ChemicalBook > CAS DataBase List > 3,4-Dichloroaniline

3,4-Dichloroaniline

Product Name
3,4-Dichloroaniline
CAS No.
95-76-1
Chemical Name
3,4-Dichloroaniline
Synonyms
3,4-dca;Gefitinib-1;3.4-Dichloroan;3,4-Dichloroanil;3,4-Dichloranilin;AKOS BBS-00003672;3,4-Dichloraniline;3,4-Dichloroanihne;3,4-dichloro-anilin;3,4-Dichloroanaline
CBNumber
CB5696598
Molecular Formula
C6H5Cl2N
Formula Weight
162.02
MOL File
95-76-1.mol
More
Less

3,4-Dichloroaniline Property

Melting point:
69-71 °C(lit.)
Boiling point:
272 °C(lit.)
Density 
1,34 g/cm3
vapor pressure 
97.5Pa at 78℃
refractive index 
1.6140 (estimate)
Flash point:
166 °C
storage temp. 
0-6°C
solubility 
0.73g/l
form 
Crystalline Mass and/or Chunks
pka
2.90±0.10(Predicted)
color 
Beige to brown
PH
7.1 (0.8g/l, H2O)
Water Solubility 
0.06 g/100 mL
Merck 
14,3054
BRN 
636837
Stability:
Stable, but darkens in storage. Combustible. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides.
LogP
2.68 at 20℃
CAS DataBase Reference
95-76-1(CAS DataBase Reference)
NIST Chemistry Reference
Benzenamine, 3,4-dichloro-(95-76-1)
EPA Substance Registry System
3,4-Dichloroaniline (95-76-1)
More
Less

Safety

Hazard Codes 
T,N
Risk Statements 
23/24/25-41-43-50/53-51/53-33
Safety Statements 
26-36/37/39-45-60-61-36/37-28
RIDADR 
UN 3442 6.1/PG 2
WGK Germany 
3
RTECS 
BX2625000
8
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29214210
Hazardous Substances Data
95-76-1(Hazardous Substances Data)
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H318Causes serious eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
437778
Product name
3,4-Dichloroaniline
Purity
98%
Packaging
5g
Price
$36.4
Updated
2024/03/01
Sigma-Aldrich
Product number
437778
Product name
3,4-Dichloroaniline
Purity
98%
Packaging
250g
Price
$95.3
Updated
2024/03/01
TCI Chemical
Product number
D0324
Product name
3,4-Dichloroaniline
Purity
>98.0%(GC)
Packaging
25g
Price
$30
Updated
2024/03/01
TCI Chemical
Product number
D0324
Product name
3,4-Dichloroaniline
Purity
>98.0%(GC)
Packaging
500g
Price
$149
Updated
2024/03/01
Alfa Aesar
Product number
A15199
Product name
3,4-Dichloroaniline, 98%
Packaging
50g
Price
$26.65
Updated
2024/03/01
More
Less

3,4-Dichloroaniline Chemical Properties,Usage,Production

Chemical Properties

brown solid

Uses

3,4-Dichloroaniline is used in the preparation of the herbicide propanil (P760840).

Uses

3,4-Dichloroaniline may be employed as derivatization reagent for the HPLC analysis of perfluorooctanoic acid (PFOA).

Uses

3,4-Dichloroaniline is used as an intermediate for pesticides and dyes.

Preparation

3,4-Dichloroaniline is produced by catalytic hydrogenation of 3,4-dichloronitrobenzene with noble metal catalysts under pressure. Various types of additives prevent dehalogenation during production and reactors must be fabricated with special steel alloys to inhibit corrosion.

Definition

ChEBI: A dichloroaniline having the two chloro-substituents at the 3- and 4-positions.

General Description

Light tan to dark gray crystals or brown solid. Melting point 71-72°C.

Air & Water Reactions

Sensitive to prolonged exposure to heat, light and air. Darkens in storage. Insoluble in water.

Reactivity Profile

3,4-Dichloroaniline is incompatible with oxidizing agetns, acids, acid chlorides and acid anhydrides. 3,4-Dichloroaniline can decompose at low pH. Hydrochloric acid accelerates decomposition. Reacts at temperatures above 356°F in the presence of ferric chloride .

Fire Hazard

3,4-Dichloroaniline is combustible.

Metabolic pathway

The basidiomycete Filoboletus sp. TA9054 metabolizes 3,4-dichloroaniline and forms several condensation products on solid media and in liquid culture, and no oligomers are produced. Six metabolites are identified as 3,3'-4,4'- tetrachloroazobenzene, 4-(3,4-dichloroanilino)-3,3',4' - trichloroazobenzene, 4-[(3,4-dichloroanilino)-4-(3,4- dichloroanilino)]-3,3'4'-trichloroazobenzene, 2-(3,4- dichloroanilino)-N-(3,4-dichlorophenyl)-4- (chlorophenylene), 6-(3,4-dichloroanilino)-N-(3,4- dichlorophenyl)-4-(chlorophenylene), and 3,5-bis(3,4- dichloroanilino)-1,4-chlorobenzoquinone.

Purification Methods

Crystallise the aniline from MeOH. [Beilstein 12 IV 1257.]

More
Less

3,4-Dichloroaniline Suppliers

Qingdao Baiyi Chemical Co., Ltd
Tel
13053388919
Email
1454485610@qq.com
Country
China
ProdList
439
Advantage
58
Shanghai Taijilin Industrial Co., Ltd.
Tel
021-50630626 18964684208
Fax
021-50563898
Email
kate@tajilin.com
Country
China
ProdList
1212
Advantage
58
Qingdao Baiyi Chemical Co., Ltd
Tel
13053388929
Email
3654853487@qq.com
Country
China
ProdList
501
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2341
Advantage
56
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
Advantage
57
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44853
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18217
Advantage
66
More
Less

View Lastest Price from 3,4-Dichloroaniline manufacturers

Firsky International Trade (Wuhan) Co., Ltd
Product
3,4-Dichloroaniline 95-76-1
Price
US $30.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2023-09-27
Hebei Mojin Biotechnology Co., Ltd
Product
3,4-Dichloroaniline 95-76-1
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-28
Hebei Guanlang Biotechnology Co., Ltd.
Product
3,4-Dichloroaniline 95-76-1
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5tons
Release date
2021-09-30

95-76-1, 3,4-DichloroanilineRelated Search:


  • 3,4-DICHLOROPHENYLAMINE
  • 3,4-dca
  • 3,4-dichlorobenzenamine
  • 3,4-Dichloroanihne
  • 3,4-DICHLOROANILINE
  • 3,4-Dichloranilin
  • 3,4-Dichloraniline
  • 3,4-Dichloroanaline
  • 3,4-dichloro-anilin
  • 3,4-dichloro-benzenamin
  • 4,5-Dichloroaniline
  • Aniline, 3,4-dichloro-
  • LABOTEST-BB LTBB000652
  • 1-AMINO-3,4-DICHLORO-BENZENE
  • Gefitinib-1
  • 3,4-Dichloroanil
  • high quality 3,4-Dichloroanilinekf-wang(at)kf-chem.com
  • m,p-dichloroaniline
  • AKOS BBS-00003672
  • Benzenamine, 3,4-dichloro-
  • 3,4-DICHLOROANILINE PESTANAL
  • 3,4-Dichloroaniline,>98%
  • 3,4-DichloroAniline(3,4-Dca)99.5%
  • 3,4-dichloroaminobenzene)
  • 3,4-DICHLOROBENZAMINE
  • DICHLORO-3,4-ANILINE
  • 3,4-Dichlorobenzeneamine
  • 3,4-Dichloroaniline, 98% 250GR
  • 3,4-Dichloroaniline, 98% 5GR
  • 3, 4-2 chloro aniline
  • 3.4-Dichloroan
  • Gefitinib IMpurity III
  • 3,4-DichloroanilineSolution,1,000mg/L,1ml
  • 3,4-Dichloroaniline &gt
  • 3,4-DichloroanilineSolution,100mg/L,1ml
  • 3,4-Dichloroaniline ISO 9001:2015 REACH
  • 3-OXO-3-P-TOLYL-PROPIONI
  • 3,4-Dichloroaniline,99%
  • Gefitinib Impurity 25
  • Gefitinib Impurity 3
  • 3,4-Dichloroaniline in methanol
  • 95-76-1
  • Building Blocks
  • Amines
  • C2 to C6
  • Nitrogen Compounds
  • Organic Building Blocks
  • amine | alkyl chloride
  • Aromatics
  • Miscellaneous Reagents
  • Anilines, Aromatic Amines and Nitro Compounds
  • Organics
  • Building Blocks
  • C6
  • Chemical Synthesis
  • Nitrogen Compounds
  • Organic Building Blocks
  • Intermediates of Dyes and Pigments