Hexamethylene diacrylate

Description Sources

Product Name: Hexamethylene diacrylate
CAS No.: 13048-33-4
Chemical Name: Hexamethylene diacrylate
Synonyms: HDDA;1,6-HEXANEDIOL DIACRYLATE;Hexanediol acrylate;HDODA;Hexamethylendiacrylat;Hexane-1,6-diyl diacrylate;c716;sr238;nkesterahd;viscoat230
CBNumber: CB1114704
Molecular Formula: C12H18O4
Formula Weight: 226.27
MOL File: 13048-33-4.mol

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Hexamethylene diacrylate Property

Melting point:: 6°C
Boiling point:: 295°C
Density: 1.01 g/mL at 25 °C (lit.)
vapor density: >1 (vs air)
vapor pressure: <0.01 mm Hg ( 20 °C)
refractive index: n20/D 1.456(lit.)
Flash point:: >230 °F
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
solubility: Chlroform (Slightly), DMSO (Slightly)
form: Liquid
color: Colourless
Specific Gravity: 1.01
Water Solubility: Slightly miscible with water.
FreezingPoint: 6
Sensitive: Hygroscopic
Stability:: Light Sensitive
InChIKey: FIHBHSQYSYVZQE-UHFFFAOYSA-N
LogP: 2.81 at 25℃
CAS DataBase Reference: 13048-33-4(CAS DataBase Reference)
NIST Chemistry Reference: Hexamethylene diacrylate(13048-33-4)
EPA Substance Registry System: 1,6-Hexanediol diacrylate (13048-33-4)

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Safety

Hazard Codes: Xi
Risk Statements: 36/38-43
Safety Statements: 39
RIDADR: UN 3082 9/PG 3
WGK Germany: 2
RTECS: AT1430000
TSCA: Yes
HazardClass: 9
PackingGroup: III
HS Code: 29161290
Hazardous Substances Data: 13048-33-4(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 246816
Product name: 1,6-Hexanediol diacrylate
Purity: technical grade, 80%
Packaging: 100g
Price: $51
Updated: 2024/03/01

Sigma-Aldrich

Product number: 246816
Product name: 1,6-Hexanediol diacrylate
Purity: technical grade, 80%
Packaging: 500g
Price: $122
Updated: 2024/03/01

TCI Chemical

Product number: B2936
Product name: 1,6-Bis(acryloyloxy)hexane (stabilized with MEHQ)
Purity: >85.0%(GC)
Packaging: 25g
Price: $27
Updated: 2024/03/01

TCI Chemical

Product number: B2936
Product name: 1,6-Bis(acryloyloxy)hexane (stabilized with MEHQ)
Purity: >85.0%(GC)
Packaging: 500g
Price: $103
Updated: 2024/03/01

Alfa Aesar

Product number: 043203
Product name: 1,6-Hexanediol diacrylate, 99% (reactive esters), stab. with 90ppm hydroquinone
Packaging: 50g
Price: $44.5
Updated: 2024/03/01

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Hexamethylene diacrylate Chemical Properties,Usage,Production

Description

Hexamethylene diacrylate (also known as hexanediol diacrylate) is a di-functional acrylic monomer that can be polymerized by free radicals. It is used in ultra violet (UV) and electron beam (EB) applications as a reactive component in formulating coatings and inks, furniture and floor coatings, coatings on plastic substrates, varnishes for packing items and more¹. The hexamethylene diacrylate cross-linked polystyrene resin can be used for the solid phase synthesis of hydrophobic peptides^2-3.

Sources

https://www.ashland.com/file_source/Ashland/Documents/Sustainability/rc_hexanediol_diacrylate.pdf
Varkey, J. T., and V. N. Pillai. "Solid phase synthesis of hydrophobic peptides on 1,6-hexanediol diacrylate cross-linked polystyrene resin." Journal of Peptide Science 5.12(1999): 577-81.
https://www.palmerholland.com/Assets/User/Documents/Product/40781/4988/MITM00481.pdf

Description

Sensitizaion occurred after accidental occupational exposure in an employee in the laboratory of a plastic paint factory.

Chemical Properties

Colorless transparent liquid

Uses

1,6-Hexandiol diacrylate is used in organic synthesis; common acrylic monomer in UV -cured inks, adhesives, coatings, photoresists, castings, artificial nails, etc.; monomer in dental composite materials.

Uses

1,6-Hexanediol diacrylate is used as a functional monomer for polymers. It acts as a cross linking agent between the molecular chains of polymers. Further, it is used in adhesives, sealants, alkyd coatings, elastomers, photopolymers, and inks for improved adhesion, hardness, abrasion and heat resistance.

General Description

Clear yellow liquid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Hexamethylene diacrylate is temperature sensitive . May react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen. Can undergo very exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides.

Fire Hazard

Hexamethylene diacrylate is probably combustible.

Flammability and Explosibility

Non flammable

Hexamethylene diacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Hexamethylene diacrylate Suppliers

Americas 1 Australia 1 CHINA 281 Europe 3 France 1 Germany 8 India 9 Japan 5 Slovakia 1 South Africa 1 South Korea 4 Switzerland 1 The Netherlands 2 United Kingdom 5 United States 30 Global 353

HBCChem, Inc.

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HBCChem Inc.

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Alichem Inc.

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MD Chemicals

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Sartomer Americas (part of the Arkema Group)

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Synasia Inc.,

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TCI America

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Aagile Labs Division of Tyger Scientific

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Synasia Inc

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3B Scientific Corporation

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BASF Corporation

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Monomer-Polymer & Dajac Laboratories, Inc.

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Sartomer Company Inc.

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View Lastest Price from Hexamethylene diacrylate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Hexamethylene diacrylate 13048-33-4
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-05-07

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Hexamethylene diacrylate 13048-33-4
Price: US $0.00/KG
Min. Order: 200KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-06

Hebei Weibang Biotechnology Co., Ltd

Product: Hexamethylene diacrylate 13048-33-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10mt
Release date: 2024-11-06

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