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Ruthenium tetroxide

Product Name
Ruthenium tetroxide
CAS No.
20427-56-9
Chemical Name
Ruthenium tetroxide
Synonyms
RuO4;rutheniumtetraoxide;RUTHENIUM TETROXIDE;Ruthenium(Ⅷ) Oxide;ruthenium(VI) oxide;RUTHENIUM (VIII) OXIDE;Ruthenium oxide (RuO4);0.5%stabilizedaqueoussolution;Ruthenium oxide (RuO4), (T-4)-;ruthenium dioxide hydrate,superfine powder
CBNumber
CB1121685
Molecular Formula
O4Ru
Formula Weight
165.07
MOL File
20427-56-9.mol
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Ruthenium tetroxide Property

Melting point:
25.4°
Boiling point:
bp 40°
Density 
3.290
storage temp. 
Refrigerator (+4°C)
solubility 
slightly soluble in H2O; very soluble in ctc; reacEtOH
form 
Crystalline Powder
color 
White
Water Solubility 
2.03g/100mL H2O (20°C); very soluble CCl4, other chlorinated hydrocarbons [MER06] [KIR82]
Sensitive 
heat sensitive, store cold
crystal system
Monoclinic
Space group
C2/c
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.93020.439670.845490116.82900.3086
Stability:
Stable.
CAS DataBase Reference
20427-56-9
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Safety

Safety Statements 
16-17-36/37/39
RIDADR 
3139
HazardClass 
5.1
PackingGroup 
I
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Strem Chemicals
Product number
44-2000
Product name
Ruthenium(VIII) oxide (0.5% stabilized aqueous solution)
Packaging
10ml
Price
$111
Updated
2024/03/01
Strem Chemicals
Product number
44-2000
Product name
Ruthenium(VIII) oxide (0.5% stabilized aqueous solution)
Purity
Ruthenium(VIII) oxide (0.5% stabilized aqueous solution)
Packaging
5x10ml
Price
$444
Updated
2024/03/01
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Ruthenium tetroxide Chemical Properties,Usage,Production

Chemical Properties

Ruthenium tetroxide is a golden-yellow volatile solid with an acrid odor, sparingly soluble in water and freely soluble in CCl4, in which it forms stable solutions. In comparison with the analogous compound OsO4, ruthenium tetroxide is a stronger oxidizing agent that reacts violently-resulting in explosion and/or flames-with most common organic solvents such as ether, alcohols, benzene, and pyridine, 1 and also with filter paper.

Ruthenium tetroxide is a clear orange to gold colored solution, It sublimes very easily at room temperature, possessing a melting point of 25.4℃ and a boiling point of 40℃ . While it is very soluble in CCl4 and other nonflammable organic solvents, a saturated solution in water at 20℃ reaches a concentration of 2% w/v.

Uses

Ruthenium tetroxide is an oxidizing agent similar to osmium tetroxide, but more difficult to handle. The solvents normally employed in OsO4 oxidations (ether, benzene, pyridine) cannot be used because of their violent reaction with RuO4. Only CCl4 is recommended.

Preparation

Ruthenium tetroxide can be conveniently handled as a carbon tetrachloride solution that is easily prepared by stirring an aqueous solution of sodium periodate NaIO4 with a suspension of hydrated ruthenium dioxide in CCl4. Ruthenium tetroxide partitions between CCl4 and water, resulting in a 60:1 concentration ratio.

Production Methods

Ruthenium(VIII) oxide (ruthenium tetraoxide) RuO4 is formed when an alkaline ruthenium solution is treated with a strong oxidant, such as chlorine, or bromate ion when the Ru is in acid solution.

Hazard

Fire risk in contact with organic materials.

Toxicity evaluation

Ruthenium tetroxide(RuO4) is a toxic and explosive compound, and, although it is less toxic than OsO4, it must be handled in a well ventilated fume hood using goggles and gloves. It can be destroyed with a sodium bisulfite solution, resulting in the much safer and less toxic ruthenium dioxide, which is a dark insoluble solid with very low vapor pressure.

Ruthenium tetroxide Preparation Products And Raw materials

Raw materials

Preparation Products

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Ruthenium tetroxide Suppliers

J & K SCIENTIFIC LTD.
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View Lastest Price from Ruthenium tetroxide manufacturers

Career Henan Chemical Co
Product
RUTHENIUM TETROXIDE 20427-56-9
Price
US $1.00/kg
Min. Order
1kg
Purity
95%-99%
Supply Ability
100kg
Release date
2018-12-24

20427-56-9, Ruthenium tetroxideRelated Search:


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  • Ruthenium oxide (RuO4)
  • Ruthenium oxide (RuO4), (T-4)-
  • ruthenium(viii)oxide(0.5%stabilizedaqueoussolution)
  • rutheniumtetraoxide
  • 0.5%stabilizedaqueoussolution
  • Ruthenium tetroxide, 0.5% solution in water, stabilized
  • ruthenium dioxide hydrate,superfine powder
  • RutheniuM tetroxide, 0.5% solution in water, stabilized 10ML
  • Ruthenium(Ⅷ) Oxide
  • Ultrafine hydrated ruthenium dioxide powder
  • ruthenium(VI) oxide
  • 20427-56-9
  • O4Ru
  • metal oxide