1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene
Uses- Product Name
- 1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene
- CAS No.
- 41481-63-4
- Chemical Name
- 1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene
- Synonyms
- Diallyl Ether Bisphenol-S;BIS(4-ALLYLOXYPHENYL)SULFONE;Bis(p-allyloxyphenyl) sulfone;4,4'-Sulfonylbis((allyloxy)benzene);Bis-[4-(2propenyloxy)-phenyl]-sulfone;1-(benzenesulfonyl)-4-prop-2-enoxybenzene;Sulfonylbis(4,1-phenylene)bis(allyl ether);1,1'-PHENYLSULFONYL-4,4'-DIENEPROPYL ETHER;1,1'-sulfonylbis[4-(2-propenyl)oxy-benzene];1,1'-Phenylsulfonyl-4,4'-Dienepropyl(2)Ether
- CBNumber
- CB0696083
- Molecular Formula
- C18H18O4S
- Formula Weight
- 330.4
- MOL File
- 41481-63-4.mol
1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene Property
- Melting point:
- 141-142 °C(Solv: ethanol (64-17-5))
- Boiling point:
- 500.7±45.0 °C(Predicted)
- Density
- 1.171±0.06 g/cm3(Predicted)
- storage temp.
- -20°C Freezer, Under inert atmosphere
- solubility
- DMSO (Slightly), Methanol (Slightly)
- form
- Solid
- color
- White to Off-White
- CAS DataBase Reference
- 41481-63-4(CAS DataBase Reference)
N-Bromosuccinimide Price
- Product number
- A614508
- Product name
- bis(4-Allyloxyphenyl)sulfone
- Packaging
- 10g
- Price
- $245
- Updated
- 2021/12/16
- Product number
- FB147064
- Product name
- Bis(4-allyloxyphenyl)sulfone
- Packaging
- 100g
- Price
- $376
- Updated
- 2021/12/16
- Product number
- P143
- Product name
- 1,1'-Sulfonylbis[4-(2-propenyl)oxy-benzene]
- Packaging
- 100g
- Price
- $557
- Updated
- 2021/12/16
- Product number
- FB147064
- Product name
- Bis(4-allyloxyphenyl)sulfone
- Packaging
- 250g
- Price
- $752.5
- Updated
- 2021/12/16
- Product number
- P143
- Product name
- 1,1'-Sulfonylbis[4-(2-propenyl)oxy-benzene]
- Packaging
- 250g
- Price
- $1065
- Updated
- 2021/12/16
1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene Chemical Properties,Usage,Production
Uses
1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene is a useful research chemical.
Chemical Properties
White crystalline powder
Preparation
The preparation of 1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene is as follows:2400g water, 216g caustic soda lye of 48% strength, 600g 4,4'-dihydroxydiphenyl sulfone and 204g Allyl chloride were mixed and the reaction was carried out at 55-60°C and autogenously generated pressure of 0.8-1. Okg/cm2 for 8 hours. 204g caustic soda lye of 48% strength was added in the reaction mixture, and maintained for 1 hour at 80°C thereafter filtered at 80°C to remove 4,4'-diallyloxydiphenyl sulfone. Further, the filtrate solution was treated with 5g activated carbon and 5g sequestering agent at 85- 90°C. The pH of filtrated solution was adjusted to 8.9 with 20% sulfuric acid and cooled to 35°C. The precipitate was separated by filtration and slurred in water. The pH was adjusted to 4.94 with 20% sulfuric acid and the precipitate was separated by filtration, and washed with water and dried to obtain 615g the product 4-allyloxy 4'-hydroxydiphenyl sulfone of 96% purity. The yield was 93.5% with respect to 4,4'-dihydroxydiphenyl sulfone. The wet cake of 4,4'-diallyloxydiphenyl sulfone was slurred in 100g of 5%w/v aqueous solution of sodium hydroxide and refluxed for 1 hour, then cooled to 80°C. The precipitate was filtered, washed with water and dried to obtain 45g of 4,4'-diallyloxy diphenyl sulfone of 91.9% purity. The yield was 6% with respect to 4,4'-dihydroxydiphenyl sulfone. pH of the mother liquor obtained after separation of 4-allyloxy 4'-hydroxydiphenyl sulfone, was adjusted to 4.5 with 20% sulfuric acid. The precipitate was separated by filtration, washed with water and dried to obtain 33g of 4,4'-dihydroxydiphenyl sulfone of 87.9% purity. The conversion of 4,4'-dihydroxydiphenyl sulfone was 94.50%.; 595g of 4-allyloxy 4'-hydroxydiphenyl sulfone of 96% purity was dissolved in 230g of 48% strength caustic soda lye and 1000g water, treated with 5g activated carbon and 5g sequestering agent at 85-90°C. The slurry was filtered and pH of the filtrate was adjusted to 8.95 with 20% sulfuric acid and then cooled to 35°C. The precipitate was separated by filtration, slurried in water and the pH was adjusted to 5.0 with 20% sulfuric acid. The slurry was filtrated and the precipitate was washed with water and dried to obtain 563g of 4- allyloxy 4'-hydroxydiphenyl sulfone of 99.273% purity.
1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene Preparation Products And Raw materials
Raw materials
Preparation Products
1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene Suppliers
View Lastest Price from 1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene manufacturers
- Product
- 1-Prop-2-enoxy-4-(4-prop-2-enoxyphenyl)sulfonyl-benzene 41481-63-4
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-09-19
- Product
- 1-Prop-2-enoxy-4-(4-prop-2-enoxyphenyl)sulfonyl-benzene 41481-63-4
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11
- Product
- 1-Prop-2-enoxy-4-(4-prop-2-enoxyphenyl)sulfonyl-benzene 41481-63-4
- Price
- US $2.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- ask
- Release date
- 2018-12-22