2-Furanboronic acid

Product Name: 2-Furanboronic acid
CAS No.: 13331-23-2
Chemical Name: 2-Furanboronic acid
Synonyms: furan-2-ylboronic acid;2-FURYLBORONIC ACID;FURAN-2-BORONIC ACID;AKOS 90301;Furan-2-acid;2-furan acid;AKOS BRN-0264;2-Boronofuran;2-Furanboronicaci;2-FURANBORONIC ACID
CBNumber: CB0474272
Molecular Formula: C4H5BO3
Formula Weight: 111.89
MOL File: 13331-23-2.mol

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2-Furanboronic acid Property

Melting point:: 112 °C (dec.) (lit.)
Boiling point:: 247.7±32.0 °C(Predicted)
Density: 1.25±0.1 g/cm3(Predicted)
storage temp.: 2-8°C
solubility: Chloroform (Slightly, Sonicated), DMSO (Slightly)
pka: 8.29±0.53(Predicted)
form: Crystalline Powder
color: Light beige
Water Solubility: Slightly soluble in water.
Sensitive: Air Sensitive
BRN: 112370
InChI: InChI=1S/C4H5BO3/c6-5(7)4-2-1-3-8-4/h1-3,6-7H
InChIKey: PZJSZBJLOWMDRG-UHFFFAOYSA-N
SMILES: O1C=CC=C1B(O)O
CAS DataBase Reference: 13331-23-2(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39-3
WGK Germany: 3
Hazard Note: Irritant
HazardClass: IRRITANT, AIR SENSITIVE, KEEP COLD
HS Code: 29321900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 464910
Product name: 2-Furanylboronic acid
Purity: ≥95.0%
Packaging: 1g
Price: $101
Updated: 2025/07/31

Sigma-Aldrich

Product number: 464910
Product name: 2-Furanylboronic acid
Purity: ≥95.0%
Packaging: 10g
Price: $321.2
Updated: 2024/03/01

TCI Chemical

Product number: F0394
Product name: 2-Furylboronic Acid (contains varying amounts of Anhydride)
Packaging: 1g
Price: $25
Updated: 2025/07/31

TCI Chemical

Product number: F0394
Product name: 2-Furylboronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $83
Updated: 2025/07/31

Usbiological

Product number: 276064
Product name: Furan-2-boronic acid
Packaging: 10g
Price: $366
Updated: 2021/12/16

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2-Furanboronic acid Chemical Properties,Usage,Production

Chemical Properties

light beige crystalline powder

Uses

It is used in Suzuki reaction for generalized route for the synthesis of β-furyl-α,β-unsaturated aldehydes.

Synthesis

1104637-62-8

13331-23-2

The general procedure for the synthesis of 2-furanboronic acid from 2-(furan-2-yl)-6-methyl-1,3,6,2-dioxaborolane-4,8-dione was as follows: a solution of MIDA borate (5 mmol) in THF (50 mL) was added to a 100 mL flask fitted with a stir bar under an ambient atmosphere followed by the addition of an aqueous 1.0 M NaOH solution (15 mL ). The reaction mixture was stirred vigorously for 20 minutes. Upon completion, the mixture was transferred to a partition funnel and diluted with ether (50 mL) and 0.5 M pH 7 sodium phosphate buffer (50 mL). The phases were separated after sufficient shaking. The aqueous phase was extracted with a solvent mixture of THF/ether (1:1, 2 x 25 mL). The organic phases were combined, dried with anhydrous MgSO4, filtered and concentrated in vacuum. The residual solvent was co-evaporated with acetonitrile and the resulting solid was dried under vacuum at about 1 Torr for 30 min. The resulting boric acid was analyzed by 1H-NMR to be >95% pure and was immediately used in the subsequent cross coupling reaction. Specific examples are as follows: 2-furanboronic acid (0.531 g, 95% yield) was obtained as an off-white solid using MIDA borate (1.127 g, 5.002 mmol) following the general procedure described above.TLC (unfolding reagent: ethyl acetate) Rf = 0.46, stained with potassium permanganate to develop color.1H-NMR (500 MHz, DMSO-d6:D2O 1H-NMR (500 MHz, DMSO-d6:D2O 95:5, with TMS) δ 7.81 (dd, J = 1.5, 5.5 Hz, 1H), 7.07 (dd, J = 3.0, 0.5 Hz, 1H), 6.48 (dd, J = 3.5, 2.0 Hz, 1H). 13C-NMR (125 MHz, DMSO-d6:D2O 95:5, with TMS) δ 146.4, 121.5, 110.3. 121.5, 110.3. HRMS (EI+) calculated value C4H3O3B [M]+: 112.0332, measured value: 112.0332.

References

[1] Journal of the American Chemical Society, 2009, vol. 131, p. 6961 - 6963
[2] Patent: WO2010/36921, 2010, A2. Location in patent: Page/Page column 41

2-Furanboronic acid Preparation Products And Raw materials

Raw materials

Nitrogen Triethyl borate 2-Chlorofuran Tetrahydrofuran Magnesium

Preparation Products

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2-Furanboronic acid Suppliers

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View Lastest Price from 2-Furanboronic acid manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 2-Furanboronic acid 13331-23-2
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5tons
Release date: 2024-12-02

Honest Joy Holdings Limited

Product: Furan-2-boronic acid 13331-23-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 97.7%
Supply Ability: 100 tons
Release date: 2022-01-25

Zhuozhou Wenxi import and Export Co., Ltd

Product: 2-Furanboronic acid 13331-23-2
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

13331-23-2, 2-Furanboronic acidRelated Search:

Furan Nitrofurantoin Ethyl 2-(Chlorosulfonyl)acetate FURAN-2-BORONIC ACID PINACOL ESTER,FURAN-2-BORONIC ACID PINACOL CYCLIC ESTER,2-Furanboronic acid pinacol ester Tetrahydrofuran Zinc borate Furazolidone FURFURYL ALCOHOL RESIN 3-FURANBORONIC ACID,FURAN-3-BORONIC ACID,FURAN-3-BORONIC ACID 97%,Furan-3-boronic acid, 98+% Folic acid FURAN-3-BORONIC ACID PINACOL ESTER,3-FURANBORONIC ACID, PINACOL ESTER 3-FURONITRILE (furan-3-yl)(phenyl)methanamine hydrochloride Carbamic acid, 3-furanyl-, 1,1-dimethylethyl ester (9CI) 2,3-Dihydro-2,2-dimethyl-7-benzofuranol Citric acid Boric acid Ethyl 3-furancarboxylate

FURAN-2-BORONIC ACID

2-Furaneboronicacid

Furane-2-boronicacid

RARECHEM AH PB 0259

TIMTEC-BB SBB004326

AKOS 90301

AKOS BRN-0264

2-FURYLBORONIC ACID

2-FURANBORONIC ACID

2-FURANYLBORONIC ACID

Furan-2-boronic acid, 2-furylboronic acid

FURAN-2-BORONIC ACID, 2-FURANBORONIC ACID, 2-FURYLBORONIC ACID

furan-2-ylboronic acid

(2-Furyl)boranediol

(2-Furyl)dihydroxyborane

Dihydroxy(2-furanyl)borane

Furan-2-boronic acid,97%

2-Furylboronic Acid (contains varying amounts of Anhydride)

Furan-2-acid

Furan-2-boronic Acid 2-Furanylboronic Acid

Boronic acid, B-2-furanyl-

2-Furanboronicacid (7CI,8CI)

2-FURANBORONICACID (7CI,8CI);BORONIC ACID, 2-FURANYL- (9CI);

Boronic acid, 2-furanyl- (9CI)

2-Boronofuran

2-Furanylboronic acid >=95.0%

2-furan acid

(5-Furanyl)boronic acid

dihydroxy-(furan-2-yl)-borane

Furan-2-boronic acid 98%

2-Furanboronicaci

2-Furanboronic acid 13331-23-2

fur-2-ylboronic acid

Furan-2-boronic acid - [F3580]

13331-23-2

1331-23-2

C14H18BNO3

C4H9O3B

C19H25BO3

C17H21BO3

C17H14BClO3

C18H23BO3

C9H11BBrFO3

C11H17BO4

C4H5BO3

Organometallic Reagents

Heteroaryl

Boronic Acids

B (Classes of Boron Compounds)

Boronic Acids and Derivatives

Boric Acid| Boric Acid Ester| Potassium Trifluoroborate

IndolesOxindoles

blocks

BoronicAcids

Heterocycles

Boronic acids

Boronic Acid

Furan