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ChemicalBook > CAS DataBase List > 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

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Product Name
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
CAS No.
95464-05-4
Chemical Name
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
Synonyms
Pd（dppf）2Cl2;Pd(dppf)Cl2.CH2Cl2;PdCl2(dppf)DCM;[PdCl2(dppf)]CH2Cl2;Palladium[PdCl2(dppf)]CH2Cl2;[1,1-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane PdCl2(dppf)CH2Cl2;CHEMDOSE;ex with dichL;adium(II),compL;Pd(dppf)Cl2 DCM
CBNumber
CB1347621
Molecular Formula
C34H28Cl2FeP2Pd.CH2Cl2
Formula Weight
816.63
MOL File
95464-05-4.mol
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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Property

Melting point:
275-280 °C(lit.)
Density 
1 g/cm3
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Powder
color 
orange-red
Water Solubility 
Insoluble in water.
Stability:
Light Sensitive
CAS DataBase Reference
95464-05-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38-40-67-48/20/22
Safety Statements 
23-24/25-26-36/37
WGK Germany 
3
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
379670
Product name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane
Packaging
1g
Price
$64.3
Updated
2024/03/01
Sigma-Aldrich
Product number
379670
Product name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane
Packaging
5g
Price
$160
Updated
2024/03/01
TCI Chemical
Product number
B2064
Product name
[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct
Purity
>98.0%(T)
Packaging
1g
Price
$58
Updated
2024/03/01
TCI Chemical
Product number
B2064
Product name
[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct
Purity
>98.0%(T)
Packaging
5g
Price
$174
Updated
2024/03/01
Alfa Aesar
Product number
041225
Product name
Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane (1:1), Pd 13%
Packaging
1g
Price
$59.9
Updated
2023/06/20
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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Chemical Properties,Usage,Production

Reaction

  1. Catalyst for the borylation of aryl halides.
  2. β-Alkyl Suzuki-Miyaura cross-coupling reactions with potassium alkyltrifluoroborates.
  3. Catalyst for modified Negishi coupling.
  4. Synthesis of polyheterocycles by a Pd-catalyzed intramolecular N-arylation/C-H bond activation/aryl-aryl bond-forming domino process.
  5. Catalyst for Stille allylation.
  6. Catalyst for the amination of aryl bromides.

Chemical Properties

orange/red solid

Uses

suzuki reaction

Uses

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is used in the preparation of imidazoles, benzimidazoles, and tetrahydropyrimidines,it is also used as a catalyst for Suzuki and Stile couplings.

Application

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is an organometallic compound that can be used as a noble metal catalyst for carbonylation reactions, cross-coupling reactions, Suzuki reaction.

Synthesis

1. Dissolve 2.00 grams of sodium palladium chloride in 30mL of anhydrous ethanol to obtain the ethanol solution of sodium palladium chloride;
2. Dissolve 4.15 grams of 1,1 '-bis (diphenylphosphine) ferrocene in 41mL dichloromethane to obtain 1,1' -bis (diphenylphosphine) ferrocene dichloromethane solution;
3. Under stirring conditions, add the ethanol solution of sodium palladite chloride in step 1 to dichloromethane solution of 1, 1 '-bis (diphenylphosphine) ferrocene in step 2. Stir and react for 1h at 25℃. 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex crystal, yield 90.46%.
In this method, the target product 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex was synthesized directly with dichloromethane as the solvent in one step, eliminating the synthesis process of precursor PDCl2 (DPPF). The reaction process is simple, the synthesis cycle is short, easy to operate, and the purity of the synthesized product is 99.4%.

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Preparation Products And Raw materials

Raw materials

Acetonitrile 1,1'-Bis(diphenylphosphino)ferrocene Toluene Palladium chloride Dichloromethane

Preparation Products

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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Suppliers

Americas 1 Australia 1 Belgium 1 Canada 2 China 364 China Hong Kong 1 Europe 1 Germany 4 India 13 Japan 3 South Korea 1 Switzerland 2 The Netherlands 1 Ukraine 1 United Kingdom 3 United States 26 Global 425
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J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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View Lastest Price from 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex manufacturers

Henan Fengda Chemical Co., Ltd
Product
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex 95464-05-4
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Shanghai Daken Advanced Materials Co.,Ltd
Product
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex 95464-05-4
Price
US $0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG /month
Release date
2021-11-12
Hebei Guanlang Biotechnology Co,.LTD
Product
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromet 95464-05-4
Price
US $8.70/g
Min. Order
10g
Purity
99.95%
Supply Ability
10000kg
Release date
2021-07-16

95464-05-4, 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complexRelated Search:

Palladium chloride Cobalt chloride ETHYNYLFERROCENE Palladium Dichloromethane Acetylferrocene Ferrocenecarboxylic acid [1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloride dichloromethane complex (1:1) Aminoferrocene Ferrocene (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Pd-107 [1,2-Bis(dicyclohexylphosphino)ethane]palladiuM(II) chloride,95% 1,1'-Bis(diphenylphosphino)ferrocene Phenyl phosphine Diphenylphosphine Chloromethane 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

  • DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]-PALLADIUM DICHLOROMETHANE ADDUCT
  • DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE ADDUCT
  • DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE COMPLEX
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE, DICHLOROMETHANE
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE-PALLADIUM(II)DICHLORIDE DICHLOROMETHANE COMPLEX
  • [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), COMPLEX WITH DICHLOROMETHANE (1:1)
  • 1'1-Bis(diphenylphosphino)fewocene Palladium(Ⅱ)chloride dichloromethane chloride
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichlorome
  • Pd(dppf)Cl2.CH2Cl2
  • 1,1'-Bis(diphenylphosphiNA)ferrocene-palladiuM(II)dichloride dichloroMethane coMplex
  • DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHA
  • 1,1'-Bis(diphenylphosphino)fer
  • Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II), coMplex with dichloroMethane (1:1), Pd 13%
  • 1,1'-Bis(diphenylphosphino)ferrocene palladium(Ⅱ)chloride dichloromethane complex
  • [PdCl2(dppf)]CH2Cl2
  • Palladium[PdCl2(dppf)]CH2Cl2
  • PALLADIUM, [1,1''-BIS(DIPHENYLPHOSPHINO-.KAPPA.P)FERROCENE]DICHLORO-, (SP-4-2)-, COMPD. WITH DICHLOROMETHANE
  • Pd（dppf）2Cl2
  • [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1), Pd 13%
  • [1,1μ-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose(R) tablets
  • ChemDose(R), [1,1μ-Bis(diphenylphosphino)ferrocene]dichloropalladium(II )complex with dichloromethane impregnated tablets
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE-PALLADIUM(II)DICHLORIDE DICHLOROMETHANE ADDUCT
  • [1,1-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane PdCl2(dppf)CH2Cl2
  • [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1), Pd
  • [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), DCM ADDUCT
  • [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), DICHLOROMETHANE ADDUCT
  • [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II) DICHLOROMETHANE COMPLEX
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM (II) CHLORIDE
  • [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) CHLORIDE, 1:1 COMPLEX WITH DICHLOROMETHANE
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM (II) CHLORIDE, COMPLEX WITH DICHLOROMETHANE
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladiuM(II)
  • (1,1'-Bis(diphenylphosphino)ferrocene)dichloropalladium-dichloromethane
  • [1,1'-Bis(diphenylphosphino)ferrocene] dichloropalladiuM(II) coMplex with dichlor
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladiuMdichloride dichloroMethanecoMplex
  • [1,1'-bis (diphenylphosphino) ferrocene] dichloropalladiuM dichloroMethane coMplex
  • [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (1:1)
  • Pd(dppf)Cl2 DCM
  • Bis(dibenzylibeneacetone)palladium
  • adium(II),compL
  • ex with dichL
  • [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1)
  • [1,1Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane PdCl2(dppf)H2Cl2
  • [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex.dichloromethane
  • [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) dichloromethane
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex [Pd(dppf)Cl2.CH2Cl2]
  • [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane,Pd(dppf)Cl2 · DCM
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladiuM(II)dichloride dic
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane com
  • 1,1'-Bis(diphenylphosphino)ferrocene palladium(II)chloride dichloromethane complex ,97%
  • [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride dichloromethane complex
  • Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II) dichloroMethane adduct, (DPPF)PdCl2·CH2Cl2
  • [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II)
  • Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II) dichloMethane coMplex
  • (1,1'-Bis(diphenylphosphino)ferrocene)dichloropalladiuM-dichloroMethane (1:1)
  • [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose(TM) tablets Loading: 2mumol per tablet
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladium dichloride dichloromethane adduct
  • 1, 1-Bis(diphenylphosphino)Ferrocene] dichloropalaldium(II) complex with DCM
  • Palladium, [1,1'-bis(diphenylphosphino-κP)ferrocene]dichloro-, (SP-4-2)-, compd. with dichloromethane