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BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL

Product Name
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
CAS No.
13007-90-4
Chemical Name
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
Synonyms
phosphine)dicarbonyL;BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL;BIS(TRIPHENYLPHOSPHINE)NICKEL &;DICARBONYL-BIS(TRIPHENYLPHOSPHINE)NICKEL;BIS(TRIPHENYLPHOSPHINE)NICKEL DICARBONYL;NICKEL-BIS(TRIPHENYLPHOSPHINE) DICARBONYL;Bis-(triphenylphosphino)-nickel dicarbonyl;dicarbonylbis(triphenylphosphine)nickel(0);Bis(triphenylphosphine)nickel(0)dicarbonyl;Bis(triphenylphosphine)nickeldicarbonyl,98%
CBNumber
CB0687047
Molecular Formula
C38H30NiO2P2
Formula Weight
639.28
MOL File
13007-90-4.mol
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BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Property

Melting point:
206-209 °C (lit.)
storage temp. 
2-8°C
solubility 
Soluble in HMPA, THF, diglyme, triglyme, benzene, acetonitrile, ethanol, and cyclohexane.
form 
crystal
color 
light yellow
Sensitive 
air sensitive
Merck 
14,1304
Exposure limits
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference
13007-90-4
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Safety

Hazard Codes 
T
Risk Statements 
45-42/43
Safety Statements 
53-22-36/37-45
RIDADR 
3281
WGK Germany 
3
HazardClass 
6.1
PackingGroup 
II
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H350May cause cancer

Precautionary statements

P201Obtain special instructions before use.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
213934
Product name
Bis(triphenylphosphine)dicarbonylnickel
Packaging
10g
Price
$134
Updated
2025/07/31
Strem Chemicals
Product number
28-0100
Product name
Bis(triphenylphosphine)nickel dicarbonyl, 98%
Packaging
5g
Price
$43
Updated
2024/03/01
Strem Chemicals
Product number
28-0100
Product name
Bis(triphenylphosphine)nickel dicarbonyl, 98%
Packaging
25g
Price
$165
Updated
2024/03/01
Strem Chemicals
Product number
28-0100
Product name
Bis(triphenylphosphine)nickel dicarbonyl, 98%
Packaging
100g
Price
$490
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
OGM0000677
Product name
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
Purity
95.00%
Packaging
10G
Price
$1167.39
Updated
2021/12/16
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BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Chemical Properties,Usage,Production

Chemical Properties

light yellow crystals or crystalline powder

Uses

Catalyst for:

  • Cyclotrimerization reactions
  • Cyclooligomerization reactions

Uses

Catalyst in polymerization of acetylene to benzene and styrene, trimerization of ethynyl Compounds, cyclization of butadiene.

reaction suitability

core: nickel
reagent type: catalyst

Synthesis

The preparative method of Bis(triphenylphosphine)dicarbonylnickel: by treating Tetracarbonylnickel with 2 equiv of Triphenylphosphine or by dissolving Dichlorobis(triphenylphosphine)nickel(II) in ethanol and treating it with CO in the presence of MeSNa. Purification: recrystallize from benzene.

Precautions

Catalytic activity decreases with storage. It is likely to be toxic, similar to nickel carbonyl, but its low volatility makes it easy to avoid ingestion. Use in a fume hood.

BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Suppliers

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13007-90-4, BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKELRelated Search:

BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE Bis-(triphenylphosphino)-cuprous borohydride [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 1,2-Dimethoxyethane Bis(tri-tert-butylphosphine)palladium(0) Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Bis(triphenylphosphine)palladium(II) chloride Bis(triphenylphosphine)nickel(II)chloride Triphenylphosphine CARBON MONOXIDE Diphenylphosphine (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Nickel sulfate hexahydrate BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL

  • NICKEL-BIS(TRIPHENYLPHOSPHINE) DICARBONYL
  • BIS(TRIPHENYLPHOSPHINE)NICKEL DICARBONYL
  • BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
  • DICARBONYL-BIS(TRIPHENYLPHOSPHINE)NICKEL
  • BIS(TRIPHENYLPHOSPHINE)NICKEL &
  • Bis(triphenylphosphine)nickel(0)dicarbonyl
  • Bis(triphenylphosphine)nickeldicarbonyl,98%
  • Nickel, dicarbonylbis(triphenylphosphine)-, (T-4)-
  • dicarbonylbis(triphenylphosphine)nickel(0)
  • Bis-(triphenylphosphino)-nickel dicarbonyl
  • Dicarbonylbis(triphenylphosphine)nickel(0), Nickel(0)bis(triphenylphosphine) dicarbonyl
  • Bis(triphenylphosphine)nickel(0)dicarbonyl, Dicarbonylbis(triphenylphosphine)nickel(0), Nickel(0)bis(triphenylphosphine) dicarbonyl
  • Bis(triphenylphosphine)dicarbonylnickel,98%
  • Nickel(0)bis(triphenylphosphine) dicarbonyl
  • phosphine)dicarbonyL
  • BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL ISO 9001：2015 REACH
  • 13007-90-4
  • C6H53P2NiCO2
  • C38H30NiO2P2
  • Catalysis and Inorganic Chemistry
  • metal carbonyl complexes