ChemicalBook > CAS DataBase List > 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone
2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone
- Product Name
- 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone
- CAS No.
- 119313-12-1
- Chemical Name
- 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone
- Synonyms
- 369;Irgacure 369;Photoinitiator369;UV-369;IHT-PI 910;Photoinitiator 910;N,N-Dimethyl-α-ethyl-α-benzyl-β-oxo-4-(4-morpholinyl)benzeneethanamine;IC-369;APi-369;YF-PI 369
- CBNumber
- CB0412472
- Molecular Formula
- C23H30N2O2
- Formula Weight
- 366.5
- MOL File
- 119313-12-1.mol
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2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone Property
- Melting point:
- 116-119 °C (lit.)
- Boiling point:
- 528.8±50.0 °C(Predicted)
- Density
- 1.094±0.06 g/cm3(Predicted)
- vapor pressure
- 0-0.01Pa at 25-95℃
- Flash point:
- >230 °F
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- 3240 in mg/100g standard fat at 20 ℃
- form
- powder to crystal
- pka
- 7.04±0.50(Predicted)
- color
- Light orange to Yellow to Green
- Water Solubility
- 5.9mg/L at 20℃
- InChIKey
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N
- LogP
- 2.91 at 25℃
- CAS DataBase Reference
- 119313-12-1(CAS DataBase Reference)
- EPA Substance Registry System
- 1-Butanone, 2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)- (119313-12-1)
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313IF exposed or concerned: Get medical advice/attention.
P391Collect spillage. Hazardous to the aquatic environment
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 405647
- Product name
- 2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone
- Purity
- 97%
- Packaging
- 25g
- Price
- $80.1
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- 405647
- Product name
- 2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone
- Purity
- 97%
- Packaging
- 100g
- Price
- $227.05
- Updated
- 2025/07/31
TCI Chemical
- Product number
- B3914
- Product name
- 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 25g
- Price
- $49
- Updated
- 2025/07/31
TCI Chemical
- Product number
- B3914
- Product name
- 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 100g
- Price
- $156
- Updated
- 2025/07/31
Biosynth Carbosynth
- Product number
- FB63048
- Product name
- 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone
- Packaging
- 50g
- Price
- $200
- Updated
- 2021/12/16
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2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone Chemical Properties,Usage,Production
Chemical Properties
Light yellow solid
Uses
DBMP can be used as a dopant to dope silicone elastomer for the formation of 3D biocompatible scaffolds. It can also be used in two photon polymerization for the micro-fabrication of 3D hydrogels for potential biomedical and tissue engineering applications.
Uses
UV solidify ink and coating
General Description
2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone (DBMP) is a photoinitiator that acts at near UV and visible range. It can be incorporated into the polymeric matrix, which upon UV irradiation forms radicals by radical chain polymerization.
Synthesis
110-91-8
119312-61-7
119313-12-1
General procedure for the synthesis of 2-benzyl-2-dimethylamino-1-P-fluorophenyl-1-butanone from 2-benzyl-2-dimethylamino-1-P-fluorophenyl-1-butanone and morpholine: 2-benzyl-2-dimethylamino-1-P-fluorophenyl-1-butanone was dissolved in ethylene dichloride and transferred to a four-necked flask. Morpholine (139.6 g, 1.6 mol) and 1 L of dichloroethane were added and the reaction was heated to reflux state. The reaction progress was monitored by TLC or high performance liquid chromatography (HPLC). After completion of the reaction, the reaction was cooled to room temperature, the reaction mixture was washed by adding 200 ml of water and stirred for 30 min. After standing and layering, the organic phase was separated. The solvent was recovered by distillation under reduced pressure to obtain the crude product. The crude product was recrystallized from 440 ml of ethanol to give 117.2 g of a light yellow solid product with a melting point of 115-116 °C, an overall yield of 80% and a purity of 99.3%.
References
[1] Patent: CN105384707, 2016, A. Location in patent: Paragraph 0003; 0034
2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone Preparation Products And Raw materials
Raw materials
Acetonitrile
Nitrogen
Fluorobenzene
Potassium carbonate
Aluminum chloride
Butyryl chloride
Benzyl bromide
Hydrogen bromide
Diethyl ether
Bromine
Acetic acid
Dimethyl sulfoxide
Sodium hydroxide
Dimethylamine
Magnesium sulfate
Morpholine
Preparation Products
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View Lastest Price from 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone manufacturers
WUHAN FORTUNA CHEMICAL CO., LTD
- Product
- Photoinitiator 369 119313-12-1
- Price
- US $0.00/KG/CTN
- Min. Order
- 20KG
- Purity
- 99%min
- Supply Ability
- 30tons/month
- Release date
- 2021-06-09
Hebei Zhuanglai Chemical Trading Co Ltd
- Product
- Photoinitiator 369 119313-12-1
- Price
- US $150.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 500kg
- Release date
- 2024-12-02
Wuhan Fortuna Chemical Co.,Ltd
- Product
- 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone 119313-12-1
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20tons
- Release date
- 2024-08-14
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