ChemicalBook > CAS DataBase List > 4,4'-Dimethyltriphenylamine

4,4'-Dimethyltriphenylamine

Product Name
4,4'-Dimethyltriphenylamine
CAS No.
20440-95-3
Chemical Name
4,4'-Dimethyltriphenylamine
Synonyms
DMTPA;4,4'-Dimethyltriphen;N,N-DI-P-TOLYLANILINE;PHENYL(DI-P-TOLYL)AMINE;n-phenyl di-p-tolylamine;4,4DimehtylTriphenylamine;4-Methyl-N-(4-methylphenyl;4,4'-Dimethyltriphenylamine;4,4'-Dimethyltriphenylamine;N-Phenyl di-p-tolylamine,97%
CBNumber
CB0686015
Molecular Formula
C20H19N
Formula Weight
273.37
MOL File
20440-95-3.mol
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4,4'-Dimethyltriphenylamine Property

Melting point:
112°C
Boiling point:
289.3 °C
Density 
1.079±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
pka
-2.19±0.50(Predicted)
color 
White to Orange to Green
CAS DataBase Reference
20440-95-3(CAS DataBase Reference)
EPA Substance Registry System
Benzenamine, 4-methyl-N-(4-methylphenyl)-N-phenyl- (20440-95-3)
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Safety

HS Code 
29214990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
D2347
Product name
4,4'-Dimethyltriphenylamine
Purity
>98.0%(GC)
Packaging
1g
Price
$21
Updated
2025/07/31
TCI Chemical
Product number
D2347
Product name
4,4'-Dimethyltriphenylamine
Purity
>98.0%(GC)
Packaging
5g
Price
$56
Updated
2025/07/31
TCI Chemical
Product number
D2347
Product name
4,4'-Dimethyltriphenylamine
Purity
>98.0%(GC)
Packaging
25g
Price
$173
Updated
2025/07/31
TRC
Product number
D462545
Product name
4,4''-Dimethyltriphenylamine
Packaging
500mg
Price
$65
Updated
2021/12/16
TRC
Product number
D462545
Product name
4,4''-Dimethyltriphenylamine
Packaging
100mg
Price
$45
Updated
2021/12/16
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4,4'-Dimethyltriphenylamine Chemical Properties,Usage,Production

Chemical Properties

White to yellow solid

Uses

4,4''-Dimethyltriphenylamine

Synthesis

108-86-1

620-93-9

20440-95-3

Bromobenzene (7.71 g, 49.1 mmol), 4,4'-dimethyldiphenylamine (9.78 g, 49.6 mmol), sodium tert-butoxide (5.70 g, 59.3 mmol), palladium acetate (110 mg, 0.490 mmol), tri-tert-butylphosphine (396 mg, 1.96 mmol), and o-xylene (110 mL) were added sequentially under nitrogen protection to a 200 mL three-neck flask equipped with a stirrer. 1.96 mmol) and o-xylene (110 mL). The reaction mixture was stirred at 120 °C for 20 hours. Upon completion of the reaction, 150 mL of pure water was added to the mixture to wash and separate the organic phase. Subsequently, the organic phase was washed with another 150 mL of pure water, followed by washing with saturated saline and separation. The resulting organic layer was concentrated under reduced pressure and the solvent was removed by distillation. The resulting residue was purified by silica gel column chromatography to give 12.9 g of the final white crystalline product 4,4'-dimethyltriphenylamine (96% yield, 99.1% purity).

Purification Methods

Crystallise the amine once from EtOAc, then twice from EtOH to give pale yellow needles [Marsden J Chem Soc 627 1937, Beilstein 12 III 2033.]

References

[1] Journal of the American Chemical Society, 2012, vol. 134, # 50, p. 20262 - 20265
[2] Patent: JP5966736, 2016, B2. Location in patent: Paragraph 0075; 0078
[3] Organic and Biomolecular Chemistry, 2009, vol. 7, # 19, p. 3922 - 3925
[4] Organic Letters, 2005, vol. 7, # 11, p. 2209 - 2211

4,4'-Dimethyltriphenylamine Preparation Products And Raw materials

Raw materials

Preparation Products

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4,4'-Dimethyltriphenylamine Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
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China
ProdList
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
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China
ProdList
24529
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
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China
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Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
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China
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JinYan Chemicals(ShangHai) Co.,Ltd.
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13817811078
Fax
86-021-50426522,50426273
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sales@jingyan-chemical.com
Country
China
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Jia Xing Isenchem Co.,Ltd
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0573-85285100 18627885956
Fax
0573-85285100
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isenchem@163.com
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China
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Shanghai Hanhong Scientific Co.,Ltd.
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021-54306202 13764082696
Email
info@hanhongsci.com
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China
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42934
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XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527768836
Email
1791901229@qq.com
Country
China
ProdList
6950
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SHANGHAI HOHANCE CHEMICAL CO.,LTD
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021-31115312 18217084087
Fax
86 021 31115317
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mary@hohance.com
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China
ProdList
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View Lastest Price from 4,4'-Dimethyltriphenylamine manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
4,4'-Dimethyltriphenylamine 20440-95-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-12-10
Shanghai UCHEM Inc.
Product
4,4'-Dimethyltriphenylamine 20440-95-3
Price
US $13.00-222.00/g
Min. Order
25g
Purity
0.98
Supply Ability
25kg
Release date
2023-11-29
Kindchem(Nanjing)Co.,Ltd
Product
4,4'-Dimethyltriphenylamine 20440-95-3
Price
US $0.00-0.00/G
Min. Order
10G
Purity
0.98
Supply Ability
500kg
Release date
2023-09-26

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