Tris(trimethylsilyloxy)ethylene

Product Name: Tris(trimethylsilyloxy)ethylene
CAS No.: 69097-20-7
Chemical Name: Tris(trimethylsilyloxy)ethylene
Synonyms: DK363;Trimethysiloxyethylene;TRIS(TRIMETHYLSILOXY)ETHYLENE;TRIS(TRIMETHYLSILYLOXY)ETHYLENE;Tris-(trimethoxysiloxy)-ethylene;Tris(Trimethylsiloxy)Ethylene,92%;TRIS(TRIMETHYLSILYLOXY)ETHYLENE 95%;Tris(trimethylsilyloxy)ethylene,95%;1,1,2-Tris(trimethylsilyloxy)ethene;[vinyl-2-ylidenetris(oxy)]tris[trimethylsilane]
CBNumber: CB1195497
Molecular Formula: C11H28O3Si3
Formula Weight: 292.59
MOL File: 69097-20-7.mol

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Tris(trimethylsilyloxy)ethylene Property

Boiling point:: 54-56 °C/0.1 mmHg (lit.)
Density: 0.886 g/mL at 25 °C (lit.)
refractive index: n20/D 1.420(lit.)
Flash point:: 103 °F
storage temp.: 2-8°C
form: Liquid
Specific Gravity: 0.885
color: Clear colorless to yellow
Water Solubility: Insoluble
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
BRN: 1962905
CAS DataBase Reference: 69097-20-7(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-10
Safety Statements: 26-36-37/39-16
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
F: 10-21
TSCA: No
HazardClass: 3.2
PackingGroup: III
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 235148
Product name: Tris(trimethylsiloxy)ethylene
Purity: 95%
Packaging: 10g
Price: $293
Updated: 2024/03/01

TCI Chemical

Product number: T1639
Product name: Tris(trimethylsilyloxy)ethylene
Purity: >95.0%(GC)
Packaging: 5g
Price: $112
Updated: 2024/03/01

TCI Chemical

Product number: T1639
Product name: Tris(trimethylsilyloxy)ethylene
Purity: >95.0%(GC)
Packaging: 25g
Price: $335
Updated: 2024/03/01

AK Scientific

Product number: 9379AL
Product name: Tris(trimethylsilyloxy)ethylene
Packaging: 100g
Price: $487
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ORS0005291
Product name: TRIS(TRIMETHYLSILYLOXY)ETHYLENE
Purity: 95.00%
Packaging: 5G
Price: $871.48
Updated: 2021/12/16

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Tris(trimethylsilyloxy)ethylene Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellowish liquid

Uses

Tris(trimethylsiloxy)ethylene has been used in:

stereospecific synthesis of insecticide ajuqarin-IV
microwave-assisted synthesis of 2-hydroxy-1-phenylethanone

Preparation

Tris(trimethylsilyloxy)ethylene is prepared from the bis(trimethylsilyl) derivative of glycolic acid by either forming the enolate with Lithium Hexamethyldisilazide at -78 °C in THF and trapping with Chlorotrimethylsilane, or by the reaction with Trimethylsilyl Trifluoromethanesulfonate and Triethylamine at rt (eq 1).

storage

Tris(trimethylsilyloxy)ethylene is readily hydrolyzed in protic solvents. It should be stored in a sealed container protected from the atmosphere. Since the reaction of the reagent with carboxylic acid chlorides and aldehydes under Lewis acid catalysis in the absence of solvent is highly exothermic, large-scale preparations may require regulation of the reaction temperature either by external cooling or by controlled addition of the reactants.

Tris(trimethylsilyloxy)ethylene Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris(trimethylsilyloxy)ethylene Suppliers

Belgium 1 China 62 Germany 2 India 1 Japan 2 Singapore 1 Slovakia 1 Switzerland 1 United Kingdom 4 United States 17 Global 92

Shanghai Guijing New Material Technology Co., Ltd.

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J & K SCIENTIFIC LTD.

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TCI (Shanghai) Development Co., Ltd.

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Energy Chemical

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Syntechem Co.,Ltd

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Tianjin heowns Biochemical Technology Co., Ltd.

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Thermo Fisher Scientific

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Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

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View Lastest Price from Tris(trimethylsilyloxy)ethylene manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: Tris(trimethylsilyloxy)ethylene 69097-20-7
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: Tris(trimethylsilyloxy)ethylene 69097-20-7
Price: US $9.80/KG
Min. Order: 1g
Purity: ≥99%
Supply Ability: 100kg
Release date: 2020-01-10

69097-20-7, Tris(trimethylsilyloxy)ethyleneRelated Search:

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TRIS(TRIMETHYLSILOXY)ETHYLENE

TRIS(TRIMETHYLSILYLOXY)ETHYLENE

[vinyl-2-ylidenetris(oxy)]tris[trimethylsilane]

Trimethysiloxyethylene

TRIS(TRIMETHYLSILYLOXY)ETHYLENE 95%

Tris-(trimethoxysiloxy)-ethylene

2,2,7,7-tetraMethyl-4-((triMethylsilyl)oxy)-3,6-dioxa-2,7-disilaoct-4-ene

1,1,2-Tris(trimethylsilyloxy)ethene

Tris(trimethylsilyloxy)ethylene,95%

3,6-Dioxa-2,7-disilaoct-4-ene, 2,2,7,7-tetramethyl-4-[(trimethylsilyl)oxy]-

Tris(Trimethylsiloxy)Ethylene,92%

DK363

69097-20-7

CH33SiO2CCHOSiCH33

C11H28O3Si3

Building Blocks

Enol Ethers

Organic Building Blocks

Oxygen Compounds

Monoalkoxysilanes

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)

Si-O Compounds

Synthetic Organic Chemistry

Enol Ethers

Organic Building Blocks

Oxygen Compounds

Monoalkoxysilanes

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)