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Phenazopyridine hydrochloride

Product Name
Phenazopyridine hydrochloride
CAS No.
136-40-3
Chemical Name
Phenazopyridine hydrochloride
Synonyms
nc150;pirid;sedural;pyrizin;urazium;uriplex;URODINE;azodyne;dolonil;giracid
CBNumber
CB0415453
Molecular Formula
C11H12ClN5
Formula Weight
249.7
MOL File
136-40-3.mol
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Phenazopyridine hydrochloride Property

Melting point:
139°C
Boiling point:
394.6°C (rough estimate)
Density 
1.2645 (rough estimate)
refractive index 
1.6110 (estimate)
storage temp. 
Sealed in dry,2-8°C
solubility 
DMSO (Slightly, Heated), Methanol (Slightly, Heated)
form 
Liquid
color 
Clear to hazy colorless to yellow
Water Solubility 
0.01-0.1 g/100 mL at 20 ºC
Merck 
14,7210
Stability:
Light Sensitive
InChIKey
QQBPIHBUCMDKFG-GEEYTBSJSA-N
CAS DataBase Reference
136-40-3(CAS DataBase Reference)
IARC
2B (Vol. 24, Sup 7) 1987
EPA Substance Registry System
Phenazopyridine hydrochloride (136-40-3)
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Safety

Hazard Codes 
Xn,C
Risk Statements 
22-36/37/38-40-34-42/43
Safety Statements 
26-36/37-45-36/37/39-27-22
RIDADR 
2811
WGK Germany 
3
RTECS 
US7875000
HS Code 
29333990
Toxicity
LD50 orally in rats: 403 mg/kg (Becker, Swift)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
PHR3220
Product name
Phenazopyridine Hydrochloride
Purity
pharmaceutical secondary standard, certified reference material
Packaging
500MG
Price
$173
Updated
2024/03/01
Sigma-Aldrich
Product number
34076
Product name
Phenazopyridine hydrochloride
Purity
VETRANAL
Packaging
100mg
Price
$113
Updated
2024/03/01
Sigma-Aldrich
Product number
1515000
Product name
Phenazopyridine hydrochloride
Purity
United States Pharmacopeia (USP) Reference Standard
Packaging
200mg
Price
$453
Updated
2024/03/01
TCI Chemical
Product number
B0022
Product name
3-Phenylazo-2,6-diaminopyridine Monohydrochloride
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$104
Updated
2024/03/01
Alfa Aesar
Product number
B21886
Product name
3-Phenylazo-2,6-diaminopyridine hydrochloride, 98+%
Packaging
5g
Price
$70.65
Updated
2024/03/01
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Phenazopyridine hydrochloride Chemical Properties,Usage,Production

Description

Phenazopyridine is an azo dye with analgesic properties. It decreases the bladder distension-induced firing rate of afferent bladder Aγ-fibers, but not C-fibers, in anesthetized rats when administered at a doses of 0.3, 1, and 3 mg/kg. Formulations containing phenazopyridine have been used as analgesics in the treatment of urinary tract infections.

Chemical Properties

Brick-Red Crystals

Originator

Phenazopyridine ,AroKor Holdings Inc.

Uses

Phenazopyridine hydrochloride has been used for 50 years as an analgesic drug either alone or in combination with other drugs to reduce pain associated with urinary tract infection. An azo dye used in urinary tract infections. Also used as a local anesthetic. Exposure to phenazopyridine hydrochloride occurs during manufacture and formulation.

Uses

An azo dye used in treatment of urinary tract infections. Used as an analgesic (urinary tract).

Uses

anticonvulsant, antieleptic

Uses

therapeutic for urinary tract infections

Definition

ChEBI: A hydrochloride obtained by combining phenazopyridine with one equivalent of hydrochloric acid. A local anesthetic that has topical analgesic effect on mucosa lining of the urinary tract. Its use is limited by problems with toxicity (primarily blood disord rs) and potential carcinogenicity.

Manufacturing Process

Phenyldiazene chloride reacted with 2,6-diaminopyridine and in the result 2,6diamino-3-(phenylazo)pyridine was obtained.
In practice it is usually used as monohydrochloride.

brand name

Pyridium (Parke-Davis).

Therapeutic Function

Urinary analgesic, Antiseptic, Diagnostic aid

General Description

Brick-red microcrystals with a slight violet luster or a purple powder. Aqueous solutions are yellow to brick-red and slightly acidic; they may be stabilized by the addition of 10% glucose. Slightly bitter taste.

Air & Water Reactions

Dust can be explosive when suspended in air at specific concentrations. Phenazopyridine hydrochloride may be sensitive to air and light. . Very slightly water soluble.

Reactivity Profile

Phenazopyridine hydrochloride is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.

Fire Hazard

Flash point data for Phenazopyridine hydrochloride are not available. Phenazopyridine hydrochloride is probably combustible.

Clinical Use

Phenazopyridine hydrochloride, 2,6-diamino-3-(phenylazopyridinehydrochloride (Pyridium), is a brick-red, finecrystalline powder. It is slightly soluble in alcohol, in chloroform,and in water.Phenazopyridine hydrochloride was formerly used asa urinary antiseptic. Although it is active in vitro againststaphylococci, streptococci, gonococci, and E. coli, it has nouseful antibacterial activity in the urine. Thus, its presentutility lies in its local analgesic effect on the mucosa of theurinary tract.
Usually, phenazopyridine is given in combination withurinary antiseptics. For example, it is available as Azo-Gantrisin, a fixed-dose combination with the sulfonamide antibacterialsulfisoxazole, and as Urobiotic, a combination withthe antibiotic oxytetracycline and the sulfonamide sulfamethizole. The drug is rapidly excreted in the urine, towhich it gives an orange-red color. Stains in fabrics may beremoved by soaking in a 0.25% solution of sodium dithionite.

Safety Profile

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. A poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion. Human systemic effects by ingestion: somnolence, cyanosis, dlarrhea, nausea or vomiting, anuria or decreased urine volume, normocytic anemia, methemoglobinemiacarboxyhemoglobinemia, dehydration, changes in blood sodium levels. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx and HCl

Carcinogenicity

Phenazopyridine hydrochloride is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity fromstudies in experimental animals.

Phenazopyridine hydrochloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Phenazopyridine hydrochloride Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10186
Advantage
62
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14103
Advantage
59
LGM Pharma
Tel
1-(800)-881-8210
Fax
615-250-9817
Email
inquiries@lgmpharma.com
Country
United States
ProdList
2123
Advantage
70
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View Lastest Price from Phenazopyridine hydrochloride manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Phenazopyridine hydrochloride 136-40-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500kg/month
Release date
2021-07-23
Baoji Guokang Bio-Technology Co., Ltd.
Product
Phenazopyridine hydrochloride 136-40-3
Price
US $161.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000kg
Release date
2021-06-04
Zhuozhou Wenxi import and Export Co., Ltd
Product
Phenazopyridine hydrochloride 136-40-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

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