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Vanadyl acetylacetonate

Reaction
Product Name
Vanadyl acetylacetonate
CAS No.
3153-26-2
Chemical Name
Vanadyl acetylacetonate
Synonyms
Bis(acetylacetonate)oxovanadiuM;Vanadylacetylacetonato;Vanadyl acetylacetonate ,98%;Vanadyl bis(acetylacetonate);VANADIUM(IV)OXY ACETYLACETONATE;VANADIUM(IV) OXIDE BIS(2,4-PENTANEDIONATE);VANADIUM(IV)-BIS(ACETYLACETONATO)OXIDE , (VANADYL PENTANEDIONATE);Vanadyl acetylaceton;VANADYL ACETYLACETONE;VO(acac)2
CBNumber
CB0679215
Molecular Formula
C10H14O5V
Formula Weight
265.16
MOL File
3153-26-2.mol
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Vanadyl acetylacetonate Property

Melting point:
235 °C (dec.)(lit.)
Boiling point:
140°C 13mm
Density 
1,4 g/cm3
vapor pressure 
0Pa at 20℃
Flash point:
79 °C
storage temp. 
Store below +30°C.
solubility 
Moderately soluble in acetone, ether and chloroform. Soluble in ethanol and benzene
form 
Crystalline Powder
color 
Green to blue-green
Specific Gravity
1.4
Water Solubility 
practically insoluble
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
4138236
Exposure limits
NIOSH: Ceiling 0.05 mg/m3
Stability:
Stable, but air sensitive. May discolour upon exposure to air. Incompatible with strong oxidizing agents.
InChIKey
JFHJZWAQYMGNBE-SUKNRPLKSA-L
LogP
0.4 at 20℃
CAS DataBase Reference
3153-26-2(CAS DataBase Reference)
NIST Chemistry Reference
Bis(2,4-pentanedionato)oxovanadium(iv)(3153-26-2)
EPA Substance Registry System
Vanadium, oxobis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-5-21)- (3153-26-2)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36/37/38-20/21/22
Safety Statements 
22-26-36-36/37/39
RIDADR 
3285
WGK Germany 
3
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29420000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
550787
Product name
Vanadyl acetylacetonate
Purity
98%
Packaging
10g
Price
$51
Updated
2024/03/01
Sigma-Aldrich
Product number
8.08505
Product name
Vanadium(IV) oxide acetylacetonate
Purity
for synthesis
Packaging
100g
Price
$146
Updated
2024/03/01
Sigma-Aldrich
Product number
550787
Product name
Vanadyl acetylacetonate
Purity
98%
Packaging
50g
Price
$89.8
Updated
2024/03/01
TCI Chemical
Product number
V0016
Product name
Bis(2,4-pentanedionato)vanadium(IV) Oxide
Purity
>95.0%(T)
Packaging
25g
Price
$32
Updated
2024/03/01
Alfa Aesar
Product number
081119
Product name
Vanadium(IV) oxide bis(2,4-pentanedionate)
Packaging
10g
Price
$22.65
Updated
2024/03/01
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Vanadyl acetylacetonate Chemical Properties,Usage,Production

Reaction

Catalyst for the hydroxyl-directed epoxidation of olefins.
Catalyst for the asymmetric oxidation of disulfides.
Catalyst for the Mannich reaction.
Catalyst for sulfoxidation of alkanes.

Chemical Properties

powder

Uses

Vanadium(IV) Oxide Acetylacetonate is used as a catalyst in organic chemistry and is also an intermediate in synthetic reactions, such as the synthesis of novel oxovanadium complexes that display antitumor activity.

Uses

Vanadyl acetylacetonate may be used as a precursor for the preparation of vanadium dioxide thin films for applications in “intelligent” window coating and data storage.

Flammability and Explosibility

Not classified

Purification Methods

It crystallises from acetone. [cf Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3672.]

Vanadyl acetylacetonate Preparation Products And Raw materials

Raw materials

Oxalic acid dihydrate Acetylacetone Ethanol Acetone [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Sodium sulfite 1-Chlorobutane Chloroform Vanadium(V) oxide Dichloromethane Activated carbon Sulfuric acid Sodium carbonate

Preparation Products

2-Oxetanone (R)-(+)-2-Methyl-2-propanesulfinamide
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Vanadyl acetylacetonate Suppliers

Belgium 1 China 294 Germany 4 India 20 Japan 4 Singapore 1 Switzerland 1 United Kingdom 4 United States 29 Global 358
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
Azumax Co.，Ltd.
Tel
--
Fax
--
Email
sales@azmax.co.jp
Country
Japan
ProdList
562
Advantage
42
Nacalai Tesque, Inc.
Tel
--
Fax
--
Email
info-tech@nacalai.co.jp
Country
Japan
ProdList
6046
Advantage
75
Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74
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View Lastest Price from Vanadyl acetylacetonate manufacturers

hebei hongtan Biotechnology Co., Ltd
Product
Vanadyl acetylacetonate 3153-26-2
Price
US $80.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000
Release date
2024-03-27
Hebei Weibang Biotechnology Co., Ltd
Product
Vanadyl acetylacetonate 3153-26-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-30
Hebei Yanxi Chemical Co., Ltd.
Product
Vanadyl acetylacetonate 3153-26-2
Price
US $40.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-08

3153-26-2, Vanadyl acetylacetonateRelated Search:

Manganic acetylacetonate VANADIUM(III) ACETYLACETONATE Vanadium(V) oxide Aluminum acetylacetonate ACETOXYACETONE Acetylacetone Ammonium metavanadate Ferric acetylacetonate Titanium(IV)oxide acetylacetonate ZINC ACETYLACETONATE HYDRATE COBALT(II) ACETYLACETONATE ZINC ACETYLACETONATE HYDRATE Acetyl coenzyme A sodium salt Cyclohexene oxide Acetylcholine Levulinic acid 2,4-PENTANEDIONE, SILVER DERIVATIVE Acetosyringone

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