2-Amino-1,1,2-triphenylethanol(R)-2-Amino-1,1,2-triphenylethanol
CBNumber: CB0379142
Molecular Formula: C20H19NO
Formula Weight: 289.37
MOL File: 79868-79-4.mol

Less

(R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL Property

Melting point:: 130-131℃
Boiling point:: 456.0±40.0 °C(Predicted)
Density: 1.162±0.06 g/cm3 (20 ºC 760 Torr)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
pka: 10.89±0.50(Predicted)

Less

Safety

HS Code: 2922190090

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

SynQuest Laboratories

Product number: 4656-1-RJ
Product name: (R)-2-(+)-Amino-1,1,2-triphenylethanol
Packaging: 100mg
Price: $184
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA140896
Product name: (R)-2-Amino-1,1,2-triphenylethanol
Packaging: 250mg
Price: $245
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4656-1-RJ
Product name: (R)-2-(+)-Amino-1,1,2-triphenylethanol
Packaging: 250mg
Price: $314
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CCH0013249
Product name: (R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL
Purity: 95.00%
Packaging: 250MG
Price: $396.9
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA140896
Product name: (R)-2-Amino-1,1,2-triphenylethanol
Packaging: 500mg
Price: $430
Updated: 2021/12/16

Less

(R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL Chemical Properties,Usage,Production

Synthesis

1395342-04-7

60539-17-5

Amino alcohol (S,R)-3n (64 mg, 0.15 mmol) was used as a raw material, and Pd(OH)2 (16 mg, 0.023 mmol, 20% Pd (dry basis) loaded on carbon, containing ~50% water) was mixed in a solvent mixture of acetic acid/ dichloromethane/ methanol (0.15 mL/0.45 mL/1.5 mL) under hydrogen atmosphere (1 atm) at 30 °C with stirring overnight. Upon completion of the reaction, 1.0 M NaOH solution was added to the reaction mixture, at which time a white solid precipitated. The solid was removed by filtration and the filtrate was extracted with dichloromethane. The combined organic phases were washed sequentially with water, brine and dried with anhydrous Na2SO4. The solvent was removed by concentration under reduced pressure and the residue was purified by silica gel column chromatography (eluent: methanol/dichloromethane = 1/50) to afford amino alcohol (R)-4 as a white solid (28 mg, 66% yield). The enantiomeric excess (ee) of the product was 100%. Specific optical rotation [α]D20 was +246.4 (c 1.0, CHCl3).1H NMR (400 MHz, CDCl3) δ 1.60 (broad peak, 2H), 4.68 (broad peak, 1H), 5.00 (single peak, 1H), 6.99-7.05 (multiple peaks, 3H), 7.10-7.13 (multiple peaks, 7H), 7.27 (triple peak) J=7.2 Hz, 1H), 7.39 (triple peaks, J=8.0 Hz, 2H), 7.74 (double peaks, J=7.6 Hz, 2H); 13C NMR (100 MHz, CDCl3) δ 61.72, 79.51, 125.98, 126.19, 126.50, 126.98, 127.19, 127.32 123.39, 128.50, 128.62, 140.02, 143.83, 146.46. The spectral data were in agreement with those reported in the literature. HPLC analysis (chiral column Chiralpak OD-H, mobile phase: hexane/isopropanol = 90/10, flow rate = 1.0 mL/min, detection wavelength λ = 214 nm): retention time of main peak tmajor=16.31 min.

References

[1] Tetrahedron Letters, 2012, vol. 53, # 38, p. 5084 - 5087

(R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL Preparation Products And Raw materials

Raw materials

Preparation Products

Less

(R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL Suppliers

China 52 India 1 Spain 1 United Kingdom 5 United States 5 Global 64

Daicel Chiral Technologies (China)CO.,LTD

Tel: 021-50460086-9 15921403865
Fax: +86-21-50462321
Email: han_yajun@dctc.daicel.com
Country: China
ProdList: 7471
Advantage: 65

Tianjin Derchemist Science & Technology Co., Ltd.

Tel: 22-58627059 13920586291
Fax: 022-58620305
Email: zdcomcon@126.com
Country: China
ProdList: 3829
Advantage: 50

ShangHai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847 13636370518
Fax: 021-55068248
Email: shyysw007@163.com
Country: China
ProdList: 4999
Advantage: 60

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-6206333 13167063860
Fax: 021-50323701
Email: anhua.mao@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

Shijiazhuang Lickon PharmaTech Co., Ltd.

Tel: 031185291771 13832391721
Fax: 0311-67305698
Email: yaofeng2005@163.com
Country: China
ProdList: 978
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

Shanghai HuanChuan Industry Co.,Ltd.

Tel: 021-61478794
Fax: 021-61478794
Email: sales@hcshhai.com
Country: China
ProdList: 9793
Advantage: 50

Shanghai XinKai Chemical Technology Co., Ltd.

Tel: 021-58930698 15921516558
Fax: 86-021-58933679
Email: zhangyichao84@126.com
Country: China
ProdList: 981
Advantage: 55

Suzhou Xinkai Bio-Medical Technology Co., Ltd.

Tel: 0512-67213637 13952409868
Email: peter19zhang@163.com
Country: China
ProdList: 442
Advantage: 55

Shanghai Chiral bio-compound co., Ltd.

Tel: 021-5068 3667/17749785980/1029026415; 17749785980
Fax: 021-50683667
Email: 1029026415@qq.com
Country: China
ProdList: 3397
Advantage: 58

Zhengzhou Acme Chemical Co., Ltd.

Tel: 0371-0371-55629727 13323845623
Fax: 037155629727
Email: 2885676761@qq.com
Country: China
ProdList: 10110
Advantage: 58

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Zhengzhou Huiju Chemical Co., Ltd.

Tel: 0371-55900031 18137872243
Fax: QQ：2853979815
Email: 2853979815@qq.com
Country: China
ProdList: 9975
Advantage: 55

Shanghai Bank Pharma Limited

Tel: 021-2221346380 021-54220652 17701603001
Fax: QQ:2221346380
Email: bankpharma@163.com
Country: China
ProdList: 423
Advantage: 58

Greenherbs Science and Technology Development Co., Ltd.

Tel: 010-61136123
Fax: +86 (10) 8857-9127
Email: pub02@greenherbs.com.cn
Country: China
ProdList: 4049
Advantage: 58

Aikon International Limited

Tel: 025-66061636 18013972705
Fax: (3)02557626880
Email: qqyang@aikonchem.com
Country: China
ProdList: 15814
Advantage: 58

Shanghai Anyinuo Biomedical Technology Co., Ltd.

Tel: 021-34625901 18018851262;
Email: 420970979@qq.com
Country: China
ProdList: 5894
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 4009004166/18616739031 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52687
Advantage: 58

Guangdong wengjiang Chemical Reagent Co., Ltd.

Tel: 0751-2815688 13927872512
Fax: 0751-8963795
Email: 3007421951@qq.com
Country: China
ProdList: 9939
Advantage: 58

Suzhou Adelaide Chemical Technology Co., Ltd.

Tel: 15995785122
Email: 3003020078@qq.com
Country: China
ProdList: 1198
Advantage: 58

CD Chemical Group Limited

Tel: +8615986615575
Fax: 0086-13651442114
Email: info@codchem.com
Country: China
ProdList: 20342
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: +86-0571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: China
ProdList: 52846
Advantage: 58

Dideu Industries Group Limited

Tel: +86-29-89586680 +86-15129568250
Email: 1026@dideu.com
Country: China
ProdList: 20284
Advantage: 58

Hubei xin bonus chemical co. LTD

Tel: 86-13657291602
Fax: 027-59338440
Email: linda@hubeijusheng.com
Country: CHINA
ProdList: 22963
Advantage: 58

Shanghai jingkang bioengineering co., ltd.

Tel: 021-54721350 13524668266
Fax: 021-5
Email: 2881505714@qq.com
Country: China
ProdList: 7872
Advantage: 58

career henan chemical co

Tel: +86-0371-86658258 +8613203830695
Fax: 0086-371-86658258
Email: factory@coreychem.com
Country: China
ProdList: 29798
Advantage: 58

Shanghai shuji biotechnology co., ltd.

Tel: 021-021-62200788 15000569291
Email: zhanlingrui@163.com
Country: China
ProdList: 500
Advantage: 58

Energy Chemical

Tel: 021-58432009 400-005-6266
Fax: 021-58436166
Email: marketing@energy-chemical.com
Country: China
ProdList: 44918
Advantage: 58

Hubei Qifei Pharmaceutical Chemical Co., Ltd

Tel: 027-59322506 18071128681
Fax: 027-59322506
Email: 1438082200@qq.com
Country: China
ProdList: 9921
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-6005915
Email: sales@picasso-e.com
Country: China
ProdList: 39653
Advantage: 58

Bejing Famous Pharmaceutical Technology Co., Ltd.

Tel: 15811073878
Email: 2559355526@qq.com
Country: China
ProdList: 10701
Advantage: 58

Shanghai Haohong Scientific Co., Ltd.

Tel: 400-8210725 4008210725
Email: malulu@leyan.com
Country: China
ProdList: 40000
Advantage: 58

Beijing Solarbio Science & Tecnology Co., Ltd.

Tel: 010-50973130 17801761073
Email: Gsiyu@solarbio.com
Country: China
ProdList: 50751
Advantage: 58

Shanghai Tengjun Biotechnology Co. LTD

Tel: 19821570922
Email: angela@labgogo.com
Country: China
ProdList: 9896
Advantage: 58

Shanghai Jieshikai Biotechnology Co. , Ltd.

Tel: 021-57520305 13795461237
Email: zhuruyan@jskchem.com
Country: China
ProdList: 49234
Advantage: 58

Soochow Chirally Material Science and Technology Co.,Ltd

Tel: 0512-66834346 17751187418
Email: sales@krl-tech.com
Country: China
ProdList: 1112
Advantage: 58

Shanghai Xinhua Chemical Technology Co., Ltd

Tel: 086-18817515273 18817515273
Email: hm-huangmiao@163.com
Country: China
ProdList: 400
Advantage: 58

Jilin Chinese Academy of Sciences-yanshen Technology

Tel: 18143011203
Email: ET-market@chemextension.com
Country: China
ProdList: 32034
Advantage: 58

Nantong Hanfang Biotechnology Co. , Ltd.

Tel: hanfangpharma@126.com; 18616537568
Email: hanfangpharma@126.com
Country: China
ProdList: 29965
Advantage: 58

Shanghai Hansi Chemical Industry Co., Ltd.

Tel: 17717618050
Email: zllg@gh-reagent.com
Country: China
ProdList: 10420
Advantage: 58

Ningbo Chaoming Biotechnology Co., Ltd

Tel: 13301662590
Email: mandy@atkchemical.com
Country: China
ProdList: 9343
Advantage: 58

Soochow Chirally Material Science and Technology Co.,Ltd

Tel: +86-51266834346 +86-17751128648
Email: sales@krl-tech.com
Country: China
ProdList: 942
Advantage: 58

Hu Bei Jiutian Bio-medical Technology CO.,Ltd

Tel: 027-88013699 17354350817
Email: Ryan@jiutian-bio.com
Country: China
ProdList: 5949
Advantage: 58

Hangzhou MolCore BioPharmatech Co.,Ltd.

Tel: +86-057181025280; +8617767106207
Fax: 0571-85806285
Email: sales@molcore.com
Country: China
ProdList: 49734
Advantage: 58

Absin Bioscience Inc.

Tel: --
Fax: --
Email: chenjw@absin.cn
Country: CHINA
ProdList: 6208
Advantage: 58

Shanghai Hao Zhun Biological Technology Co., Ltd.

Tel: --
Fax: --
Email: info@zzsrm.com
Country: CHINA
ProdList: 6650
Advantage: 58

Shanghai Qiming Biological Technology Co., Ltd.

Tel: --
Fax: --
Country: CHINA
ProdList: 6502
Advantage: 58

Beijing Luyuan Bird Biotechnology Co., Ltd.

Tel: --
Fax: --
Email: 15810802415@139.com
Country: CHINA
ProdList: 6750
Advantage: 58

Shanghai Qincheng Biological Technology Co., Ltd.

Tel: --
Fax: --
Email: shqcsw01@163.com
Country: CHINA
ProdList: 6821
Advantage: 58

Shanghai Jingke Chemical Technology Co., Ltd.

Tel: --
Fax: --
Email: jingkehuaxue@163.com
Country: CHINA
ProdList: 6141
Advantage: 58

Less

View Lastest Price from (R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL manufacturers

Career Henan Chemical Co

Product: (R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL 79868-79-4
Price: US $2.00/KG
Min. Order: 1g
Purity: 98%MIN
Supply Ability: ASK
Release date: 2020-01-09

79868-79-4, (R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOLRelated Search:

Ethanol (S)-1,2,2-TRIPHENYLETHYLAMINE (1R,2R)-(+)-2-AMINO-1,2-DIPHENYLETHANOL (R)-(-)-2-PIPERIDINO-1,1,2-TRIPHENYLETHANOL (R)-4,5,5-TRIPHENYL-2-OXAZOLIDINONE (R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL (R)-2-AMINO-1,2-DIPHENYL-1-PROPANOL (R)-(+)-N-CARBOMETHOXY-2-AMINO-1,1,2-TRIPHENYLETHANOL

(R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL

(2R)-1,1,2-Triphenyl-2-aminoethanol

(R)-1,1,2-Triphenyl-2-aminoethanol

R-N-Boc-2-Amino-1,1-diphenyl-1-propanol

(R)-2-Amino-1,1,2-triphenylethanol(R)-2-Amino-1,1,2-triphenylethanol

(S)-2-Amino-1,1-diphenyl-1-propanol,99%e.e.

Benzeneethanol, β-amino-α,α-diphenyl-, (βR)-

(R)-2-(+)-AMINO-1,1,2-TRIPHENYLETHANOL USP/EP/BP

Benzeneethanol, b-amino-a,a-diphenyl-, (bR)-

79868-79-4