2-(Trimethylsilyl)pyridine
Uses- Product Name
- 2-(Trimethylsilyl)pyridine
- CAS No.
- 13737-04-7
- Chemical Name
- 2-(Trimethylsilyl)pyridine
- Synonyms
- TriMethylsilyl)pyridin;2-pyridyltrimethylsilane;2-TRIMETHYLSILY-PYRIDINE;2-(Trimethysilyl)pyridine;Trimethyl-2-pyridylsilane;2-(TRIMETHYLSILYL)PYRIDINE;2-Trimethylsilanyl-pyridine;Pyridine,2-(trimethylsilyl)-;trimethyl(pyridin-2-yl)silane;2-(TRIMETHYLSILYL)PYRIDINE, 97+%
- CBNumber
- CB0687542
- Molecular Formula
- C8H13NSi
- Formula Weight
- 151.28
- MOL File
- 13737-04-7.mol
2-(Trimethylsilyl)pyridine Property
- Boiling point:
- 47-49 °C5 mm Hg(lit.)
- Density
- 0.9113 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.489(lit.)
- Flash point:
- 126 °F
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- clear liquid
- pka
- 6.62±0.10(Predicted)
- Specific Gravity
- 0.911
- color
- Colorless to Almost colorless
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- Sensitive
- Light Sensitive
- InChI
- InChI=1S/C8H13NSi/c1-10(2,3)8-6-4-5-7-9-8/h4-7H,1-3H3
- InChIKey
- IBLKFJNZUSUTPB-UHFFFAOYSA-N
- SMILES
- C1([Si](C)(C)C)=NC=CC=C1
- CAS DataBase Reference
- 13737-04-7(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 10-36/37/38
- Safety Statements
- 16-26-36-37/39
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 3
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29333990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H227Combustible liquid
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 649856
- Product name
- 2-(Trimethylsilyl)pyridine
- Purity
- 98%
- Packaging
- 10g
- Price
- $372
- Updated
- 2023/01/07
- Product number
- T2021
- Product name
- 2-(Trimethylsilyl)pyridine
- Purity
- >96.0%(GC)
- Packaging
- 1g
- Price
- $64
- Updated
- 2026/03/19
- Product number
- T2021
- Product name
- 2-(Trimethylsilyl)pyridine
- Purity
- >96.0%(GC)
- Packaging
- 5g
- Price
- $188
- Updated
- 2026/03/19
- Product number
- T896433
- Product name
- 2-(Trimethylsilyl)pyridine
- Packaging
- 10mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- JK210058
- Product name
- 2-(Trimethylsilyl)pyridine
- Purity
- 96%
- Packaging
- 1g
- Price
- $48
- Updated
- 2021/12/16
2-(Trimethylsilyl)pyridine Chemical Properties,Usage,Production
Uses
2-Trimethylsilylpyridine is a pyridine derivative that can be used as an intermediate in organic synthesis.
Chemical Properties
Clear colorless to brown liquid
Synthesis
A solution of 2-chloropyridine (20.7 mL, 217 mmol) and trimethylchlorosilane (28.0 mL, 221 mmol) in THF (100 mL) was added dropwise to a rapidly stirred mixture of magnesium chips (6.75 g, 281 mmol) in THF (175 mL). The solution in was added dropwise to a rapidly stirred mixture of magnesium shavings (6.75 g, 281 mmol) in THF (175 mL). After adding approximately 10 mL of solution was followed by the addition of diiodomethane (0.2 mL), then iodine pellets, and then isopropylmagnesium chloride (2.0 M THF solution, 1 mL, 2 mmol). The suspension was then carefully heated to reflux and the remaining chloride solution was added dropwise over 2.75 hours. The reaction was then allowed to cool to room temperature and stirred overnight. Approximately 200 mL of was removed by distillation of the THF and benzene (125mL) was added. The suspension was refluxed for 2 hours and the benzene was decanted. The benzene was then removed by adding more benzene (2 x 125 mL), refluxing (1 each time) and decanting. hours) and decanting the process was repeated and the combined benzene fractions were concentrated in vacuum and distilled to give 2-trimethylsilylpyridine (6.97 g, 46.2 mmol , 21%) in colorless liquid form.
2-(Trimethylsilyl)pyridine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-(Trimethylsilyl)pyridine manufacturers
- Product
- 2-(Trimethylsilyl)pyridine 13737-04-7
- Price
- US $1.10-9.90/kg
- Min. Order
- 1kg
- Purity
- 99%min
- Supply Ability
- 100kg
- Release date
- 2025-08-18
- Product
- 2-(Trimethylsilyl)pyridine 13737-04-7
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11
- Product
- 2-(Trimethylsilyl)pyridine 13737-04-7
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2018-12-21