4-FORMYL-3-HYDROXYBENZOIC ACID

Product Name: 4-FORMYL-3-HYDROXYBENZOIC ACID
CAS No.: 619-12-5
Chemical Name: 4-FORMYL-3-HYDROXYBENZOIC ACID
Synonyms: 4-CARBOXYSALICYALDEHYDE;4-FORMYL-3-HYDROXYBENZOIC ACID;3-Hydroxy-4-formylbenzoic acid;Benzoic acid, 4-forMyl-3-hydroxy-;4-Formyl-3-hydroxybenzoic acid 97%;3-hydroxy-4-methanoyl-benzoic acid
CBNumber: CB0749932
Molecular Formula: C8H6O4
Formula Weight: 166.13
MOL File: 619-12-5.mol

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4-FORMYL-3-HYDROXYBENZOIC ACID Property

Melting point:: 235-240 °C (lit.)
Boiling point:: 214.32°C (rough estimate)
Density: 1.2208 (rough estimate)
refractive index: 1.4611 (estimate)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: solid
pka: 3.66±0.10(Predicted)
Appearance: White to light brown Solid
InChI: InChI=1S/C8H6O4/c9-4-6-2-1-5(8(11)12)3-7(6)10/h1-4,10H,(H,11,12)
InChIKey: FDDHFCWYCKQKGY-UHFFFAOYSA-N
SMILES: C(O)(=O)C1=CC=C(C=O)C(O)=C1

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Safety

Hazard Codes: Xn
Risk Statements: 22-36/38-43
Safety Statements: 26-36
WGK Germany: 2
HS Code: 2918999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 633461
Product name: 4-Formyl-3-hydroxybenzoic acid
Purity: 95%
Packaging: 1g
Price: $213
Updated: 2023/06/20

Sigma-Aldrich

Product number: 633461
Product name: 4-Formyl-3-hydroxybenzoic acid
Purity: 95%
Packaging: 5g
Price: $755
Updated: 2023/06/20

TRC

Product number: B414230
Product name: 4-Formyl-3-hydroxybenzoic acid
Packaging: 50mg
Price: $45
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0079235
Product name: 4-FORMYL-3-HYDROXYBENZOIC ACID
Purity: 95.00%
Packaging: 1G
Price: $821.04
Updated: 2021/12/16

Matrix Scientific

Product number: 118984
Product name: 4-Formyl-3-hydroxybenzoic acid
Purity: 95+%
Packaging: 10g
Price: $954
Updated: 2021/12/16

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4-FORMYL-3-HYDROXYBENZOIC ACID Chemical Properties,Usage,Production

Uses

4-Formyl-3-hydroxybenzoic acid can be used as a reactant to prepare:

A pH-sensitive fluorescent probe 4,4′-(hydrazine-1,2-diylidene bis(methanylylidene)) bis(3-hydroxybenzoic acid (HDBB) by one-step condensation reaction with hydrazine.
2-Oxo-2H-1-benzopyran-3,7-dicarboxylic acid by condensation reaction with diethyl malonate.
Schiff base ligands for the preparation of stable and functional Schiff base metal complexes.

Synthesis

100-97-0

99-06-9

619-12-5

GENERAL METHOD: Hexamethylenetetramine (0.3 mmol) and cuprous oxide (0.15 mmol) were sequentially added to a solution of trifluoroacetic acid (5 mL) of the substrate (1a-1q, 0.15 mmol). The reaction mixture was heated to reflux for 5 h and subsequently cooled to room temperature. 3N hydrochloric acid (5 mL) was slowly added to the reaction system and stirring was continued for 1 hour. Upon completion of the reaction, the mixture was concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography (200-300 mesh) to afford the target compound 4-formyl-3-hydroxybenzoic acid.

References

[1] Research on Chemical Intermediates, 2015, vol. 41, # 11, p. 8147 - 8158

4-FORMYL-3-HYDROXYBENZOIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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4-FORMYL-3-HYDROXYBENZOIC ACID Suppliers

China 99 India 1 Switzerland 1 United Kingdom 2 United States 9 Global 112

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View Lastest Price from 4-FORMYL-3-HYDROXYBENZOIC ACID manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: 4-FORMYL-3-HYDROXYBENZOIC ACID 619-12-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: 4-FORMYL-3-HYDROXYBENZOIC ACID 619-12-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1ton
Release date: 2018-08-06

619-12-5, 4-FORMYL-3-HYDROXYBENZOIC ACIDRelated Search:

2,5-Dihydroxyterephthalic acid Diacerein 2-(Trifluoromethoxy)terephthalic acid Sennoside A DIETHYL 2,5-DIHYDROXYTEREPHTHALATE 5-HYDROXYBENZENE-1,2,4-TRICARBOXYLIC ACID Sennoside B Rhein SENNOSIDE 5-FORMYL-2-HYDROXYBENZOIC ACID METHYL ESTER 5-FORMYL-2-HYDROXYBENZOIC ACID 4-Formylbenzoic acid 3-Hydroxybenzoic acid 4-(2,6-dihydroxybenzoyl)-3-formyl-5-hydroxybenzoic acid RHEIN-8-GLUCOSIDE CALCIUM SENNOSIDE SENNIDINE A SENNIDINE B

3-Hydroxy-4-formylbenzoic acid

3-hydroxy-4-methanoyl-benzoic acid

4-FORMYL-3-HYDROXYBENZOIC ACID

4-CARBOXYSALICYALDEHYDE

Benzoic acid, 4-forMyl-3-hydroxy-

4-Formyl-3-hydroxybenzoic acid 97%

619-12-5

Carbonyl Compounds

C8

Aldehydes

Building Blocks

Organic Building Blocks

Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts

Aldehydes

C8

Carbonyl Compounds

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Carbonyl Compounds

Chemical Synthesis

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