Allyl ether
- Product Name
- Allyl ether
- CAS No.
- 557-40-4
- Chemical Name
- Allyl ether
- Synonyms
- ALLYL ETHER;Allylethers;Allylic Ether;ether,diallyl;DIALLYL ETHER;propenylether;ether,propenyl;Ether, diallyl;Allyl ether 98%;Allyl ether,99%
- CBNumber
- CB8753777
- Molecular Formula
- C6H10O
- Formula Weight
- 98.14
- MOL File
- 557-40-4.mol
Allyl ether Property
- Melting point:
- -6°C
- Boiling point:
- 94 °C
- Density
- 0.803 g/mL at 25 °C(lit.)
- refractive index
- 1.415-1.417
- Flash point:
- -7 °C
- storage temp.
- Refrigerator (+4°C) + Flammables area
- solubility
- Chloroform, Methanol (Slightly)
- form
- clear liquid
- color
- Colorless to Almost colorless
- Water Solubility
- insoluble
- Merck
- 14,292
- CAS DataBase Reference
- 557-40-4(CAS DataBase Reference)
- NIST Chemistry Reference
- (CH2=CHCH2)2O(557-40-4)
- EPA Substance Registry System
- 1-Propene, 3,3'-oxybis- (557-40-4)
Safety
- Hazard Codes
- Xn-F,Xn,F
- Risk Statements
- 36/37/38-20/21/22-11
- Safety Statements
- 9-36/37/39-33-26-16-45
- RIDADR
- 2360
- WGK Germany
- 3
- RTECS
- KN7525000
- HS Code
- 2909.19.1800
- HazardClass
- 3.1
- PackingGroup
- II
- Toxicity
- LD50 orally in rats: 0.32 g/kg (Smyth)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H311Toxic in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 259470
- Product name
- Allyl ether
- Purity
- 98%
- Packaging
- 25g
- Price
- $173
- Updated
- 2024/03/01
- Product number
- A0229
- Product name
- Allyl Ether
- Purity
- >98.0%(GC)
- Packaging
- 25mL
- Price
- $71
- Updated
- 2024/03/01
- Product number
- A0229
- Product name
- Allyl Ether
- Purity
- >98.0%(GC)
- Packaging
- 100mL
- Price
- $217
- Updated
- 2024/03/01
- Product number
- A0229
- Product name
- Allyl Ether
- Purity
- >98.0%(GC)
- Packaging
- 500mL
- Price
- $613
- Updated
- 2024/03/01
- Product number
- A552625
- Product name
- Allyl Ether
- Packaging
- 50ml
- Price
- $215
- Updated
- 2021/12/16
Allyl ether Chemical Properties,Usage,Production
Chemical Properties
clear colorless liquid
Uses
Allyl Ether is a modifier used in the manufacture of foamable polystyrene.
General Description
A liquid with an odor of radishes. Less dense than water. Flash point 20°F. May be toxic by ingestion, skin absorption, and inhalation, and may irritate skin and eyes. Vapors heavier than air. Used to make other chemicals.
Air & Water Reactions
Highly flammable. Soluble in water. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154].
Reactivity Profile
Ethers, such as DIALLYLETHER can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
Health Hazard
TOXIC; may be fatal if inhaled, ingested or absorbed through skin. Inhalation or contact with some of these materials will irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire Hazard
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Toxicology
Diallyl Ether smells like horseradish and severely irritates the mucous membranes; the LD50 is approximately 270 mg/kg (rat, oral). Diallyl ether is absorbed easily through the skin; the LD50 is 540 mg/kg (rabbits, dermal, estimate).
Safety Profile
Poison by ingestion. Moderately toxic by skin contact. A skin and eye irritant. A dangerous fire hazard when exposed to heat, flame, or oxidzing materials. To fight fire, use alcohol foam. Reacts with air to form explosive peroxides. Violent explosions have occurred during distillation. When heated to decomposition it emits acrid smoke and fumes. See also ALLYL COMPOUNDS and ETHERS.
Allyl ether Preparation Products And Raw materials
Raw materials
Preparation Products
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