Tris(2-Methoxyphenyl)phosphine

Product Name: Tris(2-Methoxyphenyl)phosphine
CAS No.: 4731-65-1
Chemical Name: Tris(2-Methoxyphenyl)phosphine
Synonyms: NSC 93545;Tris(o-methoxyphenyL;Tris(2-methoxyphenyl);Tri(o-anisyl)phosphine;TRIS(O-ANISYL)PHOSPHINE;TRIS-(2-ANISYL)PHOSPHINE;TRI(2-METHOXYPHENYL)PHOSPHINE;TRIS(O-METHOXYPHENYL)PHOSPHINE;TRIS(2-METHOXYPHENYL)PHOSPHINE;tris(2-Methoxyphenyl)phosphane
CBNumber: CB6421041
Molecular Formula: C21H21O3P
Formula Weight: 352.36
MOL File: 4731-65-1.mol

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Tris(2-Methoxyphenyl)phosphine Property

Melting point:: 204-208 °C
Boiling point:: 477.3±40.0 °C(Predicted)
storage temp.: Inert atmosphere,Room Temperature
form: Liquid
color: Colorless to yellow or pale orange
Water Solubility: Slightly soluble in water.
Sensitive: Air Sensitive
BRN: 2776186
InChI: InChI=1S/C21H21O3P/c1-22-16-10-4-7-13-19(16)25(20-14-8-5-11-17(20)23-2)21-15-9-6-12-18(21)24-3/h4-15H,1-3H3
InChIKey: IIOSDXGZLBPOHD-UHFFFAOYSA-N
SMILES: P(C1=CC=CC=C1OC)(C1=CC=CC=C1OC)C1=CC=CC=C1OC
CAS DataBase Reference: 4731-65-1(CAS DataBase Reference)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 36/37/38-22
Safety Statements: 37/39-26
WGK Germany: 3
TSCA: No
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: S543160
Product name: TRIS(2-METHOXYPHENYL)PHOSPHINE
Purity: AldrichCPR
Packaging: 250mg
Price: $110
Updated: 2024/03/01

Sigma-Aldrich

Product number: 710563
Product name: Tris(o-methoxyphenyl)phosphine
Purity: 96%
Packaging: 1g
Price: $52.7
Updated: 2023/01/07

TCI Chemical

Product number: T3005
Product name: Tris(2-methoxyphenyl)phosphine
Purity: >97.0%(HPLC)
Packaging: 1g
Price: $41
Updated: 2024/03/01

TCI Chemical

Product number: T3005
Product name: Tris(2-methoxyphenyl)phosphine
Purity: >97.0%(HPLC)
Packaging: 5g
Price: $132
Updated: 2024/03/01

Alfa Aesar

Product number: A11096
Product name: Tris(2-methoxyphenyl)phosphine
Purity: 98%
Packaging: 1g
Price: $40.65
Updated: 2024/03/01

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Tris(2-Methoxyphenyl)phosphine Chemical Properties,Usage,Production

Chemical Properties

white powder or crystals

Uses

suzuki reaction

Uses

Tris(2-methoxyphenyl)phosphine is a phosphine ligand used for catalysis. It is used as a catalyst for allylic substitution of simple alkenes, suzuki coupling reactions, hydrogenation of quinolines and other addition reactions.

References

[1] Raymond C. Bott, Graham Smith, Peter C. Healy. “Structural studies of two-coordinate complexes of tris(2-methoxylphenyl)phosphine and tris(4-methoxyphenyl)phosphine with gold(I) halides.” Polyhedron 26 12 (2007): Pages 2803-2809.
[2] O. Shawkataly. “Pentacarbonyl[tris(2-methoxyphenyl)phosphine-P]chromium and its Molybdenum Analogue.” Acta crystallographica. Section C, Crystal structure communications 75 1 (1996): 1352–1355.

Tris(2-Methoxyphenyl)phosphine Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris(2-Methoxyphenyl)phosphine Suppliers

Belgium 2 China 177 France 1 Germany 2 India 4 Japan 2 Russia 1 Ukraine 1 United Kingdom 8 United States 23 Global 221

BeiJing Greenchem Technology Co.,Ltd.

Tel: 131-21959385 15640741633
Fax: 010-62925455
Email: chemrocking@bjgreenchem.com
Country: China
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Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
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ShangHai DEMO Chemical Co.,Ltd

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Beijing HwrkChemical Technology Co., Ltd

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Energy Chemical

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Capot Chemical Co., Ltd

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JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
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View Lastest Price from Tris(2-Methoxyphenyl)phosphine manufacturers

Shanghai UCHEM Inc.

Product: Tris(2-methoxyphenyl)phosphine 4731-65-1
Price: US $26.00-86.00/g
Min. Order: 25g
Purity: 0.98
Supply Ability: 25kg
Release date: 2024-04-12

Shaanxi Dideu Medichem Co. Ltd

Product: Tris(2-Methoxyphenyl)phosphine 4731-65-1
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 tons
Release date: 2020-01-15

Career Henan Chemical Co

Product: TRIS(2-METHOXYPHENYL)PHOSPHINE 4731-65-1
Price: US $1.00/KG
Min. Order: 1G
Purity: 99%
Supply Ability: 1MT
Release date: 2018-08-09

4731-65-1, Tris(2-Methoxyphenyl)phosphineRelated Search:

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TRI(2-METHOXYPHENYL)PHOSPHINE

TRIS(O-ANISYL)PHOSPHINE

TRIS(2-METHOXYPHENYL)PHOSPHINE

TRIS(O-METHOXYPHENYL)PHOSPHINE

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Tris(o-methoxyphenyl)phosphine,min.98%

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tri(2-methoxyphenyl)phosphine 98%

Tris(o-methoxyphenyl)phosphine, 98+%

tris(2-Methoxyphenyl)phosphane

NSC 93545

Tris(o-methoxyphenyl)phosphine 96%

Tris(2-methoxyphenyl)

Tris(o-methoxyphenyL

TRIS(2-METHOXYPHENYL)PHOSPHINE CAS

4731-65-1

oCH3OC6H43P

Achiral Phosphine

Aryl Phosphine

organophosphine ligand