TERT-BUTYL-2-BROMOBENZOATE
- Product Name
- TERT-BUTYL-2-BROMOBENZOATE
- CAS No.
- 55666-42-7
- Chemical Name
- TERT-BUTYL-2-BROMOBENZOATE
- Synonyms
- TERT-BUTYL-2-BROMOBENZOATE;2-BROMO-BENZOIC ACID TERT-BUTYL ESTER;Benzoic acid, 2-bromo-, 1,1-dimethylethyl ester
- CBNumber
- CB0401922
- Molecular Formula
- C11H13BrO2
- Formula Weight
- 257.12
- MOL File
- 55666-42-7.mol
TERT-BUTYL-2-BROMOBENZOATE Property
- Boiling point:
- 280.3±13.0 °C(Predicted)
- Density
- 1.331±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- Colorless to light yellow Liquid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B789290
- Product name
- tert-Butyl2-Bromobenzoate
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- J96520
- Product name
- tert-Butyl2-bromobenzoate
- Packaging
- 5g
- Price
- $80
- Updated
- 2021/12/16
- Product number
- HCH0027223
- Product name
- TERT-BUTYL-2-BROMOBENZOATE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $685.21
- Updated
- 2021/12/16
- Product number
- HCH0027223
- Product name
- TERT-BUTYL-2-BROMOBENZOATE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $1103.6
- Updated
- 2021/12/16
- Product number
- A252201
- Product name
- tert-Butyl2-bromobenzoate
- Purity
- 97%
- Packaging
- 1g
- Price
- $23
- Updated
- 2021/12/16
TERT-BUTYL-2-BROMOBENZOATE Chemical Properties,Usage,Production
Synthesis
7154-66-7
75-65-0
55666-42-7
Example 64: Synthesis of tert-butyl 2-bromobenzoate Step A. To a solution of 2-bromobenzoyl chloride (2.0 g, 9.11 mmol) in anhydrous ethyl ether (40 mL) was added sequentially tert-butanol (0.96 mL, 10.02 mmol) and 4-(dimethylamino)pyridine (111 mg, 0.91 mmol). The reaction mixture was stirred at room temperature for 48 hours under nitrogen protection. After completion of the reaction, the resulting white suspension was extracted by partitioning with ethyl acetate (100 mL) and 1 M hydrochloric acid (100 mL). The organic phase was separated and washed sequentially with 1 M hydrochloric acid (100 mL), 2 M sodium hydroxide (2 x 100 mL), water (100 mL) and saturated saline (100 mL). The organic phase was dried with anhydrous magnesium sulfate and concentrated under reduced pressure to give a yellow oil. Purification by fast column chromatography with ethyl acetate/hexane as eluent gave tert-butyl 2-bromobenzoate (1.22 g, 52% yield) as a colorless oil.
References
[1] Organic Letters, 2011, vol. 13, # 19, p. 5326 - 5329
[2] Patent: US2006/287522, 2006, A1. Location in patent: Page/Page column 41
TERT-BUTYL-2-BROMOBENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
TERT-BUTYL-2-BROMOBENZOATE Suppliers
- Tel
- --
- Fax
- --
- info@specs.net
- Country
- The Netherlands
- ProdList
- 6833
- Advantage
- 70