9-BROMO-9-BORABICYCLO[3.3.1]NONANE Property

Boiling point:

54-59 °C(Press: 0.3-0.4 Torr)

Density 

1.315 g/mL at 25 °C

Flash point:

-17 °C

solubility 

sol pentane, CH2Cl2; dec ethers, alcohols

Safety

Hazard Codes 

F,C,Xn

Risk Statements 

17-23/24/25-34-40-67-36/37/38

Safety Statements 

16-26-36/37/39-45-36/37

RIDADR 

UN 2845 4.2/PG 1

WGK Germany 

3

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

H351Suspected of causing cancer

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P281Use personal protective equipment as required.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

9-BROMO-9-BORABICYCLO[3.3.1]NONANE Chemical Properties,Usage,Production

Uses

9-BROMO-9-BORABICYCLO[3.3.1]NONANE is a selective reagent for the cleavage of ethers and deoxygenation of sulfoxides; adds regioselectively and stereoselectively to terminal alkynes; undergoes conjugate addition to α,β-unsaturated ketones; converts vinyltins to vinylboranes.

storage

9-BROMO-9-BORABICYCLO[3.3.1]NONANE is pyrophoric and reacts violently with moisture and protic solvents. Individuals should thoroughly familiarize themselves with the special handling techniques required for such reagents prior to use. Use in a well-ventilated fume hood.