Description References
ChemicalBook > CAS DataBase List > Undecan-4-olide

Undecan-4-olide

Description References
Product Name
Undecan-4-olide
CAS No.
104-67-6
Chemical Name
Undecan-4-olide
Synonyms
GAMMA-UNDECALACTONE;γ-Undecalactone;γ-Undecalactone;ALDEHYDE C-14;PEACH ALDEHYDE;5-Heptyldihydro-2(3H)-furanone;γ-Unsecalactone;δ-Undecalactone;Peach;FEMA 3091
CBNumber
CB0396763
Molecular Formula
C11H20O2
Formula Weight
184.28
MOL File
104-67-6.mol
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Undecan-4-olide Property

Melting point:
164～166℃
Boiling point:
164-166 °C/13 mmHg (lit.)
Density 
0.949 g/mL at 25 °C (lit.)
vapor pressure 
0.274Pa at 25℃
FEMA 
3091 | GAMMA-UNDECALACTONE
refractive index 
n20/D 1.451
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Insoluble in water
form 
Liquid
Specific Gravity
0.944 (20/4℃)
color 
Clear colorless
Odor
at 100.00 %. fruity peach creamy fatty lactonic apricot ketonic coconut
Odor Type
fruity
Water Solubility 
158mg/L at 20℃
JECFA Number
233
BRN 
81943
LogP
3.6 at 25℃
CAS DataBase Reference
104-67-6(CAS DataBase Reference)
NIST Chemistry Reference
2(3H)-Furanone, 5-heptyldihydro-(104-67-6)
EPA Substance Registry System
5-Heptyldihydro-2(3H)-furanone (104-67-6)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-52/53
Safety Statements 
26-36-37/39-36/37-24/25
WGK Germany 
3
RTECS 
YQ2485000
TSCA 
Yes
HS Code 
29322090
Toxicity
The acute oral LD50 in rats was reported as 18.5 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964). Fatty infiltration of liver parenchymal cells occurred in rats fed 13-115 mg y-undecalactone for 5-9 days (Shillinger, 1950).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W309109
Product name
γ-Undecalactone
Purity
≥98%, FCC, FG
Packaging
1kg
Price
$75.4
Updated
2024/03/01
Sigma-Aldrich
Product number
W309109
Product name
γ-Undecalactone
Purity
≥98%, FCC, FG
Packaging
5kg
Price
$355
Updated
2024/03/01
Sigma-Aldrich
Product number
W309109
Product name
γ-Undecalactone
Purity
≥98%, FCC, FG
Packaging
10Kg
Price
$531
Updated
2024/03/01
Sigma-Aldrich
Product number
U806
Product name
Undecanoic γ-lactone
Purity
99%
Packaging
100ml
Price
$25.4
Updated
2024/03/01
Sigma-Aldrich
Product number
89985
Product name
γ-Undecalactone
Purity
analytical standard
Packaging
1ml
Price
$73.5
Updated
2022/05/15
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Undecan-4-olide Chemical Properties,Usage,Production

Description

GAMMA-UNDECALACTONE  is a flavoring ingredient. It is industrially important flavor compounds that are widely distributed in foods, fruits, and beverages and are used in many fruity aromatic foods and cosmetics. It is often used in peach, apricot, pear, maple, coconut, tropical, butterscotch, grenadine and date flavors. It is also a volatile flavor constituent found in low-fat ice cream.

References

  1. https://www.sigmaaldrich.com/catalog/product/aldrich/w309109?lang=en&region=US
  2. https://pubchem.ncbi.nlm.nih.gov/compound/Gamma-undecalactone#section=Top
  3. http://www.thegoodscentscompany.com/data/rw1000822.html
  4. An, J. U., Y. C. Joo, and D. K. Oh. "New biotransformation process for production of the fragrant compound γ-dodecalactone from 10-hydroxystearate by permeabilized Waltomyces lipofer cells. " Applied & Environmental Microbiology 79.8(2013): 2636-2641.

Chemical Properties

GAMMA-UNDECALACTONE is clear colourless liquid

Chemical Properties

gamma-Undecalactone has a strong, fruity odor suggestive of peach (particularly on dilution). It has a pungent and sweet flavor also similar to peach.

Occurrence

Reported found in hydrolyzed soy protein, butter, peach, apricot and passion fruit. Also reported found in fresh apple, guava fruit, fresh blackberry, heated butter, heated beef fat, ghee, pork fat, yellow passion fruit juice, cooked scented rice, origanum (Spanish) (Coridothymus cap. (L.) Rchb.), mountain papaya, starfruit, plumcot and chicken fat.

Uses

Traditionally, the bark and leaves of the peach tree have been used as an anthelmintic, an expectorant, an astringent, and a diuretic, as well as to treat insomnia, cough, and constipation. In the 1970s, peach pits (Laetrile) were a popular but unproved treatment for cancer in other countries. Topically, peach is used to treat minor skin disorders such as burns, abrasions, blisters, scratches, eczema, psoriasis, and warts.

Uses

4-Undecanolide is used in the study of primary mutagenicity screening of food additives used in Japan.

Definition

ChEBI: Xi-gamma-Undecalactone is a lactone.

Preparation

By the action of sulfuric acid on undecylenic acid; also prepared starting form castor oil; from octanol-1 plus methylacrylate with di-ter-butylperoxide; from heptylethylene oxide and sodiomalonic ester.

Aroma threshold values

Detection: 60 ppb

Taste threshold values

Taste characteristics at 30 ppm: fatty, coconut, creamy, vanilla, nutty, macadamia and peach.

General Description

γ-Undecalactone is a volatile flavor constituent found in low-fat ice cream.

Flammability and Explosibility

Not classified

Undecan-4-olide Preparation Products And Raw materials

Raw materials

1-Octanol BUTTER Methyl acrylate Undecenoic acid Sodium carbonate

Preparation Products

Vitamin A
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View Lastest Price from Undecan-4-olide manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Undecan-4-olide 104-67-6
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-13
Shandong Deshang Chemical Co., Ltd.
Product
Undecan-4-olide 104-67-6
Price
US $8.00-5.30/kg
Min. Order
1kg
Purity
99.99%
Supply Ability
10 tons
Release date
2024-06-24
Hebei Weibang Biotechnology Co., Ltd
Product
Undecan-4-olide 104-67-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-04

104-67-6, Undecan-4-olideRelated Search:

1-Nonanal BETA-BUTYROLACTONE 2(5H)-Furanone Paraldehyde Tetraheptylammonium bromide ALPHA-HYDROXY-GAMMA-BUTYROLACTONE cyclamen aldehyde TRIOXSALEN 4-Aminobutyric acid Undecan-5-olide Undecanedioic acid Gambier Gamma Butyrolactone Gibberellin A4 4-Dodecanolide Gibberellic acid GIBBERELLIC ACID POTASSIUM SALT Canrenone

  • PEACH ALDEHYDE
  • FEMA 3091
  • GAMMA-UNDECALACTONE
  • GAMMA-UNDECANOLACTONE
  • GAMMA-HEPTYL-GAMMA-BUTYROLACTONE
  • G-N-HEPTYLBUTYROLACTONE
  • G-UNDECALACTONE
  • 1,4-UNDECANOLIDE
  • UNDECALACTONE, GAMMA
  • UNDECAN-4-OLIDE
  • UNDECANOIC GAMMA-LACTONE
  • γ-n-undecalactone
  • G-UNDECALACTONE WITH GC
  • ALDEHYDE C-14, NATURAL
  • Aldehyde C14, Undecanoic γ-lactone
  • γ-Heptyl-γ-butyrolactone, 4,5-Dihydro-5-heptyl-2(3H)-furanone
  • rersicol
  • 5-Heptyl-4,5-dihydro-2(3H)-furanone
  • ^y-Undecanolactone, 99%
  • 4-undecalactone
  • γ-Undecalactone Iso
  • γ-Undecalactone >= 98.0%, Natural-identical, FCC
  • γ-Undecalactone Iso >= 98.0%, Natural, FCC
  • γ-Undecalactone >= 99.0%, Natural, FCC
  • gamma-Undecalactone,98%
  • 5-Heptyl-tetrahydro-2-furanone
  • 5-Heptyl-dihydrofuran-2(3H)-one
  • γ-Undecalactone >=99.0%
  • 4-hydroxyundecan-1-ide
  • gaMMa-Undecalactone, 98% 25ML
  • γ-Undecalactone Iso >= 98.0%,Natural
  • Nature Aldehyde C-14
  • Undecanoic gaMMa-lactone 99%
  • Gamma-Undecalactone/Peach aldehyde
  • <i>γ</i>-Undecanolactone
  • (±)-γ-Undecalactone
  • (R,S)-5-Heptyl-dihydro-furan-2-one
  • (RS)-γ-Undecalactone
  • 1,4-undecanolactone
  • 2(3H)-Furanone,5-heptyldihydro-
  • 4-Hydroxyundecanoic acid lactone
  • 4-Hydroxyundecanoic acid, gamma-lactone
  • 4-hydroxyundecanoicacid,gamma-lactone
  • 4-hydroxyundecanoicacidlactone
  • 4-hydroxy-undecanoicacigamma-lactone
  • 5-Heptylbu-tyrolactone
  • 5-heptyldihydro-2(3h)-furanon
  • 5-Heptyldihydro-2-(3H)-furanone
  • 5-Heptyldihydro-2(3H)-furanone
  • Aldehyde C-14 peach
  • aldehydec-14peach
  • dihydro-5-heptyl-2(3h)-furanone
  • gamma-Heptylbutyrolactone
  • gamma-n-Heptylbutyrolactone
  • gamma-Undecalatone
  • gamma-Undecanolide
  • gamma-Undekalakton
  • Peach lactone