1-(Benzyloxy)-2-methyl-3-nitrobenzene

Product Name: 1-(Benzyloxy)-2-methyl-3-nitrobenzene
CAS No.: 20876-37-3
Chemical Name: 1-(Benzyloxy)-2-methyl-3-nitrobenzene
Synonyms: O2NC6H3(CH3)OCH2C6H5;6-benzyloxy-2-nitrotoluene;2-BENZYLOXY-6-NITROTOLUENE;BENZYL 3-NITRO-O-TOLYL ETHER;1-BENZYLOXY-2-METHYL-3-NITROBENZENE;3-NITRO-2-METHYL PHENOL BENZYL ETHER;2-methyl-1-nitro-3-phenylmethoxybenzene;1-methyl-3-nitro-2-phenylmethoxybenzene;Benzene, 2-Methyl-1-nitro-3-(phenylMethoxy)-;1-(Benzyloxy)-2-methyl-3-nitrobenzene ISO 9001：2015 REACH
CBNumber: CB0458805
Molecular Formula: C14H13NO3
Formula Weight: 243.26
MOL File: 20876-37-3.mol

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1-(Benzyloxy)-2-methyl-3-nitrobenzene Property

Melting point:: 60-63 °C (lit.)
Boiling point:: 170-176 °C(Press: 0.8 Torr)
Density: 1.202±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: Powder
color: Yellow to pale brown
CAS DataBase Reference: 20876-37-3(CAS DataBase Reference)

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Safety

Safety Statements: 24/25
WGK Germany: 3
HS Code: 29093090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 496804
Product name: 1-Benzyloxy-2-methyl-3-nitrobenzene
Purity: 98%
Packaging: 5g
Price: $185
Updated: 2023/01/07

TRC

Product number: B411030
Product name: 1-Benzyloxy-2-methyl-3-nitrobenzene
Packaging: 50mg
Price: $45
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB71045
Product name: 2-Benzyloxy-6-nitrotoluene
Packaging: 10g
Price: $57.5
Updated: 2021/12/16

Matrix Scientific

Product number: 074115
Product name: 1-Benzyloxy-2-methyl-3-nitrobenzene
Purity: 95+%
Packaging: 1g
Price: $59
Updated: 2021/12/16

Matrix Scientific

Product number: 074115
Product name: 1-Benzyloxy-2-methyl-3-nitrobenzene
Purity: 95+%
Packaging: 10g
Price: $234
Updated: 2021/12/16

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1-(Benzyloxy)-2-methyl-3-nitrobenzene Chemical Properties,Usage,Production

General Description

1-Benzyloxy-2-methyl-3-nitrobenzene may be used in the preparation of 1-[2-[2-(benzyloxy)-6-nitrophenyl]vinyl]pyrrolidine and 4-(benzyloxy)-1H-indole.

Synthesis

5460-31-1

100-39-0

20876-37-3

General procedure: 41.5 g (300 mmol) of potassium carbonate and 200 mL of N,N-dimethylformamide were added to a reaction vial containing 30.6 g (200 mmol) of 2-methyl-3-nitrophenol. Under argon protection, 23.8 mL (200 mmol) of benzyl bromide was slowly added dropwise to the reaction system and the reaction was stirred at room temperature for 3 hours. Upon completion of the reaction, the reaction solution was poured into 1000 mL of water, extracted with 800 mL of toluene and the extraction was repeated once (500 mL of toluene). The organic phases were combined, washed sequentially with water and saturated aqueous sodium chloride, and dried over anhydrous magnesium sulfate. The organic phase was concentrated under reduced pressure to give 49.3 g of yellow powdered 1-benzyloxy-2-methyl-3-nitrobenzene in quantitative yield. rf value: 0.48 (unfolding reagent: n-hexane/ethyl acetate=4:1, v/v). Mass spectrum (CI, m/z): 244 [M+1]+. 1H-NMR (CDCl3, δ ppm): 2.42 (s, 3H), 5.13 (s, 2H), 7.08-7.11 (m, 1H), 7.21-7.27 (m, 1H), 7.32-7.44 (m, 6H).

References

[1] Patent: US2009/12123, 2009, A1. Location in patent: Page/Page column 9-10
[2] Patent: WO2005/117909, 2005, A2. Location in patent: Page/Page column 119
[3] Journal of the Chemical Society, 1948, p. 1605,1608
[4] Heterocycles, 1981, vol. 16, # 7, p. 1119 - 1124
[5] Patent: EP1870099, 2007, A1. Location in patent: Page/Page column 14

1-(Benzyloxy)-2-methyl-3-nitrobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1-(Benzyloxy)-2-methyl-3-nitrobenzene Suppliers

China 91 Europe 2 France 1 Germany 1 India 2 Switzerland 1 United Kingdom 6 United States 12 Global 116

Alchem Pharmtech,Inc.

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View Lastest Price from 1-(Benzyloxy)-2-methyl-3-nitrobenzene manufacturers

Henan Fengda Chemical Co., Ltd

Product: 1-(Benzyloxy)-2-methyl-3-nitrobenzene 20876-37-3
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-26

Zhuozhou Wenxi import and Export Co., Ltd

Product: 1-(Benzyloxy)-2-methyl-3-nitrobenzene 20876-37-3
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: 1-(Benzyloxy)-2-methyl-3-nitrobenzene 20876-37-3
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

20876-37-3, 1-(Benzyloxy)-2-methyl-3-nitrobenzeneRelated Search:

Methylparaben Phenethyl alcohol Ethoxymethylenemalononitrile 2-Methyl-3-nitrophenol Benzyl ether 4-Methoxybenzylchloride 4-Nitrobenzyl alcohol Methyl acrylate Methyltrimethoxysilane Triton X-100 2-CHLOROTHIOPHENOL Bensulfuron methyl Chlorodimethylphenylsilane Methyl acetate Dimethyldimethoxysilane Methyltriethoxysilane 2-Methyl-3-nitro-benzeneacetic acid Thiophanate-methyl

O2NC6H3(CH3)OCH2C6H5

2-BENZYLOXY-6-NITROTOLUENE

1-BENZYLOXY-2-METHYL-3-NITROBENZENE

3-NITRO-2-METHYL PHENOL BENZYL ETHER

BENZYL 3-NITRO-O-TOLYL ETHER

Benzene, 2-Methyl-1-nitro-3-(phenylMethoxy)-

1-methyl-3-nitro-2-phenylmethoxybenzene

2-methyl-1-nitro-3-phenylmethoxybenzene

1-(Benzyloxy)-2-methyl-3-nitrobenzene ISO 9001：2015 REACH

6-benzyloxy-2-nitrotoluene

20876-37-3

C6H5CH2OC6H3CH3NO2

C14H13NO3

Building Blocks

Nitro Compounds

Nitrogen Compounds

Organic Building Blocks

Anilines, Aromatic Amines and Nitro Compounds