ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE
- Product Name
- ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE
- CAS No.
- 107905-52-2
- Chemical Name
- ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE
- Synonyms
- Ethyl 2-(2,2,2-Trifluoroethyl Phosphono)propionate;ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE;Ethyl 2-(bis(2,2,2-trifluoroethoxy)phosphoryl)propanoate;2-[Bis(2,2,2-trifluoroethoxy)phosphinyl]propanoic Acid Ethyl Ester;Propanoic acid, 2-[bis(2,2,2-trifluoroethoxy)phosphinyl]-, ethyl ester
- CBNumber
- CB1110483
- Molecular Formula
- C9H13F6O5P
- Formula Weight
- 346.16
- MOL File
- 107905-52-2.mol
ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE Property
- Boiling point:
- 115-120°C/20mmHg
- Density
- 1.381±0.06 g/cm3(Predicted)
- storage temp.
- Refrigerator
- solubility
- Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
- form
- Oil
- color
- Clear Colourless to Pale Yellow
- CAS DataBase Reference
- 107905-52-2
Safety
- HS Code
- 2931599090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- E900050
- Product name
- Ethyl2-[Bis(2,2,2-trifluoroethyl)phosphono]Propionate
- Packaging
- 100mg
- Price
- $120
- Updated
- 2021/12/16
- Product number
- OPC0000902
- Product name
- ETHYL-2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO]PROPIONATE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $739.2
- Updated
- 2021/12/16
- Product number
- OPC0000902
- Product name
- ETHYL-2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO]PROPIONATE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $960.75
- Updated
- 2021/12/16
- Product number
- OPC0000902
- Product name
- ETHYL-2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO]PROPIONATE
- Purity
- 95.00%
- Packaging
- 10G
- Price
- $2333.1
- Updated
- 2021/12/16
ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE Chemical Properties,Usage,Production
Chemical Properties
Colourless Liquid
Uses
A wittig reagent.
Uses
Ethyl 2-[Bis(2,2,2-trifluoroethyl)phosphono] Propionate is an organic synthesis reagent, mainly used in organic synthesis and chemical production.
Synthesis
KHMDS (7.50 mL, 3.75 mmol, 0.5 M in toluene) was added to a solution of 18- crown-6 (4.10 g, 15.51 mmol), THF (20 mL), and bis (2,2,2-trifluoroethyl) phosphite (1) (0.50 mL, 3.41 mmol) by syringe in a dropwise manner at -78 ℃. Following 15 min, ethyl 2-bromopropionate (0.40 mL, 3.08 mmol) was added to the round bottom flask and the reaction mixture was allowed to stir for 4 hr at room temperature. Following the standard workup procedure, the crude product was then purified by flash column chromatography (3:1 to 2:1 hexanes:EtOAc, Rf = 0.33 in 1:1 hexanes:EtOAc) yielding Ethyl 2-[Bis(2,2,2-trifluoroethyl)phosphono] Propionate (112 mg, 0.33 mmol, 10.5%) as a yellow syrup.
ETHYL 2-[BIS(2,2,2-TRIFLUOROETHYL)PHOSPHONO] PROPIONATE Preparation Products And Raw materials
Raw materials
Preparation Products
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