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Azathramycin

Product Name
Azathramycin
CAS No.
76801-85-9
Chemical Name
Azathramycin
Synonyms
Azithromycin Amine;DESMETHYL AZITHROMYCIN;Desmethyl;Azaerythromycin A;Azithromycin Impurity P;Azithromycin A;9-DEOXO-9A-AZA-9A-HEMOERYTHROMYCIN;Azathramycin;Azathramycin A;Azaerthromycin A
CBNumber
CB0501390
Molecular Formula
C37H70N2O12
Formula Weight
734.96
MOL File
76801-85-9.mol
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Azathramycin Property

Melting point:
126-136°C
Boiling point:
815.2±65.0 °C(Predicted)
Density 
1.18
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
pka
13.29±0.70(Predicted)
form 
Solid
color 
White to Off-White
Stability:
Hygroscopic
InChI
InChI=1/C37H70N2O12/c1-14-26-37(10,45)30(41)23(6)38-18-19(2)16-35(8,44)32(51-34-28(40)25(39(11)12)15-20(3)47-34)21(4)29(22(5)33(43)49-26)50-27-17-36(9,46-13)31(42)24(7)48-27/h19-32,34,38,40-42,44-45H,14-18H2,1-13H3/t19-,20-,21+,22-,23-,24+,25+,26-,27+,28-,29+,30-,31+,32-,34+,35-,36-,37-/s3
InChIKey
HRKNNHYKWGYTEN-HOQMJRDDSA-N
SMILES
[C@H]1(O[C@H](C)C[C@H](N(C)C)[C@H]1O)O[C@@]1([H])[C@](C)(O)C[C@@H](C)CN[C@H](C)[C@@H](O)[C@](C)(O)[C@@H](CC)OC(=O)[C@H](C)[C@@]([H])(O[C@@H]2O[C@@H](C)[C@H](O)[C@](C)(OC)C2)[C@@H]1C |&1:0,2,5,9,12,14,18,22,24,26,29,35,37,40,42,44,46,51,r|
LogP
3.11
CAS DataBase Reference
76801-85-9
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Safety

HS Code 
2934990002
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
PHR2780
Product name
Azaerythromycin A
Purity
Pharmaceutical Secondary Standard; Certified Reference Material, certified reference material, pharmaceutical secondary standard, pkg of 200?mg
Packaging
200MG
Price
$494.95
Updated
2025/07/31
Sigma-Aldrich
Product number
1045600
Product name
Azaerythromycin A
Packaging
100mg
Price
$1360
Updated
2025/07/31
TRC
Product number
D231500
Product name
9-Deoxo-9a-aza-9a-homoErythromycinA(DesmethylAzithromycin)
Packaging
1g
Price
$425
Updated
2021/12/16
TRC
Product number
D231500
Product name
9-Deoxo-9a-aza-9a-homoErythromycinA(DesmethylAzithromycin)
Packaging
100mg
Price
$125
Updated
2021/12/16
Usbiological
Product number
257268
Product name
9-Deoxo-9a-aza-9a-homo erythromycin A
Packaging
25g
Price
$326
Updated
2021/12/16
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Azathramycin Chemical Properties,Usage,Production

Chemical Properties

White Solid

Uses

9-Deoxo-9a-aza-9a-homo Erythromycin A (Azithromycin EP Impurity A) is a novel intermediate of Azithromycin that acts as antibiotic.

Synthesis

342371-84-0

76801-85-9

Example-2; [93] [94] Preparation of 9-deoxy-9a-azo-9a-homoerythromycin A; Acetic acid was added dropwise to a methanolic (700 mL) suspension of 6,9-imino ether (II) (70.0 g), and the pH was adjusted to 5-6. Subsequently, an aqueous solution of PtO2 (7.0 g) was added to the above mixture and the reaction was carried out under a hydrogen pressure of 8-9 kg/cm2 and a temperature of 40-45°C for 4-5 hours for the hydrogenation reduction reaction. After completion of the reaction, the reaction mixture was filtered through Hyflo Super Cel and the filter cake was washed with methanol. The filtrates were combined and the methanol was removed by distillation under reduced pressure. To the residue, deionized water (700 mL) was added and the pH was adjusted to 11-12 with aqueous sodium hydroxide.The precipitated solid was filtered, drained, and dried in an oven to afford 9-deoxy-9a-azo-9a- homoerythromycin A(III) (55.0 g) in 85% yield.

References

[1] Patent: WO2009/156938, 2009, A2. Location in patent: Page/Page column 8
[2] Patent: CN106632543, 2017, A. Location in patent: Paragraph 0003; 0025-0026
[3] Organic and Biomolecular Chemistry, 2008, vol. 6, # 22, p. 4120 - 4124
[4] Patent: CN106478541, 2017, A. Location in patent: Paragraph 0022; 0047

Azathramycin Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Azathramycin manufacturers

Hefei Lbao Physical & Chemical Science Co.,Ltd
Product
Azathramycin 76801-85-9
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
Customise
Release date
2025-11-20
RongNa Biotechnology Co.,Ltd
Product
Azathramycin 76801-85-9
Price
US $1.00/g
Min. Order
1g
Purity
0.99
Supply Ability
20 tons
Release date
2025-06-02
Shaanxi Dideu New Materials Co. Ltd
Product
Azathramycin 76801-85-9
Price
US $0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-05-07

76801-85-9, AzathramycinRelated Search:

AZITHROMYCIN IMPURITY B Lexithromycin Azithromycin aspartate water-soluble azithromycin 70% Tulathromycin A Azithromycin dihydrate Erythromycin AZITHROMYCIN IMPURITY A THIOXANTHENE Azithromycin Monohydrate ERYTHROMYCIN LACTOBIONATE (200 MG) 2-Desethyl-2-propylazithromycin DesosaMinylazithroMycin 2-(2H-Benzotriazol-2-yl)-p-cresol beta-D-Desosamine 3'-N,N-Di(desMethyl)-3'-N-forMyl AzithroMycin 9a-aza-9a-homo Erythromycin A AZITHROMYCIN-D3

  • Azithromycin EP Impurity A/(2R,3S,4R,5R,8R,10R,11R,12S,13S,14R)-11-(((2S,3R,4S,6R)-4-(dimethylamino)-3-hydroxy-6-methyltetrahydro-2H-pyran-2-yl)oxy)-2-ethyl-3,4,10-trihydroxy-13-(((2R,4R,5S,6S)-5-hydroxy-4-methoxy-4,6-dimethyltetrahydro-2H-pyran-2-yl)oxy)
  • (2R,3S,4R,5R,8R,10R,11R,12S,13S,14R)-11-[(2S,3R,4S,6R)-4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy-2-ethyl-3,4,10-trihydroxy-13-[(2R,4R,5S,6S)-5-hydroxy-4-methoxy-4,6-dimethyloxan-2-yl]oxy-3,5,8,10,12,14-hexamethyl-1-oxa-6-azacyclopentadecan-15-one
  • Azithromycin Impurity P
  • Azathramycin (Azaerythromycin A
  • Azithromycin EP Impurity A (Azathramycin) (Desmethyl Azithromycin)
  • AZAERYTHROMYCIN A;DESMETHYL AZITHROMYCIN
  • Azithromycin Impurity 1（Azithromycin EP Impurity A）
  • DD-Azaerythromycin A
  • Desmethylazythromicin
  • 9-Deoxo-9a-aza-9a-homo Erythromycin A Desmethyl Azithromycin
  • AzithroMycin InterMediates
  • 9-DEOXO-9A-AZA-9A-HEMOERYTHROMYCIN
  • 10-Dihydro-10-deoxo-11-azaethrythroMycin A
  • 1-Oxa-6-azacyclopentadecan-15-one,13-[(2,6-dideoxy-3-C-Methyl-3-O-Methyl-a-L-ribo-hexopyranosyl)oxy]-2-ethyl-3,4,10-trihydroxy-3,5,8,10,12,14-hexaMethyl-11-[[3,4,6-trideoxy-3-(diMethylaMino)-b-D-xylo-hexopyranosyl]oxy]-,(2R,3S,4R,5R,8R,10R,11R,12S,13S,14R
  • Azathramycin (Desmethyl Azithromycin)
  • Azaerthromycin A
  • Azithromycin EP Impurity A
  • 9-Deoxo-9A-Aza-9A-Hom Oerythromycin A (Azithromycin Amine)
  • Azithromycin mpurity A
  • 6-DeMethylazithroMycin (AzaerythroMycin A)
  • Azithromycin A
  • Azithromycin Amine
  • N6-Demethylazithromycin
  • Azithromycin Impurity U
  • 1-Oxa-6-azacyclopentadecan-15-one
  • AZAERYTHROMYCIN A (100 MG) (9-DEOXO-9A-AZA-9A-HOMOERYTHROMYCIN A)
  • 9-Deoxo-9a-aza-9a-homo Erythromycin A
  • Azaerythromycin A
  • Azathramycin
  • Desmethyl
  • 10-dihydro-10-deoxo-11-azaerythromycin A
  • DESMETHYL AZITHROMYCIN
  • Azithromycin impurity A CRS
  • 6-Demethylazithromycin (Azaerythrom
  • 1-Oxa-6-azacyclopentadecan-15-one, 13-[(2,6-dideoxy-3-C-methyl-3-O-methyl-α-L-ribo-hexopyranosyl)oxy]-2-ethyl-3,4,10-trihydroxy-3,5,8,10,12,14-hexamethyl-11-[[3,4,6-trideoxy-3-(dimethylamino)-β-D-xylo-hexopyranosyl]oxy]-, (2R,3S,4R,5R,8R,10R,11R,12S,13S,14R)-
  • AZITHROMYCIN INTEMEDIATES
  • USP Azaerythromycin A
  • Azithromycin Imp.A (EP): 6-Demethylazithromycin (Azaerythromycin A)
  • Azathramycin A
  • Azithromycin EP Impurity A (N6-Demethylazithromycin/ Desmethylazithromycin/ 9-Deoxo-9a-aza-9a-homo Erythromycin A/ Azaerythromycin A/ Azathramycin)
  • Azithromycin Imp-A
  • 9-Deoxo-9a-aza-9a-homo Erythromycin A (Azithromycin EP Impurity A/ N6-Demethylazithromycin/ Desmethylazithromycin/ Azaerythromycin A/ Azathramycin)
  • (2R,3S,4R,5R,8R,10R,11R,12S,13S,14R)-11-(((2S,3R,4S,6R)-4-(Dimethylamino)-3-hydroxy-6-methyltetrahydro-2H-pyran-2-yl)oxy)-2-ethyl-3,4,10-trihydroxy-13-(((2R,4R,5S,6S)-5-hydroxy-4-methoxy-4,6-dimethyltetrahydro-2H-pyran-2-yl)oxy)-3,5,8,10,12,14-hexamethyl-1-oxa-6-azacyclopentadecan-15-one
  • (2R,3S,4R,5R,8R,10R,11R,12S,13S,14R)-11-(((2S,3R,4S,6R)-4-(Dimethylamino)-3-hydroxy-6-methyltetrahydro-2H-pyran-2-yl)oxy)-2-ethyl-3,4,10-trihydroxy-13-(((2R,4R,5S,6S)-5-hydroxy-4-methoxy-4,6-dimethyltetrahydro-2H-pyran-2-yl)oxy)-3,5,8,10,12,14-hexamethyl-
  • Azithromycin EP Impurity AQ: What is Azithromycin EP Impurity A Q: What is the CAS Number of Azithromycin EP Impurity A Q: What is the storage condition of Azithromycin EP Impurity A Q: What are the applications of Azithromycin EP Impurity A
  • Azaerythromycin (AZAE)
  • Azaerythromycin A (9-Deoxo-9a-aza-9a-homoerythromycin A) (1045600)
  • Azaerythromycin A (（Azithromycin Amine)
  • 1-Oxa-6-azacyclopentadecan-15-one,13-[(2,6-dideoxy-3-C-methyl-3-O-methyl-a-L-ribo-hexopyranosyl)oxy]-2-ethyl-3,4,10-trihydroxy-3,5,8,10,12,14-hexamethyl-11-[[3,4,6-trideoxy-3-(dimethylamino)-b-D-xylo-
  • 9-Deoxo-9α-azα-9α-homo Erythromycin A (Desmethyl Azithromycin)
  • (2R,3S,4R,5R,8R,10R,11R,12S,1(2R,3S,4R,5R,8R,10R,11R,12S, 13S,14R)-11-(((2S,3R,4S,6R)-4-(dimethylamino)-3-hydroxy-6- methyltetrahydro-2H-pyran-2-yl)oxy)-2-ethyl-3,4,10-trihydroxy- 13-(((2R,4R,5S,6S)-5-hydroxy-4-methoxy-4,6-dimethyltetrahydro- 2H-pyran-2-yl)oxy)-3,5,8,10,12,14-hexamethyl-1-oxa-6- azacyclopentadecan-15-one
  • Azithromycin EP Impurity A (Azathramycin)
  • Azathramycin, 10 mM in DMSO
  • (2R,3S,4R,5R,8R,10R,11R,12S,1(2R,3S,4R,5R,8R,10R,11R,12S,13S,14R)-11-(((2S,3R,4S,6R)-4-(dimethylamino)-3-hydroxy-6-methyltetrahydro-2H-pyran-2-yl)oxy)-2-ethyl-3,4,10-trihydroxy13-(((2R,4R,5S,6S)-5-hyd
  • Dihydrohomoerythromycin
  • Dihydroerythromycin
  • Azithromycin EP Impurity A (6-Demethyl Azithromycin)
  • Azithramycin Amine