P-Toluenesulfonic anhydride

Product Name: P-Toluenesulfonic anhydride
CAS No.: 4124-41-8
Chemical Name: P-Toluenesulfonic anhydride
Synonyms: 4-Methylbenzenesulfonic anhydride;p-Tolylsulfonyl 4-methylbenzenesulfonate;Tosic anhydride;Toluene-p-anhydride;3-Toluenesulfonicanhydride;P-TOLUENESULFONIC ANHYDRIDE;4-TOLUENESULFONIC ANHYDRIDE;p-Toluenesulfonyl anhydride;TOLUENE-4-SULFONIC ANHYDRIDE;P-TOLUENESULPHONIC ANHYDRIDE
CBNumber: CB1292293
Molecular Formula: C14H14O5S2
Formula Weight: 326.38
MOL File: 4124-41-8.mol

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P-Toluenesulfonic anhydride Property

Melting point:: 121-127 °C(lit.)
Boiling point:: 478.0±48.0 °C(Predicted)
Density: 1.361±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,2-8°C
form: Powder, Crystals and/or Chunks
color: Off-white to gray
Sensitive: Moisture Sensitive
BRN: 2223702
InChIKey: PDVFSPNIEOYOQL-UHFFFAOYSA-N
CAS DataBase Reference: 4124-41-8(CAS DataBase Reference)

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: UN 2585 8/PG 3
WGK Germany: 3
F: 10-21
Hazard Note: Irritant
HazardClass: 8
PackingGroup: II
HS Code: 29041000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 259764
Product name: p-Toluenesulfonic anhydride
Purity: 97%
Packaging: 5g
Price: $54.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 259764
Product name: p-Toluenesulfonic anhydride
Purity: 97%
Packaging: 25g
Price: $142
Updated: 2024/03/01

TCI Chemical

Product number: T1485
Product name: p-Toluenesulfonic Anhydride
Purity: >95.0%(T)
Packaging: 5g
Price: $28
Updated: 2024/03/01

TCI Chemical

Product number: T1485
Product name: p-Toluenesulfonic Anhydride
Purity: >95.0%(T)
Packaging: 25g
Price: $134
Updated: 2024/03/01

Alfa Aesar

Product number: L00160
Product name: p-Toluenesulfonic anhydride, 97%
Packaging: 5g
Price: $41.65
Updated: 2024/03/01

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P-Toluenesulfonic anhydride Chemical Properties,Usage,Production

Chemical Properties

Off-white to cream powder

Uses

p-Toluenesulfonic anhydride has been employed as reagent in palladium-catalyzed allylic alkenylation of allylic alcohols with n-butyl acrylate.

General Description

p-Toluenesulfonic anhydride acts as electrophilic species and activates 2-deoxy-sugar hemiacetals in situ, which reacts stereoselectively with nucleophilic acceptors to afford β-anomers.

Synthesis

Add p-toluenesulfonic acid and an m-phosphorous compound used as raw materials into a reaction kettle, dropwise adding thionyl chloride while stirring. Controlling the temperature in the reaction kettle at 68-76 ℃ and heating to perform condensation after dropwise addition; inputting water and hydrochloric acid into the reaction kettle, cooling to 0 ℃. The reaction solution generated in the previous step was drawn into the water, vacuum filtration was performed, and centrifuging was used to obtain a crude product, p-toluenesulfonic anhydride. Furthermore, it was inputting ethyl acetate, performing heating reflux, and freezing to perform crystallization, thus obtaining the qualified finished product.

P-Toluenesulfonic anhydride Preparation Products And Raw materials

Raw materials

Preparation Products

2-Aminoquinoline

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P-Toluenesulfonic anhydride Suppliers

Belgium 2 China 292 Europe 1 Germany 3 India 4 Japan 2 Switzerland 1 United Kingdom 7 United States 18 Global 330

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INTATRADE GmbH

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Alfa Aesar

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View Lastest Price from P-Toluenesulfonic anhydride manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd

Product: P-Toluenesulfonic anhydride 4124-41-8
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 ton
Release date: 2024-12-20

Shaanxi Dideu Medichem Co. Ltd

Product: P-Toluenesulfonic anhydride 4124-41-8
Price: US $1.00-50.00/KG
Min. Order: 1KG
Purity: 99%+
Supply Ability: 500KG
Release date: 2024-05-17

Henan Fengda Chemical Co., Ltd

Product: 4-Methylbenzenesulfonic Anhydride 4124-41-8
Price: US $6.00-0.60/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-01-18

4124-41-8, P-Toluenesulfonic anhydrideRelated Search:

CIS-BUTENEDIOIC ANHYDRIDE Glutaric anhydride Tosyl cyanide Trifluoromethanesulfonic anhydride TOLBUTAMIDE Succinic anhydride Isatoic Anhydride p-Toluenesulfonic acid Iron(III) p-toluenesulfonate p-Toluenesulfonamide Phthalic anhydride Sodium p-toluenesulfonate Tosyl chloride p-Toluenesulfonyl Isocyanate Ethyl p-toluenesulfonate p-Toluenesulfonic acid monohydrate Methyl p-toluenesulfonate P-TOLUENESULFONIC ACID N-BUTYL ESTER

P-TOLUENESULFONIC ANHYDRIDE

P-TOLUENESULPHONIC ANHYDRIDE

TOLUENE-4-SULFONIC ANHYDRIDE

1,3-BIS(4-METHYLPHENYL)-1,1,3,3-TETRAOXO-1LAMBDA6,3LAMBDA6-DITHIOXANE

4-TOLUENESULPHONIC ANHYDRIDE

4-Methylbenzenesulfonic anhydride

Tosic anhydride

toluene-p-sulphonic anhydride

4-Toluenesulphonic acid anhydride

4-TOLUENESULFONIC ANHYDRIDE

3-Toluenesulfonicanhydride

Toluene-4-sulphonic anhydride 95%

p-Toluenesulfonic anhydride 5GR

(4-Methylphenyl)sulfonyl 4-methylbenzenesulfonate

Toluene-4-sulfonic acid anhydride

Toluene-p-anhydride

Bis(4-methylbenzenesulfonic)anhydride

Bis(p-toluenesulfonic)anhydride

Di-p-toluenesulfonic anhydride

<i>p</i>-Toluenesulfonic Anhydride

p-Toluenesulfonyl anhydride

(4-Methylbenzene)sulfonyl 4-Methylbenzene-1-sulfonate

4-Methylbenzenesulphonic anhydride, Tosic anhydride

Toluene-4-sulphonic anhydride

p-Toluenesulfonic anhydride 97%

p-Methylbenzenesulfonic anhydride

p-Toluenesulfonic anhydride, 98%+

p-Toluenesulfonic anhydride, 95%, for synthesis

Benzenesulfonic acid, 4-methyl-, 1,1'-anhydride

p-Tolylsulfonyl 4-methylbenzenesulfonate

High Quality Pharmaceutical Intermediates P-Toluenesulfonic Anhydride

7-butoxybenzene-sulfonylchloride

p-Toluenesulfonic anhydride (6CI, 7CI, 8CI)

Toluenesulfonic anhydride (stored in the freezer, easy to decompose at high temperatures)

4124-41-8

CH3C6H4SO22O

C14H14O5S2

Protection & Derivatization Reagents (for Synthesis)

Building Blocks

Organic Building Blocks

Sulfur Compounds

Sulfonic/Sulfinic Acid Anhydrides

Pyridines

Sulfonic/Sulfinic Acid Anhydrides

Building Blocks

Chemical Synthesis

Organic Building Blocks

Sulfur Compounds

Protection & Derivatization Reagents (for Synthesis)

Synthetic Organic Chemistry

Organic Building Blocks

Sulfonic/Sulfinic Acid Anhydrides

Sulfur Compounds

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