TRIS(PENTAFLUOROPHENYL)BORANE

Uses

Product Name: TRIS(PENTAFLUOROPHENYL)BORANE
CAS No.: 1109-15-5
Chemical Name: TRIS(PENTAFLUOROPHENYL)BORANE
Synonyms: Tris(Pentafluorophenyl)Borate;TRIS(PENTAFLUOROPHENYL)BORON;Tris(pentafL;Perfluorotriphenylboron;PERFLUOROTRIPHENYLBORANE;perfluorotriphenylborone;TRIS(PENTAFLUOROPHENYL)BORANE;Tri (pentafluorobenzene) borane;Tris(pentafluorophenyl)borane 95%;Tris(pentafluorophenyl)borane,95%
CBNumber: CB1113297
Molecular Formula: C18BF15
Formula Weight: 511.98
MOL File: 1109-15-5.mol

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TRIS(PENTAFLUOROPHENYL)BORANE Property

Melting point:: 126-131 °C (lit.)
Boiling point:: 327.3±42.0 °C(Predicted)
Density: 0.73 g/mL at 20 °C
refractive index: n20/D 1.41
Flash point:: 7 °C
storage temp.: Inert atmosphere,Store in freezer, under -20°C
solubility: Soluble in hexane, chloroform, dichloromethane, toluene, and polar solvents.
form: Powder
Specific Gravity: 1.7
color: White to light yellow-beige
Sensitive: Moisture Sensitive
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
λmax: 306nm(Toluene)(lit.)
Merck: 14,9755
BRN: 2931347
InChIKey: OBAJXDYVZBHCGT-UHFFFAOYSA-N
CAS DataBase Reference: 1109-15-5(CAS DataBase Reference)
EPA Substance Registry System: Borane, tris(2,3,4,5,6-pentafluorophenyl)- (1109-15-5)

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Safety

Hazard Codes: Xi,T,N,Xn,F
Risk Statements: 36/37/38-25-67-65-50/53-38-11
Safety Statements: 60-61-62-45-37/39-26-36
RIDADR: UN 1268 3/PG 2
WGK Germany: 3
TSCA: No
HazardClass: 6.1
PackingGroup: III
HS Code: 29039990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 442593
Product name: Tris(pentafluorophenyl)borane
Purity: 95%
Packaging: 1g
Price: $209
Updated: 2024/03/01

Sigma-Aldrich

Product number: 442593
Product name: Tris(pentafluorophenyl)borane
Purity: 95%
Packaging: 5G
Price: $620
Updated: 2024/03/01

Sigma-Aldrich

Product number: 442593
Product name: Tris(pentafluorophenyl)borane
Purity: 95%
Packaging: 100G
Price: $5420
Updated: 2024/03/01

TCI Chemical

Product number: T2313
Product name: Tris(pentafluorophenyl)borane
Purity: >98.0%(NMR)
Packaging: 1g
Price: $114
Updated: 2024/03/01

TCI Chemical

Product number: T2313
Product name: Tris(pentafluorophenyl)borane
Purity: >98.0%(NMR)
Packaging: 5g
Price: $396
Updated: 2024/03/01

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TRIS(PENTAFLUOROPHENYL)BORANE Chemical Properties,Usage,Production

Uses

Tris(pentafluorophenyl)borane (CAS# 1109-15-5) is a useful research chemical, used as a catalyst in the metal-free catalytic reductive cleavage of enol ethers via proposed mechanism of tandem hydrosilylation and silicon-assisted β-elimination. Tris(pentafluorophenyl)borane also appears as an ancillary ligand in luminescent isocyano Rh(I) complexes.

Chemical Properties

white powder

Uses

Tris(pentafluorophenyl)borane is used as an excellent activator component in homogeneous Ziegler-Natta chemistry. It is also used as a catalyst for reductions, alkylations, hydrometallation reactions and catalyzed aldol-type reactions. It is a useful Lewis acid and catalyzes hydrosilylation of aldehydes. Further, it is used in olefin polymerization catalysis. It serves as a reagent in the preparation of organometallic complexes. In addition to this, it is useful as polymerization catalysts and used to study the heterolytic cleavage of dihydrogen in associated with tri-tert-butylphosphine.

Uses

Catalyst in organic transformations; cocatalyst with group IV metallocene alkyls in olefin polymerization.

General Description

B(C₆F₅)₃ is a Lewis acid, stronger than the inorganic parent molecule BF₃. In contrast to the prominent Lewis acids, the pentafluorides of the heavier elements of group 15, B(C₆F₅)₃ has no oxidizing properties. B(C₆F₅)₃forms adducts with neutral and weaker Lewis bases. B(C₆F₅)₃ has the capability to easily accept anionic ligands bonded to metals.

TRIS(PENTAFLUOROPHENYL)BORANE Preparation Products And Raw materials

Raw materials

Bromopentafluorobenzene Boron tribromide PETROLEUM ETHER n-Butyllithium

Preparation Products

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TRIS(PENTAFLUOROPHENYL)BORANE Suppliers

Belgium 1 China 185 France 1 Germany 3 India 6 Japan 4 Russia 1 Singapore 1 Switzerland 1 United Kingdom 4 United States 26 Global 233

Shanghai Weiyuan Technology Co., Ltd.

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View Lastest Price from TRIS(PENTAFLUOROPHENYL)BORANE manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: TRIS(PENTAFLUOROPHENYL)BORANE 1109-15-5
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-09

Hong Kong Tiansheng New Material Trading Co., Ltd

Product: TRIS(PENTAFLUOROPHENYL)BORANE 1109-15-5
Price: US $11.60/KG
Min. Order: 1KG
Purity: 0.99
Supply Ability: 1KG
Release date: 2021-09-24

Hong Kong Tiansheng New Material Trading Co., Ltd

Product: Tris(perfluorophenyl)borane 1109-15-5
Price: US $11.60/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10kg
Release date: 2021-09-24

1109-15-5, TRIS(PENTAFLUOROPHENYL)BORANERelated Search:

TRIPHENYLFLUOROSILANE TRIS(METHYLCYCLOPENTADIENYL)YTTRIUM (III) (TERT-BUTYLIMIDO)TRIS(ETHYLMETHYLAMINO)TANTALUM TRIS(METHYLCYCLOPENTADIENYL)ERBIUM Tris(triphenylphosphine)ruthenium(II) chloride Iridium(III) acetylacetonate BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)LEAD(II) TRIS(TETRAMETHYLCYCLOPENTADIENYL)CERIUM BISMUTH TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE) (TRIPHENYLSILYL)ACETYLENE 98 TRIS(PENTAFLUOROPHENYL)PHOSPHINE Tris(nonylphenyl) phosphite TRI-P-TOLYLPHOSPHINE TRIS(2-METHOXYPHENYL)PHOSPHINE Tris(2-phenylpyridine)iridium (Ir(ppy)3) TRIS(2-CHLOROETHYL) PHOSPHITE Pentafluorobenzene Boron

PERFLUOROTRIPHENYLBORANE

TRIS(PENTAFLUOROPHENYL)BORANE

TRIS(PENTAFLUOROPHENYL)BORON

Tris(2,3,4,5,6-pentafluorophenyl)borane

TRIS(PENTAFLUOROPHENYL)BORANE SOLUTION, ~3% IN ISOPAR

TRIS(PENTAFLUOROPHENYL)BORON, 97+%

Tris(Pentafluorophenyl)Borate

Tris(pentafluorophenyl)boron,min.97%

tris(pentafluorophenyl)borane solution

TRIS(PENTAFLUOROPHENYL)BORON, 10% in toluene

Tris(pentafluorophenyl)borane 95%

perfluorotriphenylborone

Tris(pentafluorophenyl)boron, min. 97%

Tris(pentafluorophenyl)borane,95%

Tris(pentafluorophenyl)borane ,94%

Tris(pentafluorophenyl)borane, min. 97%

Perfluorotriphenylboron

Tris(pentafluorophenyl)borane, 97%, reagent grade

Tris(pentafL

Borane, tris(2,3,4,5,6-pentafluorophenyl)-

Tri (pentafluorobenzene) borane

1109-15-5

C18BF15

C18F15B

C6F53B

Analytical Standards

Boranes

B (Classes of Boron Compounds)

Analytical Chromatography Product Catalog

Alphabetic

Reduction

TP - TZ

Synthetic Reagents

organoboron compound

BoronAlphabetic

Precursors by Metal

TP - TZ

Vapor Deposition Precursors

B (Classes of Boron Compounds)

Boranes