1-N-Boc-cis-1,4-cyclohexyldiamine

Product Name: 1-N-Boc-cis-1,4-cyclohexyldiamine
CAS No.: 247570-24-7
Chemical Name: 1-N-Boc-cis-1,4-cyclohexyldiamine
Synonyms: 1-N-Boc-cis-1,4-cycL;1-N-Boc-cis-1,4-Cyclohexyldiam;N-Boc-cis-1,4-cyclohexyldiaMine;N1-BOC-CIS-1,4-CYCLOHEXYLDIAMINE;cis-N-Boc-1,4-cyclohexanediaMine;N-Boc-cis-1,4-cyclohexanediamine;1-N-BOC-CIS-1,4-CYCLOHEXYLDIAMINE;Cis-N-Boc-cyclohexane-1,4-diamine;Cis-1N-Boc-cyclohexane-1,4-diaMine;cis-4-(Boc-amino)cyclohexylamine,97%
CBNumber: CB1123856
Molecular Formula: C11H22N2O2
Formula Weight: 214.3
MOL File: 247570-24-7.mol

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1-N-Boc-cis-1,4-cyclohexyldiamine Property

Boiling point:: 322.1±31.0 °C(Predicted)
Density: 1.02±0.1 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: powder
pka: 12.44±0.40(Predicted)
color: Off-white
Water Solubility: Soluble in methanol, ethyl acetate and Slightly soluble in water.
InChI: InChI=1S/C11H22N2O2/c1-11(2,3)15-10(14)13-9-6-4-8(12)5-7-9/h8-9H,4-7,12H2,1-3H3,(H,13,14)/t8-,9+
InChIKey: FEYLUKDSKVSMSZ-DTORHVGOSA-N
SMILES: C(OC(C)(C)C)(=O)N[C@@H]1CC[C@H](N)CC1
CAS DataBase Reference: 247570-24-7

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Safety

Hazard Codes: Xi
HazardClass: IRRITANT
HS Code: 2921309990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Usbiological

Product number: 228891
Product name: 1-N-Boc-cis-1,4-cyclohexyldiamine 98+%
Packaging: 1g
Price: $196
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB56957
Product name: 1-N-Boc-cis-1,4-cyclohexyldiamine
Packaging: 1g
Price: $70
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4H56-1-TW
Product name: cis-Cyclohexane-1,4-diamine, N-Boc protected
Purity: 98%
Packaging: 1g
Price: $90
Updated: 2021/12/16

Matrix Scientific

Product number: 032285
Product name: cis-tert-Butyl 4-aminocyclohexylcarbamate
Purity: 95%
Packaging: 5g
Price: $112
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB56957
Product name: 1-N-Boc-cis-1,4-cyclohexyldiamine
Packaging: 2g
Price: $112
Updated: 2021/12/16

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1-N-Boc-cis-1,4-cyclohexyldiamine Chemical Properties,Usage,Production

Uses

cis-4-(Boc-amino)cyclohexylamine can be used in agrochemical, pharmaceutical and dyestuff field.

Synthesis

247568-84-9

247570-24-7

Step 4: To a solution of tert-butyl (cis-4-azido-cyclohexyl)-carbamate (6.3 g, 26 mmol) in methanol (100 mL) was added 5% Pd/C (Degussa type, 0.63 g) under argon protection. The reaction flask was sealed, evacuated and backfilled with hydrogen, and the process was repeated three times. The reaction mixture was stirred for 2 h at room temperature under an atmosphere of hydrogen at 1 atm. Upon completion of the reaction, the catalyst was removed by filtration through a diatomaceous earth pad and the filtrate was concentrated under reduced pressure. The residue was partitioned between ether (Et2O) and 1N hydrochloric acid (HCl) solution. The aqueous phase was separated and alkalized with sodium hydroxide solution to pH > 10, followed by extraction with ethyl acetate (EtOAc, 2 × 100 mL). The organic phases were combined, washed with saturated sodium chloride solution (brine), dried over anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure to afford the white solid product (tert-butyl cis-4-amino-cyclohexyl)-carbamate (3.6 g, 64% yield). Mass spectrometry (MS) analysis showed (M+H)+ = 215.6.

References

[1] Patent: US2005/54626, 2005, A1. Location in patent: Page/Page column 48
[2] Patent: EP1683795, 2006, A1. Location in patent: Page/Page column 14; 15
[3] Patent: US2005/20639, 2005, A1. Location in patent: Page 14 - 15

1-N-Boc-cis-1,4-cyclohexyldiamine Preparation Products And Raw materials

Raw materials

Preparation Products

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1-N-Boc-cis-1,4-cyclohexyldiamine Suppliers

China 124 Europe 1 India 3 United Kingdom 5 United States 20 Global 153

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View Lastest Price from 1-N-Boc-cis-1,4-cyclohexyldiamine manufacturers

Career Henan Chemical Co

Product: 1-N-Boc-cis-1,4-cyclohexyldiamine 247570-24-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2019-12-30

247570-24-7, 1-N-Boc-cis-1,4-cyclohexyldiamineRelated Search:

Nylon 6/6 trans-1,4-Diaminocyclohexane Cyclohexa-1,4-diene 1,2-Diaminocyclohexane (+/-)-trans-1,2-Diaminocyclohexane 1,4-Cyclohexanedione Hexamethylenediamine N-Boc-1,4-cyclohexanediamine CIS-1,4-CYCLOHEXANEDIAMINE 2-(1-amino-4-(tert-butoxycarbonylamino)cyclohexyl)acetic acid 1-N-Boc-cis-1,2-cyclohexyldiamine 4-(N-T-BUTOXYCARBONYLAMINO)CYCLOHEXYLISOCYANIDE 1-N-Boc-cis-1,4-cyclohexyldiamine 1, 1-ACCH(4-AMINO-BOC)-OME BOC-(4-CIS/TRANS)-1, 1-ACCH(4-AMINO-FMOC) BOC-CIS-1,4-AMINO-1-CYCLOHEXYL ACETIC ACID FMOC-1, 1-ACCH(4-AMINO-BOC) BOC-CIS-1,4-AMINO-1-CYCLOHEXANE CARBOXYLIC ACID

1-N-BOC-CIS-1,4-CYCLOHEXYLDIAMINE

CIS-(4-AMINO-CYCLOHEXYL)-CARBAMIC ACID TERT-BUTYL ESTER

Carbamic acid, (cis-4-aminocyclohexyl)-, 1,1-dimethylethyl ester (9CI)

1-N-Boc-cis-1,4-Cyclohexyldiam

cis tert-Butyl 4-aminocyclohexylcarbamate

Cis-(4-Amino-cyclohexyl)-carbamic acid

cis-Cyclohexane-1,4-diamine, N-BOC protected

tert-Butyl (cis-4-aminocyclohex-1-yl)carbamate, cis-1,4-Diaminocyclohexane, N-BOC protected

(4-{[(tert-butoxy)carbonyl]aMino}cyclohexyl)azanylidene

cis-N-tert-Butoxycarbonyl-1,4-cyclohexanediaMine

N-Boc-cis-1,4-cyclohexyldiaMine

TERT-BUTYL CIS-4-AMINOCYCLOHEXYLCARBAMATE

N1-BOC-CIS-1,4-CYCLOHEXYLDIAMINE

CarbaMic acid, N-(cis-4-aMinocyclohexyl)-, 1,1-diMethylethyl ester

cis-4-(Boc-aMino)cyclohexylaMine, 97%

cis-Cyclohexane-1,4-diamine, 1-BOC protected

tert-Butyl (cis-4-aminocyclohex-1-yl)carbamate, cis-1,4-Diaminocyclohexane, 1-BOC protected

cis-N-Boc-1,4-cyclohexanediaMine

Cis-1N-Boc-cyclohexane-1,4-diaMine

(E)-tert-butyl hydrogen ((1s,4s)-4-aminocyclohexyl)carbonimidate

Cis-N-Boc-cyclohexane-1,4-diamine

N-tert-Butoxycarbonyl-1,4-cyclohexanediamine

1-N-Boc-Cis-1,4-Cyclohexyldiamine 98%

Carbamic acid, (cis-4-aminocyclohexyl)-, 1,1-dimethylethyl ester

N-(4-aminocyclohexyl)carbamic acid tert-butyl ester

1-N-Boc-cis-1,4-cycL

cis-4-(Boc-amino)cyclohexylamine,97%

N-Boc-cis-1,4-cyclohexanediamine

247570-24-7

N-BOC