1,4-Cyclohexanedione
- Product Name
- 1,4-Cyclohexanedione
- CAS No.
- 637-88-7
- Chemical Name
- 1,4-Cyclohexanedione
- Synonyms
- CHD;Cyclohexane-1,4-dione;CYCLOHEXANEDIONE;1,4-Cyclohexadione;Tetrahydroquinone;1,4-CYCHEXANEDIONE;1,4-CYCLOHEXANDIONE;1,4-cyclohexanedion;Cyclohexan-1,4-dione;1,4-Dioxocyclohexane
- CBNumber
- CB7138205
- Molecular Formula
- C6H8O2
- Formula Weight
- 112.13
- MOL File
- 637-88-7.mol
1,4-Cyclohexanedione Property
- Melting point:
- 77-78.5 °C (lit.)
- Boiling point:
- 112 °C (19.5026 mmHg)
- Density
- 1.0861
- refractive index
- 1.4570 (estimate)
- Flash point:
- 132 °C
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Soluble in methanol and ethanol.
- form
- Crystalline Powder or Flakes
- color
- Light yellow to yellow or beige
- BRN
- 774152
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- LogP
- -0.910 (est)
- CAS DataBase Reference
- 637-88-7(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,4-Cyclohexanedione(637-88-7)
- EPA Substance Registry System
- 1,4-Cyclohexanedione (637-88-7)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 125423
- Product name
- 1,4-Cyclohexanedione
- Purity
- 98%
- Packaging
- 10g
- Price
- $60.5
- Updated
- 2024/03/01
- Product number
- 125423
- Product name
- 1,4-Cyclohexanedione
- Purity
- 98%
- Packaging
- 50g
- Price
- $111
- Updated
- 2024/03/01
- Product number
- C0730
- Product name
- 1,4-Cyclohexanedione
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $54
- Updated
- 2024/03/01
- Product number
- C0730
- Product name
- 1,4-Cyclohexanedione
- Purity
- >98.0%(GC)
- Packaging
- 500g
- Price
- $527
- Updated
- 2024/03/01
- Product number
- A11100
- Product name
- 1,4-Cyclohexanedione, 98%
- Packaging
- 25g
- Price
- $58
- Updated
- 2024/03/01
1,4-Cyclohexanedione Chemical Properties,Usage,Production
Chemical Properties
tan or yellow crystalline powder
Uses
1,4-Cyclohexanedione is used in the preparation of 1,4 benzoquinone and bromoorganics. It is also used to study the influence of visible light on the bromate-1,4-cyclohexanedione-ferroin oscillating reaction. It plays a vital role in pharmaceuticals, plant growth regulator and as a conducting material.
Definition
ChEBI: 1,4-Cyclohexanedione is a cyclohexanedione with oxo substituents at positions 1 and 4.
Preparation
Synthesis of 1,4-cyclohexanedione: put diethyl succinylsuccinate into a flask, add a mixture of concentrated sulfuric acid, water and ethanol, reflux in oil solution for 5 days, cool, and neutralize to pH with ammonia water = 8; then extract 4 times with chloroform, and recover the chloroform to obtain the crude product; then the crude product is subjected to vacuum distillation, and the distillate is poured into cold petroleum ether, filtered, and air-dried to obtain 1,4-cyclohexanedi Ketone Products.
Synthesis Reference(s)
Synthesis, p. 165, 1981 DOI: 10.1055/s-1981-29377
General Description
1,4-Cyclohexanedione(CHD) undergoes uncatalyzed oscillatory reactions during oxidation by acidic bromate in nitric acid and sulphuric acid solution. It reacts with acidic bromate to form 1,4-dihydroxybenzene which on further oxidation and bromination yields 1,4-benzoquinone and bromoorganics.
Pharmacology
The cyclohexanedione (CHD) herbicides inhibit fatty acid synthesis in plants by interfering with the activity of the enzyme Acetyl-Coenzyme A Carboxylase (ACCase). ACCase-inhibiting herbicides provide excellent control of grass weeds in dicotyledonous and some grass crops. A less-sensitive ACCase mediates the intrinsic resistance of dicotyledonous plants to the AOPP and CHD herbicides (34,35). Although grasses are target species of this group of herbicides, not all are equally affected, and sensitivity differences can occur between varieties or even within a genus.
1,4-Cyclohexanedione Preparation Products And Raw materials
Raw materials
Preparation Products
1,4-Cyclohexanedione Suppliers
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View Lastest Price from 1,4-Cyclohexanedione manufacturers
- Product
- 1,4-Cyclohexanedione 637-88-7
- Price
- US $50.00/kg
- Min. Order
- 1kg
- Purity
- 99.10%
- Supply Ability
- 50000kg
- Release date
- 2024-04-24
- Product
- 1,4-Cyclohexanedione 637-88-7
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99.5%
- Supply Ability
- 10MT/month
- Release date
- 2024-03-12
- Product
- 1,4-Cyclohexanedione 637-88-7
- Price
- US $40.00-40.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10 tons
- Release date
- 2023-10-16