ChemicalBook > CAS DataBase List > Butylmagnesium chloride

Butylmagnesium chloride

Product Name
Butylmagnesium chloride
CAS No.
693-04-9
Chemical Name
Butylmagnesium chloride
Synonyms
N-BUTYLMAGNESIUM CHLORIDE;Butylmagnesium;n-Butylmagnesium chloride 2M solution in DEE;Butylchloromagnesium;ButylMagnesiuM chlor;Butyl(chloro)magnesium;BUTYLMAGNESIUM CHLORIDE;Magnesium, butylchloro-;ButylMagnesiuM Chloride Butylmagnesium Chloride, 2.0
CBNumber
CB1159923
Molecular Formula
C4H9ClMg
Formula Weight
116.87
MOL File
693-04-9.mol
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Butylmagnesium chloride Property

Melting point:
-17°C
Boiling point:
66°C
Density 
0.962 g/mL at 25 °C
Flash point:
115 °F
storage temp. 
2-8°C
form 
Solution
color 
Green-brown to brown
Water Solubility 
reacts
Sensitive 
Air & Moisture Sensitive
BRN 
3587228
InChIKey
UUNGXYVLXYGZKH-UHFFFAOYSA-M
CAS DataBase Reference
693-04-9(CAS DataBase Reference)
EPA Substance Registry System
Magnesium, butylchloro- (693-04-9)
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Safety

Hazard Codes 
C,F,F+
Risk Statements 
12-14/15-19-22-34-67-65-63-48/20-11-15-14-10-40-37
Safety Statements 
7-9-16-26-29-33-36/37/39-43-45-62-46
RIDADR 
UN 3399 4.3/PG 2
WGK Germany 
1
F 
10
TSCA 
Yes
HazardClass 
4.3
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H226Flammable liquid and vapour

H250Catches fire spontaneously if exposed to air

H260In contact with water releases flammable gases which may ignite spontaneously

H261In contact with water releases flammable gas

H302Harmful if swallowed

H303May be harmfulif swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H333May be harmful if inhaled

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

H351Suspected of causing cancer

H371May cause damage to organs

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P222Do not allow contact with air.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231+P232Handle under inert gas. Protect from moisture.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P335+P334Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P405Store locked up.

P422Store contents under …

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
224375
Product name
Butylmagnesium chloride solution
Purity
2.0M in diethyl ether
Packaging
100ml
Price
$159
Updated
2024/03/01
Sigma-Aldrich
Product number
224375
Product name
Butylmagnesium chloride solution
Purity
2.0M in diethyl ether
Packaging
800ml
Price
$193
Updated
2024/03/01
TCI Chemical
Product number
B0726
Product name
Butylmagnesium Chloride (23% in Tetrahydrofuran, ca. 2mol/L)
Packaging
250g
Price
$80
Updated
2024/03/01
Alfa Aesar
Product number
041676
Product name
n-Butylmagnesium chloride, 1.5-2.5M in THF, packaged under Argon in resealable ChemSeal? bottles
Packaging
50ml
Price
$27.4
Updated
2021/12/16
Alfa Aesar
Product number
041676
Product name
n-Butylmagnesium chloride, 1.5-2.5M in THF, packaged under Argon in resealable ChemSeal? bottles
Packaging
250ml
Price
$121
Updated
2021/12/16
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Butylmagnesium chloride Chemical Properties,Usage,Production

Chemical Properties

green-brown to brown solution

Uses

n-Butylmagnesium chloride is used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.

Uses

Butylmagnesium chloride (BuMgCl) is a Grignard reagent that can be used:

  • To prevent the formation of passivating surface films on Mg electrodes.
  • For the synthesis of lithium tributylmagnesate complex (n-Bu3MgLi) by reacting with n-BuLi.

Butylmagnesium chloride Preparation Products And Raw materials

Raw materials

Preparation Products

3-Quinolinecarboxaldehyde
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View Lastest Price from Butylmagnesium chloride manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Butylmagnesium chloride 693-04-9
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Career Henan Chemical Co
Product
Butylmagnesium chloride 693-04-9
Price
US $1.00/KG
Min. Order
1KG
Purity
97-99%
Supply Ability
1000KGS
Release date
2019-12-18

693-04-9, Butylmagnesium chlorideRelated Search:

TERT-BUTYLMAGNESIUM CHLORIDE CYCLOHEXYLMAGNESIUM CHLORIDE ISOPROPYLMAGNESIUM CHLORIDE Allylmagnesium chloride Butyldi-1-adamantylphosphine ZIRCONIUM N-PROPOXIDE Butylferrocene Butyltin oxide 1-Iodoheptane Sodium butanolate Di(1-adamantyl)-n-butylphosphine hydriodide 3-FLUOROPHENYLMAGNESIUM BROMIDE O-TOLYLMAGNESIUM BROMIDE ISOBUTYLMAGNESIUM BROMIDE 4-FLUOROPHENYLMAGNESIUM BROMIDE 4-CHLOROPHENYLMAGNESIUM BROMIDE Benzylmagnesium chloride PROPYLMAGNESIUM CHLORIDE

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  • Butylmagnesium Chloride, 2.0
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  • n-butylmagnesium chloride, 1.5-2.5m in thf, packaged under argon in resealable chemseal
  • n-Butylmagnesium chloride, 1.5-2.5M in THF, packaged under Argon in resealable ChemSealTM bottles
  • Butylmagnesium Chloride (23% in Tetrahydrofuran, ca. 2mol/L)
  • n-ButylMagnesiuM chloride, 2.0 M solution in THF, J&KSeal
  • n-ButylMagnesiuM chloride, 2.0M solution in diethyl ether, J&KSeal
  • n-ButylMagnesiuM chloride, 1.45M solution in Butyl diglyMe, SpcSeal
  • n-Butylmagnesium chloride, 1.45M solution in butyl diglyme, J&KSeal
  • ButylMagnesiuM chloride solution 2.0 M in THF
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