TRIS(PENTAFLUOROPHENYL)BORANE
Uses- Product Name
- TRIS(PENTAFLUOROPHENYL)BORANE
- CAS No.
- 1109-15-5
- Chemical Name
- TRIS(PENTAFLUOROPHENYL)BORANE
- Synonyms
- Tris(Pentafluorophenyl)Borate;TRIS(PENTAFLUOROPHENYL)BORON;B(C6F5)3;Tris(pentafL;Perfluorotriphenylboron;PERFLUOROTRIPHENYLBORANE;perfluorotriphenylborone;TRIS(PENTAFLUOROPHENYL)BORANE;trans(pentafluorophenyl)borane;Tri (pentafluorobenzene) borane
- CBNumber
- CB1113297
- Molecular Formula
- C18BF15
- Formula Weight
- 511.98
- MOL File
- 1109-15-5.mol
TRIS(PENTAFLUOROPHENYL)BORANE Property
- Melting point:
- 126-131 °C (lit.)
- Boiling point:
- 327.3±42.0 °C(Predicted)
- Density
- 0.73 g/mL at 20 °C
- refractive index
- n20/D 1.41
- Flash point:
- 7 °C
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- solubility
- Soluble in hexane, chloroform, dichloromethane, toluene, and polar solvents.
- form
- Powder
- Specific Gravity
- 1.7
- color
- White to light yellow-beige
- Sensitive
- Moisture Sensitive
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- λmax
- 306nm(Toluene)(lit.)
- Merck
- 14,9755
- BRN
- 2931347
- InChI
- 1S/C18BF15/c20-4-1(5(21)11(27)16(32)10(4)26)19(2-6(22)12(28)17(33)13(29)7(2)23)3-8(24)14(30)18(34)15(31)9(3)25
- InChIKey
- OBAJXDYVZBHCGT-UHFFFAOYSA-N
- SMILES
- Fc1c(F)c(F)c(B(c2c(F)c(F)c(F)c(F)c2F)c3c(F)c(F)c(F)c(F)c3F)c(F)c1F
- CAS DataBase Reference
- 1109-15-5(CAS DataBase Reference)
- EPA Substance Registry System
- Borane, tris(2,3,4,5,6-pentafluorophenyl)- (1109-15-5)
Safety
- Hazard Codes
- Xi,T,N,Xn,F
- Risk Statements
- 36/37/38-25-67-65-50/53-38-11
- Safety Statements
- 60-61-62-45-37/39-26-36
- RIDADR
- UN 1268 3/PG 2
- WGK Germany
- 3
- TSCA
- TSCA listed
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29039990
- Storage Class
- 11 - Combustible Solids
- Hazard Classifications
- Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 442593
- Product name
- Tris(pentafluorophenyl)borane
- Purity
- 95%
- Packaging
- 1g
- Price
- $230
- Updated
- 2026/03/19
- Product number
- 442593
- Product name
- Tris(pentafluorophenyl)borane
- Purity
- 95%
- Packaging
- 5G
- Price
- $682
- Updated
- 2026/03/19
- Product number
- 442593
- Product name
- Tris(pentafluorophenyl)borane
- Purity
- 95%
- Packaging
- 100G
- Price
- $5950
- Updated
- 2026/03/19
- Product number
- T2313
- Product name
- Tris(pentafluorophenyl)borane
- Purity
- >98.0%(NMR)
- Packaging
- 1g
- Price
- $114
- Updated
- 2026/03/19
- Product number
- T2313
- Product name
- Tris(pentafluorophenyl)borane
- Purity
- >98.0%(NMR)
- Packaging
- 5g
- Price
- $396
- Updated
- 2026/03/19
TRIS(PENTAFLUOROPHENYL)BORANE Chemical Properties,Usage,Production
Uses
Tris(pentafluorophenyl)borane (CAS# 1109-15-5) is a useful research chemical, used as a catalyst in the metal-free catalytic reductive cleavage of enol ethers via proposed mechanism of tandem hydrosilylation and silicon-assisted β-elimination. Tris(pentafluorophenyl)borane also appears as an ancillary ligand in luminescent isocyano Rh(I) complexes.
Chemical Properties
white powder
Uses
Tris(pentafluorophenyl)borane is used as an excellent activator component in homogeneous Ziegler-Natta chemistry. It is also used as a catalyst for reductions, alkylations, hydrometallation reactions and catalyzed aldol-type reactions. It is a useful Lewis acid and catalyzes hydrosilylation of aldehydes. Further, it is used in olefin polymerization catalysis. It serves as a reagent in the preparation of organometallic complexes. In addition to this, it is useful as polymerization catalysts and used to study the heterolytic cleavage of dihydrogen in associated with tri-tert-butylphosphine.
Uses
Catalyst in organic transformations; cocatalyst with group IV metallocene alkyls in olefin polymerization.
General Description
B(C6F5)3 is a Lewis acid, stronger than the inorganic parent molecule BF3. In contrast to the prominent Lewis acids, the pentafluorides of the heavier elements of group 15, B(C6F5)3 has no oxidizing properties. B(C6F5)3 forms adducts with neutral and weaker Lewis bases. B(C6F5)3 has the capability to easily accept anionic ligands bonded to metals.
Synthesis
A three-necked vial (250 mL) was charged with pentafluorobromobenzene (0.09 mol, 22.2 g) followed by 2-methyltetrahydrofuran Furan (100 mL). n-BuLi (2.5 M, 0.09 mol, 36 mL) was added dropwise at 25 C and reacted for 6.0h After that, trimethyl borate (0.03 mol, 3.1 g) was added dropwise at 25 C for 10 min. at 25 C . After 16h of reaction at 25C, the reaction was monitored by GC. The reaction solution was poured into water and extracted twice with 2-methyltetrahydrofuran, . The organic layers were combined, washed twice with water and once with saturated saline, the organic layer was dried with sodium sulfate, and the was evaporated under reduced pressure. 2-methyltetrahydrofuran and recovered 2-methyltetrahydrofuran to obtain the crude product, which was recrystallized with n-hexane to obtain trans-(pentafluorophenyltetrazolium)boron (0.0049 mol, 2.48 g) in a yield of 16.2%.
TRIS(PENTAFLUOROPHENYL)BORANE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from TRIS(PENTAFLUOROPHENYL)BORANE manufacturers
- Product
- TRIS(PENTAFLUOROPHENYL)BORANE 1109-15-5
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 10000KGS
- Release date
- 2025-05-12
- Product
- TRIS(PENTAFLUOROPHENYL)BORANE 1109-15-5
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-09
- Product
- TRIS(PENTAFLUOROPHENYL)BORANE 1109-15-5
- Price
- US $0.10/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 10
- Release date
- 2024-07-14