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Methanesulfonic anhydride

Product Name
Methanesulfonic anhydride
CAS No.
7143-01-3
Chemical Name
Methanesulfonic anhydride
Synonyms
7143/1/3;methylsulfonyl methanesulfonate;Mesic anhydride;Mesyl anhydride;METHANESULPHONIC ANHYDRIDE;Methanesulfonyl anhydride;Methanesulfonic acid, anhydride;methanesulfonyl methanesulfonate;SKL265;7143-01-3-
CBNumber
CB1109276
Molecular Formula
C2H6O5S2
Formula Weight
174.19
MOL File
7143-01-3.mol
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Methanesulfonic anhydride Property

Melting point:
64-67 °C (lit.)
Boiling point:
125 °C/4 mmHg (lit.)
Density 
1,36 g/cm3
vapor density 
3.3 (vs air)
refractive index 
1.5300 (estimate)
Flash point:
125°C/4mm
storage temp. 
Store at <= 20°C.
solubility 
Soluble in organic solvents.
form 
Powder, Crystals and/or Chunks
color 
White to light brown to gray
Sensitive 
Moisture Sensitive
BRN 
972316
InChIKey
IZDROVVXIHRYMH-UHFFFAOYSA-N
CAS DataBase Reference
7143-01-3(CAS DataBase Reference)
NIST Chemistry Reference
Methanesulfonic anhydride(7143-01-3)
EPA Substance Registry System
Methanesulfonic acid, anhydride (7143-01-3)
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Safety

Hazard Codes 
C
Risk Statements 
14-35
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
3-10
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29041000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
269190
Product name
Methanesulfonic anhydride
Purity
97%
Packaging
5g
Price
$29.8
Updated
2024/03/01
Sigma-Aldrich
Product number
269190
Product name
Methanesulfonic anhydride
Purity
97%
Packaging
25g
Price
$85.7
Updated
2024/03/01
Alfa Aesar
Product number
A13328
Product name
Methanesulfonic anhydride, 98%
Packaging
10g
Price
$32.65
Updated
2024/03/01
Alfa Aesar
Product number
A13328
Product name
Methanesulfonic anhydride, 98%
Packaging
25g
Price
$69.65
Updated
2024/03/01
Alfa Aesar
Product number
A13328
Product name
Methanesulfonic anhydride, 98%
Packaging
50g
Price
$136
Updated
2024/03/01
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Methanesulfonic anhydride Chemical Properties,Usage,Production

Chemical Properties

white to light brown to grey powder, crystals and/

Uses

Methanesulfonic anhydride is used to prepare methylsulfonyl esters called as mesylates. It finds application in the reaction of aromatic alkylation. It reacts with dimethylsulfoxide to get sulfoxonium complex, which is a useful oxidizing agent.

Preparation

Methanesulfonic anhydride may be prepared by the dehydration of methanesulfonic acid with phosphorus pentoxide.
P2O5 + 6 CH3SO3H → 3 (CH3SO2)2O + 2 H3PO4
Methanesulfonic anhydride can be purified by distillation under vacuum (distillation of a solid) or by recrystallized from Methyl tert-butyl ether/toluene.

Safety

Not only is Methanesulfonic anhydride corrosive, posing potential risks to skin, eyes, and mucous membranes, but it is also sensitive to moisture. As a hygroscopic substance, exposure to water can lead to degradation, compromising its efficacy and safety. Therefore, meticulous storage conditions are paramount to ensure the stability of the compound. To safeguard the integrity of methanesulfonic anhydride, storing it in a cool and dry environment is recommended. The storage facility should be adequately ventilated to prevent the accumulation of vapors and maintain optimal conditions for the compound. Furthermore, the storage containers must be tightly sealed to prevent moisture ingress and subsequent degradation.

Methanesulfonic anhydride Preparation Products And Raw materials

Raw materials

Preparation Products

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Methanesulfonic anhydride Suppliers

Langfang Hawk Technology & Development Co., Ltd.
Tel
0316-2224727 18631652130
Fax
0316-2224730
Email
fenghe0820@hawk-chinachem.com
Country
China
ProdList
30
Advantage
58
JIANGXI TIME PHARMACEUTICAL CO.,LTD
Tel
0794-7183888 13155888520
Fax
0794-5269668
Email
sales@groupchem.com
Country
China
ProdList
50
Advantage
60
Zhejiang zetian fine chemical co. LTD
Tel
0571-87322520 18957127338
Fax
QQ:800182836
Email
sales@zetchem.com
Country
China
ProdList
450
Advantage
58
Hubei huizepu Pharmaceutical Technology Co., Ltd
Tel
027-027-027-59212684 19371278702
Fax
QQ:2188308251
Email
p19107121455@163.com
Country
China
ProdList
3011
Advantage
58
Zhejiang Karry Pharmachem Co., Ltd.
Tel
19157666807
Email
info@karrypharma.com
Country
China
ProdList
37
Advantage
58
Nanjing Jiaju Pharmaceutical Technology Co., Ltd.
Tel
13022518189
Email
321278398@qq.com
Country
China
ProdList
153
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
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View Lastest Price from Methanesulfonic anhydride manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Methanesulfonic anhydride 7143-01-3
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100 mt
Release date
2024-11-12
Henan Fengda Chemical Co., Ltd
Product
Methanesulfonic anhydride 7143-01-3
Price
US $6.00-0.60/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-18
Hebei Mojin Biotechnology Co., Ltd
Product
Methanesulfonic anhydride 7143-01-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-28

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