Vanadyl acetylacetonate

Reaction

Product Name: Vanadyl acetylacetonate
CAS No.: 3153-26-2
Chemical Name: Vanadyl acetylacetonate
Synonyms: Bis(acetylacetonate)oxovanadiuM;Vanadylacetylacetonato;Vanadyl acetylacetonate ,98%;Vanadyl bis(acetylacetonate);VANADIUM(IV)OXY ACETYLACETONATE;VANADIUM(IV) OXIDE BIS(2,4-PENTANEDIONATE);VANADIUM(IV)-BIS(ACETYLACETONATO)OXIDE , (VANADYL PENTANEDIONATE);Vanadyl acetylaceton;VANADYL ACETYLACETONE;VO(acac)2
CBNumber: CB0679215
Molecular Formula: C10H14O5V
Formula Weight: 265.16
MOL File: 3153-26-2.mol

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Vanadyl acetylacetonate Property

Melting point:: 235 °C (dec.)(lit.)
Boiling point:: 140°C 13mm
Density: 1,4 g/cm³
vapor pressure: 0Pa at 20℃
Flash point:: 79 °C
storage temp.: Store below +30°C.
solubility: Moderately soluble in acetone, ether and chloroform. Soluble in ethanol and benzene
form: Crystalline Powder
color: Green to blue-green
Specific Gravity: 1.4
Water Solubility: practically insoluble
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
BRN: 4138236
Exposure limits: NIOSH: Ceiling 0.05 mg/m3
Stability:: Stable, but air sensitive. May discolour upon exposure to air. Incompatible with strong oxidizing agents.
InChIKey: JFHJZWAQYMGNBE-SUKNRPLKSA-L
LogP: 0.4 at 20℃
CAS DataBase Reference: 3153-26-2(CAS DataBase Reference)
NIST Chemistry Reference: Bis(2,4-pentanedionato)oxovanadium(iv)(3153-26-2)
EPA Substance Registry System: Vanadium, oxobis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-5-21)- (3153-26-2)

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Safety

Hazard Codes: Xn
Risk Statements: 22-36/37/38-20/21/22
Safety Statements: 22-26-36-36/37/39
RIDADR: 3285
WGK Germany: 3
TSCA: Yes
HazardClass: 6.1
PackingGroup: III
HS Code: 29420000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 550787
Product name: Vanadyl acetylacetonate
Purity: 98%
Packaging: 10g
Price: $51
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.08505
Product name: Vanadium(IV) oxide acetylacetonate
Purity: for synthesis
Packaging: 100g
Price: $146
Updated: 2024/03/01

Sigma-Aldrich

Product number: 550787
Product name: Vanadyl acetylacetonate
Purity: 98%
Packaging: 50g
Price: $89.8
Updated: 2024/03/01

TCI Chemical

Product number: V0016
Product name: Bis(2,4-pentanedionato)vanadium(IV) Oxide
Purity: >95.0%(T)
Packaging: 25g
Price: $32
Updated: 2024/03/01

Alfa Aesar

Product number: 081119
Product name: Vanadium(IV) oxide bis(2,4-pentanedionate)
Packaging: 10g
Price: $22.65
Updated: 2024/03/01

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Vanadyl acetylacetonate Chemical Properties,Usage,Production

Reaction

Catalyst for the hydroxyl-directed epoxidation of olefins.
Catalyst for the asymmetric oxidation of disulfides.
Catalyst for the Mannich reaction.
Catalyst for sulfoxidation of alkanes.

Chemical Properties

powder

Uses

Vanadium(IV) Oxide Acetylacetonate is used as a catalyst in organic chemistry and is also an intermediate in synthetic reactions, such as the synthesis of novel oxovanadium complexes that display antitumor activity.

Uses

Vanadyl acetylacetonate may be used as a precursor for the preparation of vanadium dioxide thin films for applications in “intelligent” window coating and data storage.

Flammability and Explosibility

Not classified

Purification Methods

It crystallises from acetone. [cf Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3672.]

Vanadyl acetylacetonate Preparation Products And Raw materials

Raw materials

Oxalic acid dihydrate Acetylacetone Ethanol Acetone [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Sodium sulfite 1-Chlorobutane Chloroform Vanadium(V) oxide Dichloromethane Activated carbon Sulfuric acid Sodium carbonate

Preparation Products

2-Oxetanone (R)-(+)-2-Methyl-2-propanesulfinamide

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Vanadyl acetylacetonate Suppliers

Belgium 1 China 288 Germany 4 India 20 Japan 4 Singapore 1 Switzerland 1 United Kingdom 4 United States 29 Global 352

Wuhan hongde yuexin pharmaceutical technology co. LTD

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Hubei ZhengXingyuan Chemical Co., Ltd.

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Suzhou Guide Fine Material Co.Ltd.

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J & K SCIENTIFIC LTD.

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Meryer (Shanghai) Chemical Technology Co., Ltd.

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INTATRADE GmbH

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View Lastest Price from Vanadyl acetylacetonate manufacturers

hebei hongtan Biotechnology Co., Ltd

Product: Vanadyl acetylacetonate 3153-26-2
Price: US $80.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000
Release date: 2024-03-27

Hebei Mojin Biotechnology Co., Ltd

Product: Vanadyl acetylacetonate 3153-26-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2024-03-26

Hebei Duling International Trade Co. LTD

Product: Vanadyl acetylacetonate 3153-26-2
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000 Ton
Release date: 2022-11-15

3153-26-2, Vanadyl acetylacetonateRelated Search:

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VANADYL ACETYLACETONE

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VANADIUM(IV) OXIDE ACETYLACETONATE FOR S

oxobis(2,4-pentanedionato-O,O’)-,(SP-5-21)-Vanadium

Oxobis(acetylacetonato)vanadium

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Oxy-bis2,4-pentandione-vanadium

Vanadium oxyacetoacetonate

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VO(acac)<sub>2</sub>

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