3-Quinolinecarboxaldehyde
- Product Name
- 3-Quinolinecarboxaldehyde
- CAS No.
- 13669-42-6
- Chemical Name
- 3-Quinolinecarboxaldehyde
- Synonyms
- 3-Q;3-Formylquinoline;AKOS BBS-00005332;RARECHEM AK ML 0129;Chinolin-3-carbaldehyd;3-QUINOLINECARBALDEHYDE;3-quinoliecarboxaldehyde;QUINOLINE-3-CARBALDEHYDE;3-quinolylcarboxaldehyde;3-QUINOLINECARBOXALDEHYDE
- CBNumber
- CB3111732
- Molecular Formula
- C10H7NO
- Formula Weight
- 157.17
- MOL File
- 13669-42-6.mol
3-Quinolinecarboxaldehyde Property
- Melting point:
- 68-71 °C (lit.)
- Boiling point:
- 128°C/1mmHg(lit.)
- Density
- 1.223±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- pka
- 3.36±0.11(Predicted)
- form
- Powder
- color
- White to yellow
- λmax
- 282nm(MeOH)(lit.)
- Sensitive
- Air Sensitive
- BRN
- 113269
- CAS DataBase Reference
- 13669-42-6(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 37/38-36/37/38
- Safety Statements
- 26-37/39-36-24/25-22
- WGK Germany
- 3
- F
- 10-23
- HS Code
- 29334900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 177121
- Product name
- 3-Quinolinecarboxaldehyde
- Purity
- 98%
- Packaging
- 1g
- Price
- $120
- Updated
- 2023/06/20
- Product number
- 177121
- Product name
- 3-Quinolinecarboxaldehyde
- Purity
- 98%
- Packaging
- 5g
- Price
- $201
- Updated
- 2023/06/20
- Product number
- Q0075
- Product name
- 3-Quinolinecarboxaldehyde
- Purity
- >96.0%(GC)(T)
- Packaging
- 1g
- Price
- $101
- Updated
- 2025/07/31
- Product number
- Q0075
- Product name
- 3-Quinolinecarboxaldehyde
- Purity
- >96.0%(GC)(T)
- Packaging
- 5g
- Price
- $335
- Updated
- 2025/07/31
- Product number
- Q700505
- Product name
- 3-Quinolinecarboxaldehyde
- Packaging
- 10mg
- Price
- $45
- Updated
- 2021/12/16
3-Quinolinecarboxaldehyde Chemical Properties,Usage,Production
Chemical Properties
White to yellow powder
Uses
3-Quinolinecarboxaldehyde was used in the synthesis of 1,4-addition products.
General Description
The structure and vibrational spectra of 3-quinolinecarboxaldehyde has been studied.
Synthesis
5332-24-1
68-12-2
13669-42-6
General method: n-Butyllithium (2.5 M in hexane, 300 μL, 0.72 mmol) was added slowly and dropwise to an anhydrous THF (1.5 mL) solution of 3-bromoquinoline (100 mg, 0.48 mmol) at -78 °C. The reaction solution turned red. The reaction solution then turned red, followed by the addition of N,N-dimethylformamide (192 μL, 2.49 mmol). After maintaining the reaction temperature at -78 °C for 10 min, the reaction was quenched with deionized water. The reaction mixture was transferred to saturated aqueous sodium bicarbonate solution (10 mL) and extracted with ethyl acetate (3 × 10 mL). The organic phases were combined, dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: n-hexane solution of 10% ethyl acetate) to give quinoline-3-carbaldehyde as a yellow solid in 53% yield.
References
[1] Tetrahedron Letters, 2003, vol. 44, # 10, p. 2033 - 2035
[2] Tetrahedron, 2003, vol. 59, # 43, p. 8629 - 8640
[3] Tetrahedron, 2002, vol. 58, # 17, p. 3387 - 3400
[4] European Journal of Medicinal Chemistry, 2019, p. 290 - 320
3-Quinolinecarboxaldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-Quinolinecarboxaldehyde manufacturers
- Product
- 3-Quinolinecarboxaldehyde 13669-42-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2024-11-20
- Product
- 3-Quinolinecarboxaldehyde 13669-42-6
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-14
- Product
- 3-Quinolinecarboxaldehyde 13669-42-6
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2021-10-13