ChemicalBook > CAS DataBase List > Tris(2-Methoxyphenyl)phosphine

Tris(2-Methoxyphenyl)phosphine

Product Name
Tris(2-Methoxyphenyl)phosphine
CAS No.
4731-65-1
Chemical Name
Tris(2-Methoxyphenyl)phosphine
Synonyms
NSC 93545;Tris(o-methoxyphenyL;Tris(2-methoxyphenyl);Tri(o-anisyl)phosphine;TRIS(O-ANISYL)PHOSPHINE;TRIS-(2-ANISYL)PHOSPHINE;TRI(2-METHOXYPHENYL)PHOSPHINE;TRIS(O-METHOXYPHENYL)PHOSPHINE;TRIS(2-METHOXYPHENYL)PHOSPHINE;tris(2-Methoxyphenyl)phosphane
CBNumber
CB6421041
Molecular Formula
C21H21O3P
Formula Weight
352.36
MOL File
4731-65-1.mol
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Tris(2-Methoxyphenyl)phosphine Property

Melting point:
204-208 °C
Boiling point:
477.3±40.0 °C(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
Liquid
color 
Colorless to yellow or pale orange
Water Solubility 
Slightly soluble in water.
Sensitive 
Air Sensitive
BRN 
2776186
InChI
InChI=1S/C21H21O3P/c1-22-16-10-4-7-13-19(16)25(20-14-8-5-11-17(20)23-2)21-15-9-6-12-18(21)24-3/h4-15H,1-3H3
InChIKey
IIOSDXGZLBPOHD-UHFFFAOYSA-N
SMILES
P(C1=CC=CC=C1OC)(C1=CC=CC=C1OC)C1=CC=CC=C1OC
CAS DataBase Reference
4731-65-1(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
36/37/38-22
Safety Statements 
37/39-26
WGK Germany 
3
TSCA 
No
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
S543160
Product name
TRIS(2-METHOXYPHENYL)PHOSPHINE
Purity
AldrichCPR
Packaging
250mg
Price
$110
Updated
2024/03/01
Sigma-Aldrich
Product number
710563
Product name
Tris(o-methoxyphenyl)phosphine
Purity
96%
Packaging
1g
Price
$52.7
Updated
2023/01/07
TCI Chemical
Product number
T3005
Product name
Tris(2-methoxyphenyl)phosphine
Purity
>97.0%(HPLC)
Packaging
1g
Price
$41
Updated
2024/03/01
TCI Chemical
Product number
T3005
Product name
Tris(2-methoxyphenyl)phosphine
Purity
>97.0%(HPLC)
Packaging
5g
Price
$132
Updated
2024/03/01
Alfa Aesar
Product number
A11096
Product name
Tris(2-methoxyphenyl)phosphine
Purity
98%
Packaging
1g
Price
$40.65
Updated
2024/03/01
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Tris(2-Methoxyphenyl)phosphine Chemical Properties,Usage,Production

Chemical Properties

white powder or crystals

Uses

suzuki reaction

Uses

Tris(2-methoxyphenyl)phosphine is a phosphine ligand used for catalysis. It is used as a catalyst for allylic substitution of simple alkenes, suzuki coupling reactions, hydrogenation of quinolines and other addition reactions.

References

[1] Raymond C. Bott, Graham Smith, Peter C. Healy. “Structural studies of two-coordinate complexes of tris(2-methoxylphenyl)phosphine and tris(4-methoxyphenyl)phosphine with gold(I) halides.” Polyhedron 26 12 (2007): Pages 2803-2809.
[2] O. Shawkataly. “Pentacarbonyl[tris(2-methoxyphenyl)phosphine-P]chromium and its Molybdenum Analogue.” Acta crystallographica. Section C, Crystal structure communications 75 1 (1996): 1352–1355.

Tris(2-Methoxyphenyl)phosphine Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris(2-Methoxyphenyl)phosphine Suppliers

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View Lastest Price from Tris(2-Methoxyphenyl)phosphine manufacturers

Shanghai UCHEM Inc.
Product
Tris(2-methoxyphenyl)phosphine 4731-65-1
Price
US $26.00-86.00/g
Min. Order
25g
Purity
0.98
Supply Ability
25kg
Release date
2024-04-12
Shaanxi Dideu Medichem Co. Ltd
Product
Tris(2-Methoxyphenyl)phosphine 4731-65-1
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2020-01-15
Career Henan Chemical Co
Product
TRIS(2-METHOXYPHENYL)PHOSPHINE 4731-65-1
Price
US $1.00/KG
Min. Order
1G
Purity
99%
Supply Ability
1MT
Release date
2018-08-09

4731-65-1, Tris(2-Methoxyphenyl)phosphineRelated Search:

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  • Phosphine, tris(2-methoxyphenyl)-
  • Tris(2-methoxyphenyl)phosphine,98%
  • TRI(2-METHOXYPHENYL)PHOSPHINE
  • TRIS(O-ANISYL)PHOSPHINE
  • TRIS(2-METHOXYPHENYL)PHOSPHINE
  • TRIS(O-METHOXYPHENYL)PHOSPHINE
  • Tri(o-anisyl)phosphine
  • TRIS-(2-ANISYL)PHOSPHINE
  • Tris(o-methoxyphenyl)phosphine,min.98%
  • Tris(o-methoxyphenyl)phosphine, min. 98%
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  • Tris(o-methoxyphenyl)phosphine, 98+%
  • tris(2-Methoxyphenyl)phosphane
  • NSC 93545
  • Tris(o-methoxyphenyl)phosphine 96%
  • Tris(2-methoxyphenyl)
  • Tris(o-methoxyphenyL
  • TRIS(2-METHOXYPHENYL)PHOSPHINE CAS
  • 4731-65-1
  • oCH3OC6H43P
  • Achiral Phosphine
  • Aryl Phosphine
  • organophosphine ligand