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Hexamethylene diacrylate

Description Sources
Product Name
Hexamethylene diacrylate
CAS No.
13048-33-4
Chemical Name
Hexamethylene diacrylate
Synonyms
HDDA;1,6-HEXANEDIOL DIACRYLATE;Hexanediol acrylate;HDODA;Hexamethylendiacrylat;Hexane-1,6-diyl diacrylate;c716;sr238;nkesterahd;viscoat230
CBNumber
CB1114704
Molecular Formula
C12H18O4
Formula Weight
226.27
MOL File
13048-33-4.mol
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Hexamethylene diacrylate Property

Melting point:
6°C
Boiling point:
295°C
Density 
1.01 g/mL at 25 °C (lit.)
vapor density 
>1 (vs air)
vapor pressure 
<0.01 mm Hg ( 20 °C)
refractive index 
n20/D 1.456(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
solubility 
Chlroform (Slightly), DMSO (Slightly)
form 
Liquid
color 
Colourless
Specific Gravity
1.01
Water Solubility 
Slightly miscible with water.
FreezingPoint 
6
Sensitive 
Hygroscopic
Stability:
Light Sensitive
InChIKey
FIHBHSQYSYVZQE-UHFFFAOYSA-N
LogP
2.81 at 25℃
CAS DataBase Reference
13048-33-4(CAS DataBase Reference)
NIST Chemistry Reference
Hexamethylene diacrylate(13048-33-4)
EPA Substance Registry System
1,6-Hexanediol diacrylate (13048-33-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/38-43
Safety Statements 
39
RIDADR 
UN 3082 9/PG 3
WGK Germany 
2
RTECS 
AT1430000
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
HS Code 
29161290
Hazardous Substances Data
13048-33-4(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
246816
Product name
1,6-Hexanediol diacrylate
Purity
technical grade, 80%
Packaging
100g
Price
$51
Updated
2024/03/01
Sigma-Aldrich
Product number
246816
Product name
1,6-Hexanediol diacrylate
Purity
technical grade, 80%
Packaging
500g
Price
$122
Updated
2024/03/01
TCI Chemical
Product number
B2936
Product name
1,6-Bis(acryloyloxy)hexane (stabilized with MEHQ)
Purity
>85.0%(GC)
Packaging
25g
Price
$27
Updated
2024/03/01
TCI Chemical
Product number
B2936
Product name
1,6-Bis(acryloyloxy)hexane (stabilized with MEHQ)
Purity
>85.0%(GC)
Packaging
500g
Price
$103
Updated
2024/03/01
Alfa Aesar
Product number
043203
Product name
1,6-Hexanediol diacrylate, 99% (reactive esters), stab. with 90ppm hydroquinone
Packaging
50g
Price
$44.5
Updated
2024/03/01
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Hexamethylene diacrylate Chemical Properties,Usage,Production

Description

Hexamethylene diacrylate (also known as hexanediol diacrylate) is a di-functional acrylic monomer that can be polymerized by free radicals. It is used in ultra violet (UV) and electron beam (EB) applications as a reactive component in formulating coatings and inks, furniture and floor coatings, coatings on plastic substrates, varnishes for packing items and more1. The hexamethylene diacrylate cross-linked polystyrene resin can be used for the solid phase synthesis of hydrophobic peptides2-3.

Sources

  1. https://www.ashland.com/file_source/Ashland/Documents/Sustainability/rc_hexanediol_diacrylate.pdf
  2. Varkey, J. T., and V. N. Pillai. "Solid phase synthesis of hydrophobic peptides on 1,6-hexanediol diacrylate cross-linked polystyrene resin." Journal of Peptide Science 5.12(1999): 577-81.
  3. https://www.palmerholland.com/Assets/User/Documents/Product/40781/4988/MITM00481.pdf

Description

Sensitizaion occurred after accidental occupational exposure in an employee in the laboratory of a plastic paint factory.

Chemical Properties

Colorless transparent liquid

Uses

1,6-Hexandiol diacrylate is used in organic synthesis; common acrylic monomer in UV -cured inks, adhesives, coatings, photoresists, castings, artificial nails, etc.; monomer in dental composite materials.

Uses

1,6-Hexanediol diacrylate is used as a functional monomer for polymers. It acts as a cross linking agent between the molecular chains of polymers. Further, it is used in adhesives, sealants, alkyd coatings, elastomers, photopolymers, and inks for improved adhesion, hardness, abrasion and heat resistance.

General Description

Clear yellow liquid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Hexamethylene diacrylate is temperature sensitive . May react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen. Can undergo very exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides.

Fire Hazard

Hexamethylene diacrylate is probably combustible.

Flammability and Explosibility

Non flammable

Hexamethylene diacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Hexamethylene diacrylate Suppliers

Carbosynth
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6005
Advantage
58
Tokyo Chemical Industry UK Ltd.
Tel
--
Fax
--
Email
sales@tci-uk.co.uk
Country
United Kingdom
ProdList
1637
Advantage
50
MOLEKULA Ltd.
Tel
--
Fax
--
Email
kevinbanks@molekula.com
Country
United Kingdom
ProdList
6140
Advantage
66
CARBONE SCIENTIFIC CO.,LTD
Tel
--
Fax
--
Email
sales@carbonesci.com
Country
United Kingdom
ProdList
6666
Advantage
30
VWR International
Tel
--
Fax
--
Email
solutions@vwr.com
Country
United Kingdom
ProdList
6548
Advantage
82
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View Lastest Price from Hexamethylene diacrylate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Hexamethylene diacrylate 13048-33-4
Price
US $0.00/KG
Min. Order
200KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-06
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Hexamethylene diacrylate 13048-33-4
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-07
Hebei Weibang Biotechnology Co., Ltd
Product
Hexamethylene diacrylate 13048-33-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10mt
Release date
2024-11-06

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