(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
- Product Name
- (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
- CAS No.
- 301224-40-8
- Chemical Name
- (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
- Synonyms
- HOVEYDA-GRUBBS;HOVEYDA-GRUBBS CATALYST;Hoveyda-Grubbs Catalyst 2nd;Hoveyda-Grubbs 2nd;Hoveyda-Grubbs Catalyst 2nd Generation;[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(2-isopropoxyphenyl)methylene]ruthenium;NH22260;eneration;Hoveyda-g;yst 2nd g
- CBNumber
- CB0667713
- Molecular Formula
- C31H37Cl2N2ORu
- Formula Weight
- 625.62
- MOL File
- 301224-40-8.mol
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Property
- Melting point:
- 216-220 °C(lit.)
- storage temp.
- 2-8°C
- solubility
- Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
- form
- Solid
- color
- Green to Very Dark Green
- Stability:
- Hygroscopic
- InChIKey
- ZRPFJAPZDXQHSM-UHFFFAOYSA-L
- CAS DataBase Reference
- 301224-40-8
- EPA Substance Registry System
- Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-.kappa.O)phenyl]methylene-.kappa.C]-, (SP-5-41)- (301224-40-8)
Safety
- WGK Germany
- 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H227Combustible liquid
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P363Wash contaminated clothing before reuse.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 569755
- Product name
- Hoveyda-Grubbs Catalyst 2nd Generation
- Purity
- 97%
- Packaging
- 2g
- Price
- $1050
- Updated
- 2024/03/01
- Product number
- 569755
- Product name
- Hoveyda-Grubbs Catalyst 2nd Generation
- Purity
- 97%
- Packaging
- 25g
- Price
- $8610
- Updated
- 2024/03/01
- Product number
- 569755
- Product name
- Hoveyda-Grubbs Catalyst 2nd Generation
- Purity
- 97%
- Packaging
- 100mg
- Price
- $60.7
- Updated
- 2024/03/01
- Product number
- 569755
- Product name
- Hoveyda-Grubbs Catalyst 2nd Generation
- Purity
- 97%
- Packaging
- 500mg
- Price
- $277
- Updated
- 2024/03/01
- Product number
- 569755
- Product name
- Hoveyda-Grubbs Catalyst 2nd Generation
- Purity
- 97%
- Packaging
- 10g
- Price
- $3490
- Updated
- 2024/03/01
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Chemical Properties,Usage,Production
Chemical Properties
Bright green crystalline powder
Uses
It′s a phosphine free version of Grubbs 2nd Generation Catalyst with comparable reactivity, but initiates more readily at lower temperatures. Efficient for metathesis of electron-deficient substrates including fluorinated olefins. Demonstrated in multiple large-scale pharmaceutical applications.
It can be used as a catalyst for olefin cross-metathesis with fluorinated olefins (CM), ring-closing metathesis (RCM), ring-opening metathesis (ROM), and a sequence of a metathesis reaction and subsequent dihydroxylation of the newly formed double bond.
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM manufacturers
- Product
- (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM 301224-40-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2018-08-13