3-Bromoquinoline
Bromoquinoline Application and synthesis method Uses- Product Name
- 3-Bromoquinoline
- CAS No.
- 5332-24-1
- Chemical Name
- 3-Bromoquinoline
- Synonyms
- Quinoline, 3-bromo-;NSC 3995;CETH-016;3-BromoquinoL;Bromoquinoline;3-BROMOQUINOLINE;3-BROMOQUINLIINE;3-bromo-quinolin;3-Bromoquuinoline;1-3-Bromoquinoline
- CBNumber
- CB4220082
- Molecular Formula
- C9H6BrN
- Formula Weight
- 208.05
- MOL File
- 5332-24-1.mol
3-Bromoquinoline Property
- Melting point:
- 13-15 °C (lit.)
- Boiling point:
- 274-276 °C (lit.)
- Density
- 1.533 g/mL at 25 °C (lit.)
- vapor pressure
- 0.196Pa at 25℃
- refractive index
- n20/D 1.664(lit.)
- Flash point:
- >230 °F
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- 2.69(at 25℃)
- form
- Liquid
- color
- Clear colorless to yellow
- Water Solubility
- 103mg/L at 25℃
- BRN
- 112939
- InChIKey
- ZGIKWINFUGEQEO-UHFFFAOYSA-N
- LogP
- 3.03
- CAS DataBase Reference
- 5332-24-1(CAS DataBase Reference)
- NIST Chemistry Reference
- Quinoline, 3-bromo-(5332-24-1)
- EPA Substance Registry System
- Quinoline, 3-bromo- (5332-24-1)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-37/39
- RIDADR
- UN2810
- WGK Germany
- 3
- TSCA
- Yes
- HS Code
- 29334900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 124133
- Product name
- 3-Bromoquinoline
- Purity
- 98%
- Packaging
- 25g
- Price
- $119
- Updated
- 2024/03/01
- Product number
- 124133
- Product name
- 3-Bromoquinoline
- Purity
- 98%
- Packaging
- 100g
- Price
- $319
- Updated
- 2024/03/01
- Product number
- B1013
- Product name
- 3-Bromoquinoline
- Purity
- >98.0%(GC)(T)
- Packaging
- 25g
- Price
- $94
- Updated
- 2024/03/01
- Product number
- A14573
- Product name
- 3-Bromoquinoline, 98%
- Packaging
- 10g
- Price
- $30.65
- Updated
- 2024/03/01
- Product number
- A14573
- Product name
- 3-Bromoquinoline, 98%
- Packaging
- 50g
- Price
- $113.65
- Updated
- 2024/03/01
3-Bromoquinoline Chemical Properties,Usage,Production
Bromoquinoline
There are seven position isomers with the main properties are as follows:
(2399.79Pa)
Application and synthesis method
3-Bromoquinoline can have action with mixed acid to generate 3-bromo-5-nitroquinoline, followed by heating with potassium permanganate to be oxidized to 5-bromo-2, 3-pyridine dicarboxylic acid.
6-bromo-quinoline can be heated together nitric acid to generate 6-bromo-8-nitro-quinoline, followed by reaction with potassium permanganate to be oxidized into 2, 3-pyridinedicarboxylic acid.
2-bromo-quinoline can be manufactured through the reaction between 2-hydroxyquinoline and phosphorus pentabromide
3-bromo-quinoline can be obtained through heating the quinoline perbromide at 180 ° C.
4-bromoquinoline can be obtained through either the heating reaction between 4-hydroxyquinoline and phosphorus pentabromide or by the diazotization reaction of 4-aminoquinoline.
5-bromo-quinoline can be obtained from the heating reaction between m-bromo aniline, glycerol, m-bromonitrobenzene and concentrated sulfuric acid, or through the diazotization reaction of 5-amino-quinoline.
6-bromo-quinoline can be obtained through the heating reaction between p-bromoaniline, glycerol, concentrated sulfuric acid and p-bromo-nitrobenzene.
7-bromoquinoline can be obtained through the diazotization of 7-aminoquinoline.
8-bromo-quinoline can be obtained through the heating of o-bromo aniline, glycerol, concentrated sulfuric acid and o-bromo-nitrobenzene in the heating system.
Purposes: as organic synthesis reagents.
Uses
For pharmaceuticals
Medicine, pesticide intermediates
Chemical Properties
colorless to light yellow liquid
Synthesis Reference(s)
The Journal of Organic Chemistry, 27, p. 1318, 1962 DOI: 10.1021/jo01051a047
General Description
3-Bromoquinoline undergoes bromine-magnesium exchange reaction with lithium tributylmagnesate in toluene at -10°C, which is quenched by various electrophiles to yield functionalized quinolines.
Flammability and Explosibility
Not classified
3-Bromoquinoline Preparation Products And Raw materials
Raw materials
Preparation Products
3-Bromoquinoline Suppliers
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View Lastest Price from 3-Bromoquinoline manufacturers
- Product
- 3-Bromoquinoline 5332-24-1
- Price
- US $11.00-119.00/g
- Min. Order
- 25g
- Purity
- 0.98
- Supply Ability
- 25kg
- Release date
- 2023-12-14
- Product
- 3-Bromoquinoline 5332-24-1
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-12
- Product
- 3-Bromoquinoline 5332-24-1
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 Tons
- Release date
- 2021-10-13