2-BROMO-3-FLUOROBENZALDEHYDE
- Product Name
- 2-BROMO-3-FLUOROBENZALDEHYDE
- CAS No.
- 149947-15-9
- Chemical Name
- 2-BROMO-3-FLUOROBENZALDEHYDE
- Synonyms
- 3-Bromo-2-fluorobenzadehyde;2-BROMO-3-FLUOROBENZALDEHYDE;Benzaldehyde, 3-bromo-2-fluoro-;3-BroMo-2-fluorobenzenecarbaldehyde, 95+%
- CBNumber
- CB11092290
- Molecular Formula
- C7H4BrFO
- Formula Weight
- 203.01
- MOL File
- 149947-15-9.mol
2-BROMO-3-FLUOROBENZALDEHYDE Property
- Melting point:
- 43-46°C
- Boiling point:
- 233.7±20.0 °C(Predicted)
- Density
- 1.670±0.06 g/cm3(Predicted)
- Flash point:
- >110°(230°F)
- storage temp.
- Inert atmosphere,2-8°C
- form
- Powder
- color
- Off-white
- Water Solubility
- Slightly soluble in water.
- Sensitive
- Light Sensitive
- InChI
- InChI=1S/C7H4BrFO/c8-6-3-1-2-5(4-10)7(6)9/h1-4H
- InChIKey
- OUAZPCKRSSEQKB-UHFFFAOYSA-N
- SMILES
- C(=O)C1=CC=CC(Br)=C1F
- CAS DataBase Reference
- 149947-15-9
Safety
- Hazard Codes
- Xi
- HazardClass
- IRRITANT
- HS Code
- 2913000090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- B5363
- Product name
- 3-Bromo-2-fluorobenzaldehyde
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $66
- Updated
- 2025/07/31
- Product number
- B5363
- Product name
- 3-Bromo-2-fluorobenzaldehyde
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $197
- Updated
- 2025/07/31
- Product number
- B700250
- Product name
- 3-Bromo-2-fluorobenzaldehyde
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 2615-B-23
- Product name
- 3-Bromo-2-fluorobenzaldehyde
- Purity
- 97%
- Packaging
- 1g
- Price
- $18
- Updated
- 2021/12/16
- Product number
- PC8581
- Product name
- 3-Bromo-2-fluorobenzaldehyde
- Purity
- 98%
- Packaging
- 5g
- Price
- $20
- Updated
- 2021/12/16
2-BROMO-3-FLUOROBENZALDEHYDE Chemical Properties,Usage,Production
Uses
It can be used as pharmaceutical raw material and intermediate.
Synthesis
261723-32-4
149947-15-9
General procedure for the synthesis of 3-bromo-2-fluorobenzaldehyde from (3-bromo-2-fluorophenyl)methanol: Manganese dioxide (9.32 g, 107.31 mmol) was added to a solution of dichloromethane (50 mL) containing (3-bromo-2-fluorophenyl)methanol (2.750 g, 13.413 mmol). The reaction mixture was stirred at 45°C overnight. Upon completion of the reaction, the mixture was filtered through diatomaceous earth and the filter cake was washed with dichloromethane. The filtrate was collected and concentrated under reduced pressure to give 3-bromo-2-fluorobenzaldehyde as a white solid (2.24 g, 83% yield). The product was characterized by 1H NMR (400 MHz, DMSO-d6): δ10.19 (dt, J=1.3,0.7 Hz, 1H), 8.05 (tdd, J=6.8,3.1,1.5 Hz, 1H), 7.85 (ddt, J=7.9,6.4,1.5 Hz, 1H), 7.37 (tdt, J=7.8,1.6, 1H). 0.8 Hz, 1H).
References
[1] Patent: WO2015/52226, 2015, A1. Location in patent: Paragraph 0379
[2] Organic Letters, 2017, vol. 19, # 5, p. 1112 - 1115
[3] Patent: US2008/114167, 2008, A1. Location in patent: Page/Page column 120
2-BROMO-3-FLUOROBENZALDEHYDE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-BROMO-3-FLUOROBENZALDEHYDE manufacturers
- Product
- 2-BROMO-3-FLUOROBENZALDEHYDE 149947-15-9
- Price
- US $0.00-0.00/KG
- Min. Order
- 10mg
- Purity
- 99%HPLC
- Supply Ability
- 2000tons
- Release date
- 2020-01-13
- Product
- 2-BROMO-3-FLUOROBENZALDEHYDE 149947-15-9
- Price
- US $1.80-3.60/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 88KG
- Release date
- 2019-09-04